Vai al contenuto principale della pagina
Autore: | Ren Zefeng |
Titolo: | State-to-state dynamical research in the F+H2 reaction system / / Zefeng Ren |
Pubblicazione: | Heidelberg [Germany] : , : Springer, , 2014 |
Edizione: | 1st ed. 2014. |
Descrizione fisica: | 1 online resource (xii, 77 pages) : illustrations (some color) |
Disciplina: | 538 |
539 | |
Soggetto topico: | Chemical reactions |
Hydrogen | |
Rydberg states | |
Note generali: | "ISSN: 2190-5053." |
Nota di bibliografia: | Includes bibliographical references. |
Nota di contenuto: | Introduction -- Hydrogen Atom Rydberg Tagging Time-of-Flight Crossed Molecular Beam Apparatus -- Dynamical Resonances in F+H2 Reactions -- The Non-Adiabatic Effects in F(2P)+D2→DF+D. |
Sommario/riassunto: | This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. . |
Titolo autorizzato: | State-to-State Dynamical Research in the F+H2 Reaction System |
ISBN: | 3-642-39756-5 |
Formato: | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione: | Inglese |
Record Nr.: | 9910298637903321 |
Lo trovi qui: | Univ. Federico II |
Opac: | Controlla la disponibilità qui |