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010   $a3-642-39756-5
024 7 $a10.1007/978-3-642-39756-1
035   $a(OCoLC)865508052
035   $a(MiFhGG)GVRL6XDC
035   $a(EXLCZ)993710000000074273
100   $a20130726d2014      uy             0
101 0 $aeng
135   $aurun|---uuuua
181   $ctxt
182   $cc
183   $acr
200 10$aState-to-state dynamical research in the F+H2 reaction system /$fZefeng Ren
205   $a1st ed. 2014.
210  1$aHeidelberg [Germany] :$cSpringer,$d2014.
215   $a1 online resource (xii, 77 pages) $cillustrations (some color)
225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053
300   $a"ISSN: 2190-5053."
311   $a3-642-39755-7 
320   $aIncludes bibliographical references.
327   $aIntroduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2?DF+D.
330   $aThis thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. .
410  0$aSpringer theses.
606   $aChemical reactions
606   $aHydrogen
606   $aRydberg states
615  0$aChemical reactions.
615  0$aHydrogen.
615  0$aRydberg states.
676   $a538
676   $a539
700   $aRen$b Zefeng$4aut$4http://id.loc.gov/vocabulary/relators/aut$01063198
801  0$bMiFhGG
801  1$bMiFhGG
906   $aBOOK
912   $a9910298637903321
996   $aState-to-State Dynamical Research in the F+H2 Reaction System$92530914
997   $aUNINA