Integrated chemical processes [[electronic resource] ] : synthesis, operation, analysis, and control / / edited by Kai Sundmacher, Achim Kienle and Andreas Seidel-Morgenstern

• Pubblicazione: Weinheim, : Wiley-VCH, c2005
• Descrizione fisica: 1 online resource (568 p.)
• Disciplina: 660.284
• Soggetto topico: Chemical processes; Chemical reactions
• Altri autori: KienleAchim Seidel-MorgensternAndreas SundmacherKai
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Integrated Chemical Processes; Contents; Preface; List of Contributors; Part I Integration of Heat Transfer and Chemical Reactions; 1 Enhancing Productivity and Thermal Efficiency of High-Temperature Endothermic Processes in Heat-Integrated Fixed-Bed Reactors; Abstract; 1.1 Introduction; 1.2 Heat-Integrated Processes for Endothermic Reactions; 1.2.1 Optimality Conditions; 1.2.1.1 Efficiency of Heat Recovery; 1.2.1.2 Temperature Control; 1.3 Multifunctional Reactor Concepts; 1.3.1 Regenerative Processes; 1.3.1.1 Simultaneous Mode; 1.3.1.2 Asymmetric Mode ; 1.3.1.3 Symmetric Mode with Side Stream Injection1.3.1.4 Counter-cocurrent Mode; 1.3.1.5 Overheating During Oxidative Coke Removal; 1.3.2 Recuperative Processes; 1.3.2.1 Processes for Large-Scale Applications; 1.3.2.2 Processes for Small-scale Applications; 1.4 Conclusions; Symbols and Abbreviations; References; 2 Conceptual Design of Internal Reforming in High-Temperature Fuel Cells; 2.1 Introduction; 2.2 Technical Background; 2.3 Modeling; 2.3.1 Model Derivation; 2.3.1.1 Anode Channel; 2.3.1.2 Mixing Rules; 2.3.1.3 Cathode Channel; 2.3.1.4 Reaction Kinetics; 2.3.1.5 Cell Power ; 2.3.2 Conversion Diagram2.4 Applications; 2.4.1 Comparison of Reforming Concepts; 2.4.2 Anode Cascade; 2.4.3 Anode Exhaust Gas Recycling; 2.5 Summary and Conclusions; Symbols; References; 3 Instabilities in High-Temperature Fuel Cells due to Combined Heat and Charge Transport; 3.1 Introduction; 3.2 Modeling; 3.2.1 Model Assumptions; 3.2.2 Model Equations; 3.2.3 Simplified Model; 3.3 Potentiostatic Operation; 3.3.1 Cell with Infinite Length; 3.3.2 Cell with Finite Length; 3.4 Galvanostatic Operation; 3.5 Conclusions; Symbols ; Appendix: Numerical Methods for the Bifurcation Analysis in Section 3.0References; Part II Integration of Separations and Chemical Reactions; 4 Thermodynamic and Kinetic Effects on the Feasible Products of Reactive Distillation: A-zeo-tropes and A-rheo-tropes; 4.1 Introduction; 4.2 Azeotropes; 4.2.1 Reactive Condenser and Reboiler; 4.2.2 Conditions for Singular Points; 4.2.2.1 Potential Singular Point Surface; 4.2.2.2 Reaction Kinetic Surface; 4.2.3 Examples; 4.2.3.1 Hypothetical Ternary Systems; 4.2.3.2 Real Ternary System: MTBE-Synthesis ; 4.2.3.3 Real Ternary System with Phase Splitting: Methanol Dehydration4.2.3.4 Real Quaternary System: Isopropyl Acetate Hydrolysis; 4.2.4 Application of Feasibility Diagram: Column Feasible Split; 4.2.5 Remarks on Azeotropes; 4.3 Arheotropes; 4.3.1 Definition and Conditions; 4.3.2 Illustrative Examples; 4.3.2.1 Example 1: Stagnant Sweep Gas; 4.3.2.2 Example 2: Flowing Sweep Gas; 4.3.2.3 Example 3: Flowing Sweep Gas with Pervaporation; 4.3.2.4 Example 4: Reactive Liquid Mixture; 4.3.3 Remarks on Arheotropes; 4.4 Kinetic Arheotropes in Reactive Membrane Separation; 4.4.1 Model Formulation ; 4.4.1.1 Reaction Kinetics and Mass Balances
• Sommario/riassunto: This is the first book dedicated to the entire field of integrated chemical processes, covering process design, analysis, operation and control of these processes. Both the editors and authors are internationally recognized experts from different fields in industry and academia, and their contributions describe all aspects of intelligent integrations of chemical reactions and physical unit operations such as heat exchange, separational operations and mechanical unit operations. As a unique feature, the book also introduces new concepts for treating different integration concepts on a generaliz
• Titolo autorizzato: Integrated chemical processes
• ISBN: 1-280-52061-2; 9786610520619; 3-527-60573-8; 3-527-60555-X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910841527303321
• Lo trovi qui: Univ. Federico II