Iridium complexes in organic synthesis [[electronic resource] /] / edited by Luis A. Oro and Carmen Claver

• Pubblicazione: Weinheim, : Wiley-VCH, c2009
• Descrizione fisica: 1 online resource (xvii, 396 pages) : illustrations (some color)
• Disciplina: 547.215
• Soggetto topico: Organic compounds - Synthesis; Iridium catalysts; Asymmetric synthesis
• Altri autori: OroLuis A ClaverCarmen
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation ; 1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand? ; 2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity ; 3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction ; 5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols ; 5.6.4 Amidation of Alcohols with Hydroxylamine
• Sommario/riassunto: Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis.A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
• Titolo autorizzato: Iridium complexes in organic synthesis
• ISBN: 1-282-02533-3; 9786612025334; 3-527-62307-8; 3-527-62308-6
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910830692603321
• Lo trovi qui: Univ. Federico II