MWW-Type Titanosilicate : Synthesis, Structural Modification and Catalytic Applications to Green Oxidations / / by Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He

• Autore: Wu Peng
• Pubblicazione: Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2013
• Edizione: 1st ed. 2013.
• Descrizione fisica: 1 online resource (viii, 125 pages) : illustrations (some color)
• Disciplina: 541
• Soggetto topico: Catalysis; Environmental chemistry; Chemistry, Technical; Physical chemistry; Environmental Chemistry; Industrial Chemistry; Physical Chemistry
• Note generali: "ISSN: 2212-9898."
• Nota di bibliografia: Includes bibliographical references.
• Nota di contenuto: Introduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects.
• Sommario/riassunto: This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
• Titolo autorizzato: MWW-Type Titanosilicate
• ISBN: 9783642391156; 364239115X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910437822103321
• Lo trovi qui: Univ. Federico II
• Serie: SpringerBriefs in Green Chemistry for Sustainability, . 2452-185X