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[null,"1.","Record Nr.",null,"UNINA9910159532203321"]
[null,null,"Autore",null,"Hou Ruijun"]
[null,null,"Titolo",null,"Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene / / by Ruijun Hou"]
[null,null,"Pubbl/distr/stampa",null,"Singapore : , : Springer Nature Singapore : , : Imprint : Springer, , 2017"]
[null,null,"ISBN",null,"9789811007736"]
[null,null,"Edizione",null,"[1st ed. 2017.]"]
[null,null,"Descrizione fisica",null,"1 online resource (XII, 141 p. 83 illus., 42 illus. in color.)"]
[null,null,"Collana",null,"Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5061"]
[null,null,"Disciplina",null,"547.23"]
[null,null,"Soggetti",null,"Catalysis"]
[{"$nulls":4},"Chemistry, Physical and theoretical"]
[{"$nulls":4},"Chemistry, Technical"]
[{"$nulls":4},"Chemistry, Organic"]
[{"$nulls":4},"Theoretical Chemistry"]
[{"$nulls":4},"Industrial Chemistry"]
[{"$nulls":4},"Organic Chemistry"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","\"Doctoral Thesis accepted by Tsinghua University, Beijing, China\"--Title page."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references at the end of each chapters."]
[null,null,"Nota di contenuto",null,"Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion."]
[null,null,null,"Sommario/riassunto","This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage "]
[{"$nulls":4},"slurry bed reactor for industrial applications."]