LEADER 05295nam 2200613 450 001 9910824405303321 005 20200520144314.0 010 $a3-527-65900-5 010 $a3-527-65898-X 010 $a3-527-65901-3 035 $a(CKB)2550000001123271 035 $a(EBL)1407871 035 $a(OCoLC)858968879 035 $a(MiAaPQ)EBC1407871 035 $a(Au-PeEL)EBL1407871 035 $a(CaPaEBR)ebr10766993 035 $a(CaONFJC)MIL521991 035 $a(PPN)190220198 035 $a(EXLCZ)992550000001123271 100 $a20131011h20142014 uy| 0 101 0 $aeng 135 $aur|n|---||||| 181 $2rdacontent 182 $2rdamedia 183 $2rdacarrier 200 00$aHeterogeneous catalysts for clean technology $espectroscopy, design, and monitoring /$fedited by Karen Wilson and Adam F. Lee 210 1$aWeinheim :$cWiley-VCH,$d[2014] 210 4$dİ2014 215 $a1 online resource (502 p.) 300 $aDescription based upon print version of record. 311 $a3-527-33213-8 311 $a1-299-90740-7 320 $aIncludes bibliographical references and index. 327 $aHeterogeneous Catalysts for Clean Technology; Title Page; Copyright; Contents; Preface; List of Contributors; Chapter 1 Introduction to Clean Technology and Catalysis; 1.1 Green Chemistry and Clean Technology; 1.1.1 Ideals of Green Chemistry; 1.2 Green Chemistry Metrics; 1.3 Alternative Solvents; 1.4 Heterogeneous or Homogeneous; 1.5 Alternative Energy Reactors for Green Chemistry; 1.5.1 Microchannel Reactors; 1.5.2 Microwave Reactors; 1.6 Concluding Remarks; References; Chapter 2 Mechanistic Studies of Alcohol Selective Oxidation; 2.1 Introduction; 2.1.1 Applications of Selective Oxidation 327 $a2.1.2 Oxidant Considerations2.2 Metal-Catalyzed Alcohol Selox; 2.2.1 Monometallic Catalysts; 2.2.2 Bimetallic Selox Catalysts; 2.2.3 Support Effects; 2.3 Oxide, Sulfide, and Vanadate Catalysts; 2.4 Solvent Selection; 2.4.1 Supercritical Fluids; 2.4.2 Ionic Liquids and Water; 2.5 In Situ and Operando X-Ray Studies of Selox Catalysts; 2.5.1 X-Ray Absorption Spectroscopy; 2.5.2 X-Ray Photoelectron Spectroscopy; 2.6 Conclusions; References; Chapter 3 Reaction Monitoring in Multiphase Systems: Application of Coupled In Situ Spectroscopic Techniques in Organic Synthesis; 3.1 Introduction 327 $a3.2 Method Coupling3.3 Spectroscopic Reactors and Practical Aspects; 3.4 Selected Examples of Use; 3.4.1 Heterogeneously Catalyzed Hydrogenation of Imines; 3.4.2 Three-Phase Hydrogenation of Nitrobenzene over Nanosized Au on TiO2; 3.4.3 Elucidating the Mechanism of Cu(II)-Catalyzed Arylation of Imidazole and Phenylboronic Acid by a Multitechnique Approach; 3.5 Conclusion and Outlook; References; Chapter 4 In Situ Studies on Photocatalytic Materials, Surface Intermediates, and Reaction Mechanisms; 4.1 Introduction; 4.2 In Situ Investigations; 4.2.1 FTIR; 4.2.1.1 NOx Depollution 327 $a4.2.1.2 Hydrocarbon Oxidation4.2.1.3 Oxidation of Oxygen-Containing Compounds; 4.2.2 EPR; 4.2.2.1 Semiconductor Charge Separation and Transfer; 4.2.2.2 Reactive Oxygen Species; 4.2.2.3 Local Structure of Active Sites; 4.2.3 XPS; 4.2.4 XAFS and UV Vis; 4.2.5 NMR; 4.2.6 Other Methods; 4.3 Concluding Remarks; References; Chapter 5 Enantioselective Heterogeneous Catalysis; 5.1 Introduction; 5.2 Strategies for the Creation of Enantioselective Heterogeneous Catalysts; 5.2.1 Immobilization of Homogeneous or Enzyme Catalysts; 5.2.1.1 Covalent Tethering 327 $a5.2.1.1.1 Covalent Immobilization on Inorganic Supports5.2.1.1.2 Covalent Immobilization on Polymeric Resins; 5.2.1.1.3 Covalent Immobilization by Copolymerization; 5.2.1.2 Immobilization by Encapsulation; 5.2.1.2.1 Construction of Catalyst within the Pores of a Support; 5.2.1.2.2 Construction of Support around the Catalyst; 5.2.1.3 Immobilization by Electrostatic Interactions; 5.2.1.4 Industrial Application of Immobilized Catalysts; 5.2.2 Use of Chiral Solids; 5.2.2.1 Metal or Metal Oxide on a Chiral Support; 5.2.2.2 Chiral Zeolites; 5.2.2.3 Chiral Metal-Organic Catalysts 327 $a5.2.3 Chirally Modified Metal Surfaces 330 $aThis ready reference and handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology in a single volume.As such, it focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid the design of catalysts for use in liquid phase reactions, their application in industrially important chemistries -- including selective oxidation, hydrogenation, solid acid and base catalyzed processes ? as well as the role of process intensification and use of renewable resources in improving 606 $aHeterogeneous catalysis 606 $aHeterogeneous catalysis$xIndustrial applications 615 0$aHeterogeneous catalysis. 615 0$aHeterogeneous catalysis$xIndustrial applications. 676 $a660.2995 701 $aWilson$b Karen$01722221 701 $aLee$b Adam F$01722222 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910824405303321 996 $aHeterogeneous catalysts for clean technology$94122418 997 $aUNINA