LEADER 05137nam 2200649Ia 450 001 9910830692603321 005 20221206105042.0 010 $a1-282-02533-3 010 $a9786612025334 010 $a3-527-62307-8 010 $a3-527-62308-6 035 $a(CKB)1000000000707511 035 $a(EBL)481579 035 $a(OCoLC)441886919 035 $a(SSID)ssj0000183753 035 $a(PQKBManifestationID)11170424 035 $a(PQKBTitleCode)TC0000183753 035 $a(PQKBWorkID)10195912 035 $a(PQKB)11650923 035 $a(MiAaPQ)EBC481579 035 $a(PPN)160584868 035 $a(EXLCZ)991000000000707511 100 $a20080902d2009 uy 0 101 0 $aeng 135 $aurcn||||||||| 181 $ctxt 182 $cc 183 $acr 200 00$aIridium complexes in organic synthesis$b[electronic resource] /$fedited by Luis A. Oro and Carmen Claver 210 $aWeinheim $cWiley-VCH$dc2009 215 $a1 online resource (xvii, 396 pages) $cillustrations (some color) 311 $a3-527-31996-4 320 $aIncludes bibliographical references and index. 327 $aIridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation 327 $a1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand? 327 $a2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity 327 $a3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction 327 $a5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols 327 $a5.6.4 Amidation of Alcohols with Hydroxylamine 330 $aRanging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis.A must for organic, complex and catalytic chemists, as well as those working with/on organometallics. 606 $aOrganic compounds$xSynthesis 606 $aIridium catalysts 606 $aAsymmetric synthesis 615 0$aOrganic compounds$xSynthesis. 615 0$aIridium catalysts. 615 0$aAsymmetric synthesis. 676 $a547.215 701 $aOro$b Luis A$01603145 701 $aClaver$b Carmen$01603146 712 02$aJohn Wiley & Sons. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910830692603321 996 $aIridium complexes in organic synthesis$93927401 997 $aUNINA