05137nam 2200649Ia 450 991083069260332120221206105042.01-282-02533-397866120253343-527-62307-83-527-62308-6(CKB)1000000000707511(EBL)481579(OCoLC)441886919(SSID)ssj0000183753(PQKBManifestationID)11170424(PQKBTitleCode)TC0000183753(PQKBWorkID)10195912(PQKB)11650923(MiAaPQ)EBC481579(PPN)160584868(EXLCZ)99100000000070751120080902d2009 uy 0engurcn|||||||||txtccrIridium complexes in organic synthesis[electronic resource] /edited by Luis A. Oro and Carmen ClaverWeinheim Wiley-VCHc20091 online resource (xvii, 396 pages) illustrations (some color)3-527-31996-4 Includes bibliographical references and index.Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand?2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols5.6.4 Amidation of Alcohols with HydroxylamineRanging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis.A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.Organic compoundsSynthesisIridium catalystsAsymmetric synthesisOrganic compoundsSynthesis.Iridium catalysts.Asymmetric synthesis.547.215Oro Luis A1603145Claver Carmen1603146John Wiley & Sons.MiAaPQMiAaPQMiAaPQBOOK9910830692603321Iridium complexes in organic synthesis3927401UNINA