03600nam 22006975 450 991043782210332120251113195627.09783642391156364239115X10.1007/978-3-642-39115-6(PPN)172427649(OCoLC)857224137(MiFhGG)GVRL6WIA(CKB)3710000000015871(MiAaPQ)EBC1398823(MiFhGG)9783642391156(DE-He213)978-3-642-39115-6(EXLCZ)99371000000001587120130804d2013 u| 0engurun#---uuuuatxtccrMWW-Type Titanosilicate Synthesis, Structural Modification and Catalytic Applications to Green Oxidations /by Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He1st ed. 2013.Berlin, Heidelberg :Springer Berlin Heidelberg :Imprint: Springer,2013.1 online resource (viii, 125 pages) illustrations (some color)SpringerBriefs in Green Chemistry for Sustainability,2452-185X"ISSN: 2212-9898."9783642391149 3642391141 Includes bibliographical references.Introduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects.This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.SpringerBriefs in Green Chemistry for Sustainability,2452-185XCatalysisEnvironmental chemistryChemistry, TechnicalChemistry, Physical and theoreticalCatalysisEnvironmental ChemistryIndustrial ChemistryPhysical ChemistryCatalysis.Environmental chemistry.Chemistry, Technical.Chemistry, Physical and theoretical.Catalysis.Environmental Chemistry.Industrial Chemistry.Physical Chemistry.541Wu Peng1058437MiAaPQMiAaPQMiAaPQBOOK9910437822103321MWW-Type Titanosilicate2532851UNINA