Heterogeneous catalysts for clean technology : spectroscopy, design, and monitoring / / edited by Karen Wilson and Adam F. Lee

• Pubblicazione: Weinheim : , : Wiley-VCH, , [2014]; ©2014
• Descrizione fisica: 1 online resource (502 p.)
• Disciplina: 660.2995
• Soggetto topico: Heterogeneous catalysis; Heterogeneous catalysis - Industrial applications
• Altri autori: WilsonKaren LeeAdam F
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Heterogeneous Catalysts for Clean Technology; Title Page; Copyright; Contents; Preface; List of Contributors; Chapter 1 Introduction to Clean Technology and Catalysis; 1.1 Green Chemistry and Clean Technology; 1.1.1 Ideals of Green Chemistry; 1.2 Green Chemistry Metrics; 1.3 Alternative Solvents; 1.4 Heterogeneous or Homogeneous; 1.5 Alternative Energy Reactors for Green Chemistry; 1.5.1 Microchannel Reactors; 1.5.2 Microwave Reactors; 1.6 Concluding Remarks; References; Chapter 2 Mechanistic Studies of Alcohol Selective Oxidation; 2.1 Introduction; 2.1.1 Applications of Selective Oxidation ; 2.1.2 Oxidant Considerations2.2 Metal-Catalyzed Alcohol Selox; 2.2.1 Monometallic Catalysts; 2.2.2 Bimetallic Selox Catalysts; 2.2.3 Support Effects; 2.3 Oxide, Sulfide, and Vanadate Catalysts; 2.4 Solvent Selection; 2.4.1 Supercritical Fluids; 2.4.2 Ionic Liquids and Water; 2.5 In Situ and Operando X-Ray Studies of Selox Catalysts; 2.5.1 X-Ray Absorption Spectroscopy; 2.5.2 X-Ray Photoelectron Spectroscopy; 2.6 Conclusions; References; Chapter 3 Reaction Monitoring in Multiphase Systems: Application of Coupled In Situ Spectroscopic Techniques in Organic Synthesis; 3.1 Introduction ; 3.2 Method Coupling3.3 Spectroscopic Reactors and Practical Aspects; 3.4 Selected Examples of Use; 3.4.1 Heterogeneously Catalyzed Hydrogenation of Imines; 3.4.2 Three-Phase Hydrogenation of Nitrobenzene over Nanosized Au on TiO2; 3.4.3 Elucidating the Mechanism of Cu(II)-Catalyzed Arylation of Imidazole and Phenylboronic Acid by a Multitechnique Approach; 3.5 Conclusion and Outlook; References; Chapter 4 In Situ Studies on Photocatalytic Materials, Surface Intermediates, and Reaction Mechanisms; 4.1 Introduction; 4.2 In Situ Investigations; 4.2.1 FTIR; 4.2.1.1 NOx Depollution ; 4.2.1.2 Hydrocarbon Oxidation4.2.1.3 Oxidation of Oxygen-Containing Compounds; 4.2.2 EPR; 4.2.2.1 Semiconductor Charge Separation and Transfer; 4.2.2.2 Reactive Oxygen Species; 4.2.2.3 Local Structure of Active Sites; 4.2.3 XPS; 4.2.4 XAFS and UV Vis; 4.2.5 NMR; 4.2.6 Other Methods; 4.3 Concluding Remarks; References; Chapter 5 Enantioselective Heterogeneous Catalysis; 5.1 Introduction; 5.2 Strategies for the Creation of Enantioselective Heterogeneous Catalysts; 5.2.1 Immobilization of Homogeneous or Enzyme Catalysts; 5.2.1.1 Covalent Tethering ; 5.2.1.1.1 Covalent Immobilization on Inorganic Supports5.2.1.1.2 Covalent Immobilization on Polymeric Resins; 5.2.1.1.3 Covalent Immobilization by Copolymerization; 5.2.1.2 Immobilization by Encapsulation; 5.2.1.2.1 Construction of Catalyst within the Pores of a Support; 5.2.1.2.2 Construction of Support around the Catalyst; 5.2.1.3 Immobilization by Electrostatic Interactions; 5.2.1.4 Industrial Application of Immobilized Catalysts; 5.2.2 Use of Chiral Solids; 5.2.2.1 Metal or Metal Oxide on a Chiral Support; 5.2.2.2 Chiral Zeolites; 5.2.2.3 Chiral Metal-Organic Catalysts ; 5.2.3 Chirally Modified Metal Surfaces
• Sommario/riassunto: This ready reference and handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology in a single volume.As such, it focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid the design of catalysts for use in liquid phase reactions, their application in industrially important chemistries -- including selective oxidation, hydrogenation, solid acid and base catalyzed processes ? as well as the role of process intensification and use of renewable resources in improving
• Titolo autorizzato: Heterogeneous catalysts for clean technology
• ISBN: 3-527-65900-5; 3-527-65898-X; 3-527-65901-3
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910824405303321
• Lo trovi qui: Univ. Federico II