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Vibrational optical activity : principles and applications / Laurence A. Nafie
| Vibrational optical activity : principles and applications / Laurence A. Nafie |
| Autore | Nafie, Laurence A. |
| Pubbl/distr/stampa | Chichester : Wiley, 2011 |
| Descrizione fisica | XX, 378 p. ; 25 cm. |
| Disciplina | 543.54 |
| Soggetto topico | Spettroscopia vibrazionale |
| ISBN | 978-0-470-03248-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNIBAS-000033781 |
Nafie, Laurence A.
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| Chichester : Wiley, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. della Basilicata | ||
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Vibrational optical activity : principles and applications / / Laurence A. Nafie
| Vibrational optical activity : principles and applications / / Laurence A. Nafie |
| Autore | Nafie Laurence A |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester [England] ; ; Syracuse, N.Y., : Wiley, 2011 |
| Descrizione fisica | 1 online resource (400 p.) |
| Disciplina | 539.6 |
| Soggetto topico | Vibrational spectra |
| ISBN |
1-119-97753-3
1-283-17786-2 9786613177865 1-119-97651-0 1-119-97650-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
VIBRATIONAL OPTICAL ACTIVITY: Principles and Applications; Contents; Preface; 1 Overview of Vibrational Optical Activity; 1.1 Introduction to Vibrational Optical Activity; 1.1.1 Field of Vibrational Optical Activity; 1.1.2 Definition of Vibrational Circular Dichroism; 1.1.3 Definition of Vibrational Raman Optical Activity; 1.1.4 Unique Attributes of Vibrational Optical Activity; 1.1.4.1 VOA is the Richest Structural Probe of Molecular Chirality; 1.1.4.2 VOA is the Most Structurally Sensitive Form of Vibrational Spectroscopy
1.1.4.3 VOA Can be Used to Determine Unambiguously the Absolute Configuration of a Chiral Molecule1.1.4.4 VOA Spectra Can be Used to Determine the Solution-State Conformer Populations; 1.1.4.5 VOA Can be Used to Determine the ee of Multiple Chiral Species of Changing Absolute and Relative Concentration; 1.2 Origin and Discovery of Vibrational Optical Activity; 1.2.1 Early Attempts to Measure VOA; 1.2.2 Theoretical Predictions of VCD; 1.2.3 Theoretical Predictions of ROA; 1.2.4 Discovery and Confirmation of ROA; 1.2.5 Discovery and Confirmation of VCD; 1.3 VCD Instrumentation Development 1.3.1 First VCD Measurements - Dispersive, Hydrogen-Stretching Region1.3.2 Near-IR VCD Measurements; 1.3.3 Mid-IR VCD Measurements; 1.3.4 Fourier Transform VCD Instrumentation; 1.3.5 Commercially Available VCD Instrumentation; 1.4 ROA Instrumentation Development; 1.4.1 First ROA Measurements - Single Channel ICP-ROA; 1.4.2 Multi-Channel ROA Measurements; 1.4.3 Backscattering ROA Measurements; 1.4.4 SCP-ROA Measurements; 1.4.5 DCP-ROA Measurements; 1.4.6 Commercially Available ROA Instruments; 1.5 Development of VCD Theory and Calculations; 1.5.1 Models of VCD Spectra 1.5.1.1 Coupled Oscillator Model1.5.1.2 Fixed Partial Charge Model; 1.5.1.3 Localized Molecular Orbital Model; 1.5.1.4 Charge Flow Model; 1.5.1.5 Ring Current Model; 1.5.2 Vibronic Coupling Theory of VCD; 1.5.3 Magnetic Field Perturbation Formulation of VCD; 1.5.4 Nuclear Velocity Perturbation Formulation of VCD; 1.5.5 Ab Initio Calculations of VCD Spectra; 1.5.6 Commercially Available Software for VCD Calculations; 1.6 Development of ROA Theory and Calculations; 1.6.1 Original Theory of ROA; 1.6.2 Models of ROA Spectra; 1.6.3 General Unrestricted Theory of Circular Polarization ROA 1.6.4 Linear Polarization ROA1.6.5 Theory of Resonance ROA in the SES Limit; 1.6.6 Near Resonance Theory of ROA; 1.6.7 Ab Initio Calculations of ROA Spectra; 1.6.8 Quantum Chemistry Programs for ROA Calculations; 1.7 Applications of Vibrational Optical Activity; 1.7.1 Biological Applications of VOA; 1.7.2 Absolute Configuration Determination; 1.7.3 Solution-State Conformation Determination; 1.7.4 Enantiomeric Excess and Reaction Monitoring; 1.7.5 Applications with Solid-Phase Sampling; 1.8 Comparison of Infrared and Raman Vibrational Optical Activity 1.8.1 Frequency Ranges and Structural Sensitivities |
| Record Nr. | UNINA-9910819130303321 |
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Nafie Laurence A
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| Chichester [England] ; ; Syracuse, N.Y., : Wiley, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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