|
|
|
|
|
|
|
|
1. |
Record Nr. |
UNINA9910159532203321 |
|
|
Autore |
Hou Ruijun |
|
|
Titolo |
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene / / by Ruijun Hou |
|
|
|
|
|
|
|
Pubbl/distr/stampa |
|
|
Singapore : , : Springer Singapore : , : Imprint : Springer, , 2017 |
|
|
|
|
|
|
|
ISBN |
|
|
|
|
|
|
Edizione |
[1st ed. 2017.] |
|
|
|
|
|
Descrizione fisica |
|
1 online resource (XII, 141 p. 83 illus., 42 illus. in color.) |
|
|
|
|
|
|
Collana |
|
Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5053 |
|
|
|
|
|
|
|
|
Disciplina |
|
|
|
|
|
|
Soggetti |
|
Catalysis |
Chemistry, Physical and theoretical |
Chemical engineering |
Organic chemistry |
Theoretical and Computational Chemistry |
Industrial Chemistry/Chemical Engineering |
Organic Chemistry |
|
|
|
|
|
|
|
|
Lingua di pubblicazione |
|
|
|
|
|
|
Formato |
Materiale a stampa |
|
|
|
|
|
Livello bibliografico |
Monografia |
|
|
|
|
|
Note generali |
|
"Doctoral Thesis accepted by Tsinghua University, Beijing, China"--Title page. |
|
|
|
|
|
|
|
|
Nota di bibliografia |
|
Includes bibliographical references at the end of each chapters. |
|
|
|
|
|
|
Nota di contenuto |
|
Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion. |
|
|
|
|
|
|
|
|
Sommario/riassunto |
|
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, |
|
|
|
|