LEADER 04529nam 22006735 450 001 9910410046603321 005 20230918140412.0 010 $a981-15-4063-2 024 7 $a10.1007/978-981-15-4063-9 035 $a(CKB)4100000011208559 035 $a(MiAaPQ)EBC6178570 035 $a(DE-He213)978-981-15-4063-9 035 $a(PPN)243761929 035 $a(EXLCZ)994100000011208559 100 $a20200418d2020 u| 0 101 0 $aeng 135 $aurcnu|||||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aNovel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties /$fby Mingoo Jin 205 $a1st ed. 2020. 210 1$aSingapore :$cSpringer Singapore :$cImprint: Springer,$d2020. 215 $a1 online resource (200 pages) 225 1 $aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 311 $a981-15-4062-4 327 $a1. General Introduction -- 2. Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) -- 3. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety -- 4. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups -- 5. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color -- 6. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphane-Gold(I) Complex -- 7. Conclusion. 330 $aThis book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals? chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies. . 410 0$aSpringer Theses, Recognizing Outstanding Ph.D. Research,$x2190-5053 606 $aOrganometallic chemistry  606 $aOptical materials 606 $aElectronic materials 606 $aPhysical chemistry 606 $aInorganic chemistry 606 $aOrganometallic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C19020 606 $aOptical and Electronic Materials$3https://scigraph.springernature.com/ontologies/product-market-codes/Z12000 606 $aPhysical Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C21001 606 $aInorganic Chemistry$3https://scigraph.springernature.com/ontologies/product-market-codes/C16008 606 $aLuminescència$2thub 608 $aLlibres electrònics$2thub 615 0$aOrganometallic chemistry . 615 0$aOptical materials. 615 0$aElectronic materials. 615 0$aPhysical chemistry. 615 0$aInorganic chemistry. 615 14$aOrganometallic Chemistry. 615 24$aOptical and Electronic Materials. 615 24$aPhysical Chemistry. 615 24$aInorganic Chemistry. 615 7$aLuminescència 676 $a541.35 700 $aJin$b Mingoo$4aut$4http://id.loc.gov/vocabulary/relators/aut$01060592 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910410046603321 996 $aNovel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties$92514382 997 $aUNINA