Rheokinetics : rheological transformations in synthesis and reactions of oligomers and polymers / / A. Ya. Malkin and S.G. Kulichikhin

• Autore: Malkin Aleksandr IAkovlevich
• Pubblicazione: Zug ; ; Oxford, Conn., : Huthig & Wepf, c1996
• Descrizione fisica: 1 online resource (328 p.)
• Disciplina: 0068.9
• Soggetto topico: Polymers - Rheology
• Altri autori: KulichikhinS. G (Sergei Grigorevich)
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Rheological Transformations in Synthesis and Reactions of Oligomers and Polymers; Table of Contents; Chapter 1 Introduction; 1.1 References for Chapter 1; Chapter 2 Rheokinetics of Linear Polymer Formation; 2.1 General; 2.2 Ionic Polymerization; 2.2.1 A Direct Rheokinetic Problem; 2.2.2 Anionic Polymerization with Varying Amounts of Active Centres; 2.2.3 An Inverse Kinetic Problem; 2.2.4 Experimental Methods; 2.2.5 Anionic Polymerization of Dodecalactam; 2.2.6 Increase of Viscosity during Anionic Polymerization with Changing Concentration of Active Centres ; 2.2.7 Anionic Polymerization of &-caprolactam2.2.8 References for Section 2.2; 2.3 Free Radical Polymerization; 2.3.1 Rheokinetics of the Process - Theoretical Considerations; 2.3.2 Steady Stage of Polymerization - Experimental; 2.3.3 Viscosity of the Medium - Its Role; 2.3.4 Gel Effect; 2.3.5 Polymerization in Heterogeneous Medium; 2.3.6 References for Section 2.3; 2.4 Polycondensation; 2.4.1 Introduction; 2.4.2 Rheokinetic Pattern of the Process; 2.4.3 Experimental; 2.4.4 References for Section 2.4; Chapter 3 Rheokinetics of Oligomer Curing; 3.1 General principles ; 3.1.1 References for Section 3.13.2 Determination of the Point of Gel Formation; 3.2.1 References for Section 3.2; 3.3 Viscosity Increase to the Point of Gel Formation; 3.3.1 References for Section 3.3; 3.4 Microphase Separation in Reactive Systems; 3.4.1 References for Section 3.4; 3.5 Curing After the Point of Gel Formation; 3.5.1 References for Section 3.5; 3.6 Rheokinetic Equations of Curing; 3.6.1 References for Section 3.6; 3.7 Non-isothermal Curing; 3.7.1 Causes of Non-isothermal Behaviour; 3.7.2 Determination of Kinetic Constants in an Adiabatic Process ; 3.7.3 Non-isothermal Curing - Calculations3.7.4 Heat Transfer from an External Source (Linear Temperature Increase); 3.7.5 Curing at High Shear Rates; 3.7.6 References for Section 3.7; 3.8 Structuring Peculiarities of Different Forms of Oligomers and Polymers; 3.8.1 Curing Phenolformaldehyde Resins and Related Oligomers; 3.8.2 Production of Polyurethanes; 3.8.3 The Curing of Unsaturated Polyesters; 3.8.4 Silico-organic Polymers; 3.8.5 Amino-formaldehyde Resins; 3.8.6 Epoxy silico-organic Oligomers; 3.8.7 Rubber Compositions; 3.8.8 Thermo-reactive Pol yamides; 3.8.9 Epoxy Oligomers ; 3.8.10 References for Section 3.8Chapter 4 Transformation in Polymeric Systems; 4.1 Polymer-analogous Transformations; 4.1.1 Transformations in the Solid Phase; 4.1.2 Photo-viscous Effect; 4.1.3 References for Section 4.1; 4.2 Gelation (Curing in Solution); 4.2.1 General Remarks; 4.2.2 Antithixotropy During Gel Formation; 4.2.3 The Role of the Solvent; 4.2.4 Gelation Kinetics; 4.2.5 Gelation of Plastisols; 4.2.6 References for Section 4.2; 4.3 Rheolunetics of Phase Transitions; 4.3.1 Plotting Phase Diagrams; 4.3.2 Crystallization; 4.3.3 Phase Transformations in Reactive Systems ; 4.3.4 References for Section 4.3
• Sommario/riassunto: A book on the role of rheokinetics in polymer technology This book looks at rheokinetics as a subject that can be taught to university students as part of a chemistry, rheology, hydrodynamics or related course. Rheokinetics: Rheological Transformations in Synthesis and Reactions of Oligomers and Polymers examines rheokinetics as a foundational concept in successful polymer technology. Following an introduction, the book chapters cover: Rheokinetics of Linear Polymer Formation, Rheokinetics of Oligomer Curing, and Transformation in Polymeric Systems. The authors sought to discover general rheological roots within the technological processes of polymer syntheses and transformations. They also offer a generalized description of the kinetics of chemical transformations and the process of monitoring them with rheological methods.
• Altri titoli varianti: Rheological transformations in synthesis and reactions of oligomers and polymers
• Titolo autorizzato: Rheokinetics
• ISBN: 9786611842659; 9781281842657; 1281842656; 9783527614950; 3527614958; 9783527614943; 352761494X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911020124303321
• Lo trovi qui: Univ. Federico II