LEADER 05636nam 2200661 a 450 001 9911020124303321 005 20200520144314.0 010 $a9786611842659 010 $a9781281842657 010 $a1281842656 010 $a9783527614950 010 $a3527614958 010 $a9783527614943 010 $a352761494X 035 $a(CKB)1000000000555692 035 $a(EBL)481692 035 $a(OCoLC)264389557 035 $a(SSID)ssj0000237945 035 $a(PQKBManifestationID)11187763 035 $a(PQKBTitleCode)TC0000237945 035 $a(PQKBWorkID)10222016 035 $a(PQKB)10889680 035 $a(MiAaPQ)EBC481692 035 $a(Perlego)2767484 035 $a(EXLCZ)991000000000555692 100 $a19990615d1996 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aRheokinetics $erheological transformations in synthesis and reactions of oligomers and polymers /$fA. Ya. Malkin and S.G. Kulichikhin 210 $aZug ;$aOxford, Conn. $cHuthig & Wepf$dc1996 215 $a1 online resource (328 p.) 300 $aDescription based upon print version of record. 311 08$a9783527297030 311 08$a3527297030 320 $aIncludes bibliographical references and index. 327 $aRheological Transformations in Synthesis and Reactions of Oligomers and Polymers; Table of Contents; Chapter 1 Introduction; 1.1 References for Chapter 1; Chapter 2 Rheokinetics of Linear Polymer Formation; 2.1 General; 2.2 Ionic Polymerization; 2.2.1 A Direct Rheokinetic Problem; 2.2.2 Anionic Polymerization with Varying Amounts of Active Centres; 2.2.3 An Inverse Kinetic Problem; 2.2.4 Experimental Methods; 2.2.5 Anionic Polymerization of Dodecalactam; 2.2.6 Increase of Viscosity during Anionic Polymerization with Changing Concentration of Active Centres 327 $a2.2.7 Anionic Polymerization of &-caprolactam2.2.8 References for Section 2.2; 2.3 Free Radical Polymerization; 2.3.1 Rheokinetics of the Process - Theoretical Considerations; 2.3.2 Steady Stage of Polymerization - Experimental; 2.3.3 Viscosity of the Medium - Its Role; 2.3.4 Gel Effect; 2.3.5 Polymerization in Heterogeneous Medium; 2.3.6 References for Section 2.3; 2.4 Polycondensation; 2.4.1 Introduction; 2.4.2 Rheokinetic Pattern of the Process; 2.4.3 Experimental; 2.4.4 References for Section 2.4; Chapter 3 Rheokinetics of Oligomer Curing; 3.1 General principles 327 $a3.1.1 References for Section 3.13.2 Determination of the Point of Gel Formation; 3.2.1 References for Section 3.2; 3.3 Viscosity Increase to the Point of Gel Formation; 3.3.1 References for Section 3.3; 3.4 Microphase Separation in Reactive Systems; 3.4.1 References for Section 3.4; 3.5 Curing After the Point of Gel Formation; 3.5.1 References for Section 3.5; 3.6 Rheokinetic Equations of Curing; 3.6.1 References for Section 3.6; 3.7 Non-isothermal Curing; 3.7.1 Causes of Non-isothermal Behaviour; 3.7.2 Determination of Kinetic Constants in an Adiabatic Process 327 $a3.7.3 Non-isothermal Curing - Calculations3.7.4 Heat Transfer from an External Source (Linear Temperature Increase); 3.7.5 Curing at High Shear Rates; 3.7.6 References for Section 3.7; 3.8 Structuring Peculiarities of Different Forms of Oligomers and Polymers; 3.8.1 Curing Phenolformaldehyde Resins and Related Oligomers; 3.8.2 Production of Polyurethanes; 3.8.3 The Curing of Unsaturated Polyesters; 3.8.4 Silico-organic Polymers; 3.8.5 Amino-formaldehyde Resins; 3.8.6 Epoxy silico-organic Oligomers; 3.8.7 Rubber Compositions; 3.8.8 Thermo-reactive Pol yamides; 3.8.9 Epoxy Oligomers 327 $a3.8.10 References for Section 3.8Chapter 4 Transformation in Polymeric Systems; 4.1 Polymer-analogous Transformations; 4.1.1 Transformations in the Solid Phase; 4.1.2 Photo-viscous Effect; 4.1.3 References for Section 4.1; 4.2 Gelation (Curing in Solution); 4.2.1 General Remarks; 4.2.2 Antithixotropy During Gel Formation; 4.2.3 The Role of the Solvent; 4.2.4 Gelation Kinetics; 4.2.5 Gelation of Plastisols; 4.2.6 References for Section 4.2; 4.3 Rheolunetics of Phase Transitions; 4.3.1 Plotting Phase Diagrams; 4.3.2 Crystallization; 4.3.3 Phase Transformations in Reactive Systems 327 $a4.3.4 References for Section 4.3 330 8 $aA book on the role of rheokinetics in polymer technology This book looks at rheokinetics as a subject that can be taught to university students as part of a chemistry, rheology, hydrodynamics or related course. Rheokinetics: Rheological Transformations in Synthesis and Reactions of Oligomers and Polymers examines rheokinetics as a foundational concept in successful polymer technology. Following an introduction, the book chapters cover: Rheokinetics of Linear Polymer Formation, Rheokinetics of Oligomer Curing, and Transformation in Polymeric Systems. The authors sought to discover general rheological roots within the technological processes of polymer syntheses and transformations. They also offer a generalized description of the kinetics of chemical transformations and the process of monitoring them with rheological methods. 517 3 $aRheological transformations in synthesis and reactions of oligomers and polymers 606 $aPolymers$xRheology 615 0$aPolymers$xRheology. 676 $a0068.9 700 $aMalkin$b Aleksandr IAkovlevich$0149795 701 $aKulichikhin$b S. G$g(Sergei Grigorevich)$01343032 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9911020124303321 996 $aRheokinetics$93066988 997 $aUNINA