State-to-state dynamical research in the F+H2 reaction system / / Zefeng Ren

• Autore: Ren Zefeng
• Pubblicazione: Heidelberg [Germany] : , : Springer, , 2014
• Edizione: 1st ed. 2014.
• Descrizione fisica: 1 online resource (xii, 77 pages) : illustrations (some color)
• Disciplina: 538; 539
• Soggetto topico: Chemical reactions; Hydrogen; Rydberg states
• Note generali: "ISSN: 2190-5053."
• Nota di bibliografia: Includes bibliographical references.
• Nota di contenuto: Introduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2→DF+D.
• Sommario/riassunto: This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. .
• Titolo autorizzato: State-to-State Dynamical Research in the F+H2 Reaction System
• ISBN: 3-642-39756-5
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910298637903321
• Lo trovi qui: Univ. Federico II
• Serie: Springer theses.