Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene / / by Ruijun Hou
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| Autore: |
Hou Ruijun
|
| Titolo: |
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene / / by Ruijun Hou
|
| Pubblicazione: | Singapore : , : Springer Singapore : , : Imprint : Springer, , 2017 |
| Edizione: | 1st ed. 2017. |
| Descrizione fisica: | 1 online resource (XII, 141 p. 83 illus., 42 illus. in color.) |
| Disciplina: | 547.23 |
| Soggetto topico: | Catalysis |
| Chemistry, Physical and theoretical | |
| Chemical engineering | |
| Organic chemistry | |
| Theoretical and Computational Chemistry | |
| Industrial Chemistry/Chemical Engineering | |
| Organic Chemistry | |
| Note generali: | "Doctoral Thesis accepted by Tsinghua University, Beijing, China"--Title page. |
| Nota di bibliografia: | Includes bibliographical references at the end of each chapters. |
| Nota di contenuto: | Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion. |
| Sommario/riassunto: | This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<. |
| Titolo autorizzato: | Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene |
| ISBN: | 9789811007736 |
| Formato: | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione: | Inglese |
| Record Nr.: | 9910159532203321 |
| Lo trovi qui: | Univ. Federico II |
| Opac: | Controlla la disponibilità qui |
Serie:
Springer Theses, Recognizing Outstanding Ph.D. Research, . 2190-5053