Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties [[electronic resource] /] / by Mingoo Jin

• Autore: Jin Mingoo
• Pubblicazione: Singapore : , : Springer Singapore : , : Imprint : Springer, , 2020
• Edizione: 1st ed. 2020.
• Descrizione fisica: 1 online resource (200 pages)
• Disciplina: 541.35
• Soggetto topico: Organometallic chemistry ; Optical materials; Electronic materials; Physical chemistry; Inorganic chemistry; Organometallic Chemistry; Optical and Electronic Materials; Physical Chemistry; Inorganic Chemistry; Luminescència
• Soggetto genere / forma: Llibres electrònics
• Nota di contenuto: 1. General Introduction -- 2. Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) -- 3. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety -- 4. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups -- 5. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color -- 6. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphane-Gold(I) Complex -- 7. Conclusion.
• Sommario/riassunto: This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies. .
• Titolo autorizzato: Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties
• ISBN: 981-15-4063-2
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910410046603321
• Lo trovi qui: Univ. Federico II
• Serie: Springer Theses, Recognizing Outstanding Ph.D. Research, . 2190-5053