Bioorganic and Enzymatic Catalysis

• Autore: Woggon Wolf-D
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2023; ©2024
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (192 pages)
• Disciplina: 547.215
• Soggetto topico: Bioorganic chemistry; Catalysis
• Nota di contenuto: Cover -- Title Page -- Contents -- Preface -- 1 Enzymatic CC Bond Formation by Aldol Reactions -- Aldolases -- Class I Aldolases -- Bioorganic Class I Aldolase Reactions -- Class II Aldolases -- Class II Aldolase Mimics -- References -- 2 Fatty Acid- and Polyketide-Synthases - Claisen-Type CC Bond Formation -- Biomimetic Decarboxylative CC Bond Formation -- References -- 3 Carbenium-Ion-Driven CC Bond Formations - Terpenes -- Enzyme-like Cyclisations Involving Carbenium Ions -- References -- 4 Oxidations Catalysed by Heme Complexes -- Monooxygenases -- Cytochromes P450 -- Synthetic P450 Enzyme Models -- Chloroperoxidase (CPO) -- Synthetic Enzyme Mimics of Chloroperoxidase (CPO) -- NO Synthase (NOS) -- References -- 5 Oxidations Catalysed by Non-heme Complexes and Other Co-factors -- Methane Monooxygenase -- Active Site Analogues of Methane Monooxygenase -- Enzyme Mimics of Cu Monooxygenases -- Flavin-dependent Monooxygenases -- Enzyme Mimics of Baeyer-Villiger Monooxygenases -- References -- 6 C-H Activation -- References -- 7 Dioxygenases -- Metal Complexes Displaying Dioxygenase-like Reactivity -- References -- 8 Oxidoreductases -- Cytochrome c Oxidase -- References -- 9 Synthetic Systems That Mimic Certain Aspects of Oxidoreductases -- References -- Index -- EULA.
• Sommario/riassunto: This book, authored by Prof. Wolf-D. Woggon, provides an in-depth exploration of bioorganic and enzymatic catalysis, focusing on the chemical processes involved in enzymatic C-C bond formation, particularly through aldol reactions, and the synthesis of enzyme mimics. It offers a detailed comparison of natural enzymatic reactions with synthetic analogs, emphasizing reaction mechanisms. The text covers topics such as aldolases, Claisen-type reactions, and terpene cyclization, as well as oxidation processes catalyzed by both heme and non-heme complexes. The book is aimed at students with a basic understanding of organic chemistry and professionals in academia or industry seeking to enhance their knowledge of enzymatic catalysis. It includes didactic examples and references, making it a valuable resource for those interested in the application of synthetic methods to mimic natural enzymatic processes.
• Titolo autorizzato: Bioorganic and Enzymatic Catalysis
• ISBN: 9783527678365; 3527678360; 9783527678334; 3527678336
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911020229003321
• Lo trovi qui: Univ. Federico II