LEADER 03041oam 2200529 450 001 9910437822103321 005 20190911112726.0 010 $a3-642-39115-X 024 7 $a10.1007/978-3-642-39115-6 035 $a(OCoLC)857224137 035 $a(MiFhGG)GVRL6WIA 035 $a(EXLCZ)993710000000015871 100 $a20130716d2013 uy 0 101 0 $aeng 135 $aurun|---uuuua 181 $ctxt 182 $cc 183 $acr 200 10$aMWW-type titanosilicate $esynthesis, structural modification and catalytic applications to green oxidations /$fPeng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He 205 $a1st ed. 2013. 210 1$aHeidelberg [Germany] :$cSpringer,$d2013. 215 $a1 online resource (viii, 125 pages) $cillustrations (some color) 225 1 $aSpringerBriefs in Green Chemistry for Sustainability,$x2212-9898 300 $a"ISSN: 2212-9898." 311 $a3-642-39114-1 320 $aIncludes bibliographical references. 327 $aIntroduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects. 330 $aThis book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta. 410 0$aSpringerBriefs in molecular science.$pGreen chemistry for sustainability. 606 $aSilicates 606 $aZeolites 606 $aGreen chemistry 615 0$aSilicates. 615 0$aZeolites. 615 0$aGreen chemistry. 676 $a541 700 $aWu$b Peng$4aut$4http://id.loc.gov/vocabulary/relators/aut$01058437 702 $aXu$b Hao 702 $aXu$b Le 702 $aLiu$b Yueming 702 $aHe$b Mingyuan 801 0$bMiFhGG 801 1$bMiFhGG 906 $aBOOK 912 $a9910437822103321 996 $aMWW-Type Titanosilicate$92532851 997 $aUNINA