LEADER 03872nam 22006495 450 001 9910159532203321 005 20200701023524.0 010 $a9789811007736 024 7 $a10.1007/978-981-10-0773-6 035 $a(CKB)3710000001008960 035 $a(DE-He213)978-981-10-0773-6 035 $a(MiAaPQ)EBC4777491 035 $a(PPN)198338678 035 $a(EXLCZ)993710000001008960 100 $a20170105d2017 u| 0 101 0 $aeng 135 $aurnn|008mamaa 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aCatalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene /$fby Ruijun Hou 205 $a1st ed. 2017. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2017. 215 $a1 online resource (XII, 141 p. 83 illus., 42 illus. in color.) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 300 $a"Doctoral Thesis accepted by Tsinghua University, Beijing, China"--Title page. 311 $a981-10-0772-1 311 $a981-10-0773-X 320 $aIncludes bibliographical references at the end of each chapters. 327 $aIntroduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd?Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion. 330 $aThis thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd?Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<. 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aCatalysis 606 $aChemistry, Physical and theoretical 606 $aChemical engineering 606 $aOrganic chemistry 606 $aCatalysis$3https://scigraph.springernature.com/ontologies/product-market-codes/C29000 606 $aTheoretical and Computational Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C25007 606 $aIndustrial Chemistry/Chemical Engineering$3https://scigraph.springernature.com/ontologies/product-market-codes/C27000 606 $aOrganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19007 615 0$aCatalysis. 615 0$aChemistry, Physical and theoretical. 615 0$aChemical engineering. 615 0$aOrganic chemistry. 615 14$aCatalysis. 615 24$aTheoretical and Computational Chemistry. 615 24$aIndustrial Chemistry/Chemical Engineering. 615 24$aOrganic Chemistry. 676 $a547.23 700 $aHou$b Ruijun$4aut$4http://id.loc.gov/vocabulary/relators/aut$0767662 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910159532203321 996 $aCatalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene$91563135 997 $aUNINA