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[null,"1.","Record Nr.",null,"UNINA9910298637903321"]
[null,null,"Autore",null,"Ren Zefeng"]
[null,null,"Titolo",null,"State-to-state dynamical research in the F+H2 reaction system / / Zefeng Ren"]
[null,null,"Pubbl/distr/stampa",null,"Heidelberg [Germany] : , : Springer, , 2014"]
[null,null,"ISBN",null,"3-642-39756-5"]
[null,null,"Edizione",null,"[1st ed. 2014.]"]
[null,null,"Descrizione fisica",null,"1 online resource (xii, 77 pages) : illustrations (some color)"]
[null,null,"Collana",null,"Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5053"]
[null,null,"Disciplina",null,"538"]
[{"$nulls":4},"539"]
[null,null,"Soggetti",null,"Chemical reactions"]
[{"$nulls":4},"Hydrogen"]
[{"$nulls":4},"Rydberg states"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","\"ISSN: 2190-5053.\""]
[null,null,null,"Nota di bibliografia","Includes bibliographical references."]
[null,null,"Nota di contenuto",null,"Introduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2→DF+D."]
[null,null,null,"Sommario/riassunto","This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg \"tagging\" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. ."]