Cyclic [beta]-keto esters : synthesis and reactions / / M.A. Metwally and E.G. Sadek

• Autore: Metwally M. A
• Pubblicazione: Hauppauge, N.Y., : Nova Science Publishers, c2010
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (125 p.)
• Disciplina: 547/.638
• Soggetto topico: Ketones; Esters; Organic cyclic compounds
• Altri autori: SadekE. G
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references (p. [93]-106) and index.
• Nota di contenuto: Intro -- CYCLIC -KETO ESTERS: SYNTHESIS AND REACTIONS -- CYCLIC -KETO ESTERS: SYNTHESIS AND REACTIONS -- CONTENTS -- PREFACE -- Chapter 1 SYNTHESIS -- 1. CARBOXYLATION OF KETONES -- 2. INTRAMOLECULAR CONDENSATION AND CYCLIZATION OF SIX-MEMBERED RINGS -- 3. ISOMERIZATION -- 4. DIECKMANN CONDENSATION (INTRAMOLECULAR CLAISEN CONDENSATION -- 5. MILLER AND NORD REACTION -- 6. ESTERS OF , -DIETHYLACETONEDICARBOXYLIC ACID REACT WITH FORMALDEHYDE AND METHYLAMINE TO GIVE PYRIDONES [12] -- 7. CYCLIC -KETO ESTERS OF THE TYPE (G) CAN BE PREPARED FROM CYCLIC KETONES AND ETHYL CYANOACETATE -- 8. CLAISEN ACYLATION AND CARBOETHOXYLATION OF KETONES AND ESTERS [14,15] -- 9. HOMOLOGATION OF KETONES WITH ETHYL DIAZOACETATE -- 10. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE -- 11. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE -- 12. THE ENAMINE ACYLATION AND ALKYLATION OF CARBONYL COMPOUND -- 13. SYNTHESIS OF 2-CARBOETHOXYCYCLOHEXANONE -- 14. SYNTHESIS OF N-CONTAINING CYCLIC -KETO ESTERS -- 15. SYNTHESIS OF , -DIFLUORO- -KETO ESTERS: -- Chapter 2 REACTIONS -- 1. ALKYLATION -- 2. MICHAEL REACTION -- 3. ACYLATION AND ARYLATION -- 4. MANNICH REACTION -- 5. NITROSATION -- 6. THE JAPP-KLINGEMANN REACTION -- 7. REACTION WITH AMINES -- 8. REACTION WITH HYDRAZINES AND ACID HYDRAZIDES -- 9. REACTION WITH HYDROXYLAMINE -- 10. REACTION WITH UREA AND THIOUREA -- 11. REACTION WITH GUANIDINES -- 12. REACTIONS WITH AMINOAZOLES -- 13. REFORMATSKY REACTION -- 14. REACTION WITH GLYCOLS AND DITHIOLS -- 15. OXIDATION -- 16. REDUCTION -- 17. PECHMANN REACTION -- 18. REACTION WITH HALOGENS -- 19. WITTIG REACTION -- 20. DECARBOXYLATION -- 21. SULFURATION -- 22. KNOEVENAGEL REACTION -- 23. RING EXPANSION -- 24. SCHMIDT REACTION -- 25. KETALIZATION -- 26. EFFECT OF ULTRAVIOLET LIGHT -- 27. HYDROXYLATION -- 28. BROMINATION AND CHLORINATION -- 29. TRANSESTERIFICATION. ; 30. ANNELATION REACTION -- 31. CYCLIZATION WITH 5-AMINOPYRAZOLES -- 32. COUPLING WITH -(N-CARBAMOYL) ALKYLCUPRATES -- 33. TAUTOMERIZATION -- 34. ALDOL AND DEHYDRATION -- 35. REACTION WITH ACETYLENE -- 36. BIOTRANSFORMATION -- 37. REACTION WITH 1,4- DIHALOBUTENES: -- 38. CYCLIZATION OF ALKENYL -KETO ESTERS AND AMIDES -- 39. HYDROGENATION -- 40. REACTION WITH SERINE-DERIVED CYCLIC SULFAMIDATES -- 41. RITTER REACTION -- 42. SULFENYLATION -- 43. REACTION WITH SODIUM HYDRIDE -- 44. REACTION WITH CHIRAL CYCLIC DIOLS -- 45. DEHYDROGENATION -- 46. REGIOSELECTIVE CONVERSION -- 47. REACTION WITH FURAN DERIVATIVES -- 48. CONDENSATION WITH INDOLEETHANAMINES -- 49. PHOTOLYTIC CLEAVAGE -- 50. THERMAL SELFCONDENSATION -- 51. CONDENSATION WITH ETHYLENE OXIDE -- REFERENCES -- INDEX.
• Sommario/riassunto: The chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group. This title review the syntheses and reactions of cyclic ss-ketoesters.
• Titolo autorizzato: Cyclic -keto esters
• ISBN: 1-61324-325-1
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910955842203321
• Lo trovi qui: Univ. Federico II
• Serie: Chemistry research and applications series.