LEADER 05234nam 2200625Ia 450 001 9910841527303321 005 20230617040620.0 010 $a1-280-52061-2 010 $a9786610520619 010 $a3-527-60573-8 010 $a3-527-60555-X 035 $a(CKB)1000000000376048 035 $a(EBL)481490 035 $a(OCoLC)68964075 035 $a(SSID)ssj0000180256 035 $a(PQKBManifestationID)11197687 035 $a(PQKBTitleCode)TC0000180256 035 $a(PQKBWorkID)10149549 035 $a(PQKB)10446774 035 $a(MiAaPQ)EBC481490 035 $a(EXLCZ)991000000000376048 100 $a20040621d2005 fy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aIntegrated chemical processes$b[electronic resource] $esynthesis, operation, analysis, and control /$fedited by Kai Sundmacher, Achim Kienle and Andreas Seidel-Morgenstern 210 $aWeinheim $cWiley-VCH$dc2005 215 $a1 online resource (568 p.) 300 $aDescription based upon print version of record. 311 $a3-527-30831-8 320 $aIncludes bibliographical references and index. 327 $aIntegrated Chemical Processes; Contents; Preface; List of Contributors; Part I Integration of Heat Transfer and Chemical Reactions; 1 Enhancing Productivity and Thermal Efficiency of High-Temperature Endothermic Processes in Heat-Integrated Fixed-Bed Reactors; Abstract; 1.1 Introduction; 1.2 Heat-Integrated Processes for Endothermic Reactions; 1.2.1 Optimality Conditions; 1.2.1.1 Efficiency of Heat Recovery; 1.2.1.2 Temperature Control; 1.3 Multifunctional Reactor Concepts; 1.3.1 Regenerative Processes; 1.3.1.1 Simultaneous Mode; 1.3.1.2 Asymmetric Mode 327 $a1.3.1.3 Symmetric Mode with Side Stream Injection1.3.1.4 Counter-cocurrent Mode; 1.3.1.5 Overheating During Oxidative Coke Removal; 1.3.2 Recuperative Processes; 1.3.2.1 Processes for Large-Scale Applications; 1.3.2.2 Processes for Small-scale Applications; 1.4 Conclusions; Symbols and Abbreviations; References; 2 Conceptual Design of Internal Reforming in High-Temperature Fuel Cells; 2.1 Introduction; 2.2 Technical Background; 2.3 Modeling; 2.3.1 Model Derivation; 2.3.1.1 Anode Channel; 2.3.1.2 Mixing Rules; 2.3.1.3 Cathode Channel; 2.3.1.4 Reaction Kinetics; 2.3.1.5 Cell Power 327 $a2.3.2 Conversion Diagram2.4 Applications; 2.4.1 Comparison of Reforming Concepts; 2.4.2 Anode Cascade; 2.4.3 Anode Exhaust Gas Recycling; 2.5 Summary and Conclusions; Symbols; References; 3 Instabilities in High-Temperature Fuel Cells due to Combined Heat and Charge Transport; 3.1 Introduction; 3.2 Modeling; 3.2.1 Model Assumptions; 3.2.2 Model Equations; 3.2.3 Simplified Model; 3.3 Potentiostatic Operation; 3.3.1 Cell with Infinite Length; 3.3.2 Cell with Finite Length; 3.4 Galvanostatic Operation; 3.5 Conclusions; Symbols 327 $aAppendix: Numerical Methods for the Bifurcation Analysis in Section 3.0References; Part II Integration of Separations and Chemical Reactions; 4 Thermodynamic and Kinetic Effects on the Feasible Products of Reactive Distillation: A-zeo-tropes and A-rheo-tropes; 4.1 Introduction; 4.2 Azeotropes; 4.2.1 Reactive Condenser and Reboiler; 4.2.2 Conditions for Singular Points; 4.2.2.1 Potential Singular Point Surface; 4.2.2.2 Reaction Kinetic Surface; 4.2.3 Examples; 4.2.3.1 Hypothetical Ternary Systems; 4.2.3.2 Real Ternary System: MTBE-Synthesis 327 $a4.2.3.3 Real Ternary System with Phase Splitting: Methanol Dehydration4.2.3.4 Real Quaternary System: Isopropyl Acetate Hydrolysis; 4.2.4 Application of Feasibility Diagram: Column Feasible Split; 4.2.5 Remarks on Azeotropes; 4.3 Arheotropes; 4.3.1 Definition and Conditions; 4.3.2 Illustrative Examples; 4.3.2.1 Example 1: Stagnant Sweep Gas; 4.3.2.2 Example 2: Flowing Sweep Gas; 4.3.2.3 Example 3: Flowing Sweep Gas with Pervaporation; 4.3.2.4 Example 4: Reactive Liquid Mixture; 4.3.3 Remarks on Arheotropes; 4.4 Kinetic Arheotropes in Reactive Membrane Separation; 4.4.1 Model Formulation 327 $a4.4.1.1 Reaction Kinetics and Mass Balances 330 $aThis is the first book dedicated to the entire field of integrated chemical processes, covering process design, analysis, operation and control of these processes. Both the editors and authors are internationally recognized experts from different fields in industry and academia, and their contributions describe all aspects of intelligent integrations of chemical reactions and physical unit operations such as heat exchange, separational operations and mechanical unit operations. As a unique feature, the book also introduces new concepts for treating different integration concepts on a generaliz 606 $aChemical processes 606 $aChemical reactions 615 0$aChemical processes. 615 0$aChemical reactions. 676 $a660.284 701 $aKienle$b Achim$01728470 701 $aSeidel-Morgenstern$b Andreas$01728307 701 $aSundmacher$b Kai$0923327 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910841527303321 996 $aIntegrated chemical processes$94137980 997 $aUNINA