Metal amide chemistry [[electronic resource] /] / Michael Lappert ... [et al.]

• Pubblicazione: Chichester, U.K., : Wiley, c2009
• Descrizione fisica: 1 online resource (371 p.)
• Disciplina: 547/.042
• Soggetto topico: Amides; Alkaline earth metals; Organometallic compounds
• Altri autori: LappertM. F
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Metal Amide Chemistry; Contents; Biographies; Preface; 1 Introduction; 1.1 Scope and Organisation of Subject Matter; 1.2 Developments and Perspectives; 2 Alkali Metal Amides; 2.1 Introduction; 2.2 Lithium Amides; 2.2.1 Introduction; 2.2.2 Monomeric Lithium Amides; 2.2.3 Dimeric Lithium Amides; 2.2.4 Trimeric Lithium Amides; 2.2.5 Tetrameric Lithium Amides; 2.2.6 Higher Aggregate Lithium Amides; 2.2.7 Laddering; 2.2.8 Heterometallic Derivatives; 2.3 Sodium Amides; 2.3.1 Introduction; 2.3.2 Monomeric and Dimeric Sodium Amides; 2.3.3 Higher Aggregate Sodium Amides ; 2.3.4 Heterometallic Sodium Amides2.4 Potassium Amides; 2.4.1 Introduction; 2.4.2 Potassium Parent Amides ( NH2 as Ligand); 2.4.3 Potassium Primary and Secondary Amides; 2.4.4 Heterometallic Potassium Amides; 2.5 Rubidium Amides; 2.6 Caesium Amides; References; 3 Beryllium and the Alkaline Earth Metal Amides; 3.1 Introduction; 3.2 Beryllium Amides 403.3 Magnesium Amides; 3.3.1 Introduction; 3.3.2 Monomeric Magnesium Amides; 3.3.3 Dimeric Magnesium Amides; 3.3.4 Higher Aggregates and Related Magnesium Amides; 3.3.5 Heterometallic Magnesium Amides; 3.3.6 Magnesium Inverse Crown Complexes ; 3.3.7 Magnesium Imides3.4 Calcium Amides; 3.4.1 Introduction; 3.4.2 Monomeric Calcium Amides; 3.4.3 Dimeric Calcium Amides and Higher Aggregates; 3.4.4 Heterometallic Calcium Amide Derivatives; 3.5 Strontium Amides; 3.5.1 Introduction; 3.5.2 Monomeric Strontium Amides; 3.5.3 Higher Aggregate Strontium Amides; 3.6 Barium Amides; 3.6.1 Introduction; 3.6.2 Monomeric Barium Amides; 3.6.3 Dimeric Barium Amides; 3.6.4 Heterometallic Barium Amides; References; 4 Amides of the Group 3 and Lanthanide Metals; 4.1 Introduction; 4.2 The Pre-1996 Literature: Anwander's Review; 4.2.1 Introduction ; 4.2.2 LnIIIComplexes withN-Hydrocarbyl-Amido Ligands4.2.3 LnIIIComplexes having Silylamido Ligands; 4.2.4 Bis(Trimethylsilyl)Amido-LnII Complexes and a CeIVAnalogue; 4.2.5 LnIIIComplexes having Donor-Functionalised Amido Ligands; 4.2.6 Ln Amides as Precursors for Ln Coordination or Organometallic Compounds; 4.2.7 Applications as Materials or Catalysts; 4.3 The Recent (Post-1995) Literature; 4.3.1 Introduction; 4.3.2 LnIIIComplexes withN-Hydrocarbyl Substituted Ligands; 4.3.3 LnIIIComplexes having Silylamido Ligands; 4.3.4 LnII and CeIVAmides ; 4.3.5 Ln Complexes having Donor-Functionalised Amido Ligands4.3.6 Ln Amides as Precursors for Ln Coordination or Organometallic Compounds; 4.3.7 Applications as Materials or Catalysts; 4.3.8 Ln Complexes having 1,4-Disubstituted-1,4-Diazabutadiene Ligands, R2-DAD; References; 5 Amides of the Actinide Metals; 5.1 Introduction; 5.2 Neutral Amidouranium(IV) and Thorium(IV) Complexes; 5.2.1 Introduction; 5.2.2 Hydrocarbylamido-AnIVCompounds Free of p-Centred Ligands; 5.2.3 Silylamido-AnIVCompounds Free ofp-Centred Ligands; 5.2.4 AnIVAmides Containingp-Centred Co-ligands; 5.3 Neutral UIIIAmides ; 5.4 Neutral Mixed Valence (UIII /UIV ), UII ,U Vand UVIAmides
• Sommario/riassunto: Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power's 1980 book "Metal and Metalloid Amides." An introduction to the topic is followed by in-depth discussions of the amide compounds of:alkali metalsalkaline earth metalszinc, cadmium and mercurythe transition metalsgroup 3 and lanthanide metalsgroup 13 metalssilicon and the group 14 metalsgroup 15 metalsthe actinide metals Accompanied by a substantial bibliograp
• Titolo autorizzato: Metal amide chemistry
• ISBN: 1-282-68784-0; 9786612687846; 0-470-74038-8; 0-470-74037-X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910144377503321
• Lo trovi qui: Univ. Federico II