03497nam 22006495 450 991015953220332120250616090252.0978981100773610.1007/978-981-10-0773-6(CKB)3710000001008960(DE-He213)978-981-10-0773-6(MiAaPQ)EBC4777491(PPN)198338678(EXLCZ)99371000000100896020170105d2017 u| 0engurnn|008mamaatxtrdacontentcrdamediacrrdacarrierCatalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene /by Ruijun Hou1st ed. 2017.Singapore :Springer Nature Singapore :Imprint: Springer,2017.1 online resource (XII, 141 p. 83 illus., 42 illus. in color.) Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061"Doctoral Thesis accepted by Tsinghua University, Beijing, China"--Title page.981-10-0772-1 981-10-0773-X Includes bibliographical references at the end of each chapters.Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion.This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061CatalysisChemistry, Physical and theoreticalChemistry, TechnicalChemistry, OrganicCatalysisTheoretical ChemistryIndustrial ChemistryOrganic ChemistryCatalysis.Chemistry, Physical and theoretical.Chemistry, Technical.Chemistry, Organic.Catalysis.Theoretical Chemistry.Industrial Chemistry.Organic Chemistry.547.23Hou Ruijunauthttp://id.loc.gov/vocabulary/relators/aut767662MiAaPQMiAaPQMiAaPQBOOK9910159532203321Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene1563135UNINA