04556nam 22006735 450 991041004660332120230918140412.0981-15-4063-210.1007/978-981-15-4063-9(CKB)4100000011208559(MiAaPQ)EBC6178570(DE-He213)978-981-15-4063-9(PPN)243761929(EXLCZ)99410000001120855920200418d2020 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierNovel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties[electronic resource] /by Mingoo Jin1st ed. 2020.Singapore :Springer Singapore :Imprint: Springer,2020.1 online resource (200 pages)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053981-15-4062-4 1. General Introduction -- 2. Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) -- 3. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety -- 4. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups -- 5. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color -- 6. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphane-Gold(I) Complex -- 7. Conclusion.This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies. .Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053Organometallic chemistry Optical materialsElectronic materialsPhysical chemistryInorganic chemistryOrganometallic Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C19020Optical and Electronic Materialshttps://scigraph.springernature.com/ontologies/product-market-codes/Z12000Physical Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C21001Inorganic Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C16008LuminescènciathubLlibres electrònicsthubOrganometallic chemistry .Optical materials.Electronic materials.Physical chemistry.Inorganic chemistry.Organometallic Chemistry.Optical and Electronic Materials.Physical Chemistry.Inorganic Chemistry.Luminescència541.35Jin Mingooauthttp://id.loc.gov/vocabulary/relators/aut1060592MiAaPQMiAaPQMiAaPQBOOK9910410046603321Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties2514382UNINA