LEADER 04767nam 2200625 a 450 001 9910955842203321 005 20251117090858.0 010 $a1-61324-325-1 035 $a(CKB)2550000000043805 035 $a(EBL)3019548 035 $a(SSID)ssj0000521854 035 $a(PQKBManifestationID)12212541 035 $a(PQKBTitleCode)TC0000521854 035 $a(PQKBWorkID)10527271 035 $a(PQKB)10246560 035 $a(MiAaPQ)EBC3019548 035 $a(Au-PeEL)EBL3019548 035 $a(CaPaEBR)ebr10671113 035 $a(OCoLC)739712847 035 $a(BIP)28894492 035 $a(EXLCZ)992550000000043805 100 $a20091222d2010 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCyclic [beta]-keto esters $esynthesis and reactions /$fM.A. Metwally and E.G. Sadek 205 $a1st ed. 210 $aHauppauge, N.Y. $cNova Science Publishers$dc2010 215 $a1 online resource (125 p.) 225 1 $aChemistry research and applications series 300 $aDescription based upon print version of record. 311 08$a1-61668-282-5 320 $aIncludes bibliographical references (p. [93]-106) and index. 327 $aIntro -- CYCLIC -KETO ESTERS: SYNTHESIS AND REACTIONS -- CYCLIC -KETO ESTERS: SYNTHESIS AND REACTIONS -- CONTENTS -- PREFACE -- Chapter 1 SYNTHESIS -- 1. CARBOXYLATION OF KETONES -- 2. INTRAMOLECULAR CONDENSATION AND CYCLIZATION OF SIX-MEMBERED RINGS -- 3. ISOMERIZATION -- 4. DIECKMANN CONDENSATION (INTRAMOLECULAR CLAISEN CONDENSATION -- 5. MILLER AND NORD REACTION -- 6. ESTERS OF , -DIETHYLACETONEDICARBOXYLIC ACID REACT WITH FORMALDEHYDE AND METHYLAMINE TO GIVE PYRIDONES [12] -- 7. CYCLIC -KETO ESTERS OF THE TYPE (G) CAN BE PREPARED FROM CYCLIC KETONES AND ETHYL CYANOACETATE -- 8. CLAISEN ACYLATION AND CARBOETHOXYLATION OF KETONES AND ESTERS [14,15] -- 9. HOMOLOGATION OF KETONES WITH ETHYL DIAZOACETATE -- 10. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE -- 11. SYNTHESIS OF CARBOETHOXYCYCLOHEXANONE -- 12. THE ENAMINE ACYLATION AND ALKYLATION OF CARBONYL COMPOUND -- 13. SYNTHESIS OF 2-CARBOETHOXYCYCLOHEXANONE -- 14. SYNTHESIS OF N-CONTAINING CYCLIC -KETO ESTERS -- 15. SYNTHESIS OF , -DIFLUORO- -KETO ESTERS: -- Chapter 2 REACTIONS -- 1. ALKYLATION -- 2. MICHAEL REACTION -- 3. ACYLATION AND ARYLATION -- 4. MANNICH REACTION -- 5. NITROSATION -- 6. THE JAPP-KLINGEMANN REACTION -- 7. REACTION WITH AMINES -- 8. REACTION WITH HYDRAZINES AND ACID HYDRAZIDES -- 9. REACTION WITH HYDROXYLAMINE -- 10. REACTION WITH UREA AND THIOUREA -- 11. REACTION WITH GUANIDINES -- 12. REACTIONS WITH AMINOAZOLES -- 13. REFORMATSKY REACTION -- 14. REACTION WITH GLYCOLS AND DITHIOLS -- 15. OXIDATION -- 16. REDUCTION -- 17. PECHMANN REACTION -- 18. REACTION WITH HALOGENS -- 19. WITTIG REACTION -- 20. DECARBOXYLATION -- 21. SULFURATION -- 22. KNOEVENAGEL REACTION -- 23. RING EXPANSION -- 24. SCHMIDT REACTION -- 25. KETALIZATION -- 26. EFFECT OF ULTRAVIOLET LIGHT -- 27. HYDROXYLATION -- 28. BROMINATION AND CHLORINATION -- 29. TRANSESTERIFICATION. 327 $a30. ANNELATION REACTION -- 31. CYCLIZATION WITH 5-AMINOPYRAZOLES -- 32. COUPLING WITH -(N-CARBAMOYL) ALKYLCUPRATES -- 33. TAUTOMERIZATION -- 34. ALDOL AND DEHYDRATION -- 35. REACTION WITH ACETYLENE -- 36. BIOTRANSFORMATION -- 37. REACTION WITH 1,4- DIHALOBUTENES: -- 38. CYCLIZATION OF ALKENYL -KETO ESTERS AND AMIDES -- 39. HYDROGENATION -- 40. REACTION WITH SERINE-DERIVED CYCLIC SULFAMIDATES -- 41. RITTER REACTION -- 42. SULFENYLATION -- 43. REACTION WITH SODIUM HYDRIDE -- 44. REACTION WITH CHIRAL CYCLIC DIOLS -- 45. DEHYDROGENATION -- 46. REGIOSELECTIVE CONVERSION -- 47. REACTION WITH FURAN DERIVATIVES -- 48. CONDENSATION WITH INDOLEETHANAMINES -- 49. PHOTOLYTIC CLEAVAGE -- 50. THERMAL SELFCONDENSATION -- 51. CONDENSATION WITH ETHYLENE OXIDE -- REFERENCES -- INDEX. 330 $aThe chemistry of cyclic ss-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group. This title review the syntheses and reactions of cyclic ss-ketoesters. 410 0$aChemistry research and applications series. 606 $aKetones 606 $aEsters 606 $aOrganic cyclic compounds 615 0$aKetones. 615 0$aEsters. 615 0$aOrganic cyclic compounds. 676 $a547/.638 700 $aMetwally$b M. A$01865897 701 $aSadek$b E. G$01865898 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910955842203321 996 $aCyclic -keto esters$94473125 997 $aUNINA