LEADER 05290nam 2200673 a 450 001 9910144377503321 005 20200520144314.0 010 $a1-282-68784-0 010 $a9786612687846 010 $a0-470-74038-8 010 $a0-470-74037-X 035 $a(CKB)1000000000687231 035 $a(EBL)416457 035 $a(OCoLC)476248213 035 $a(SSID)ssj0000201622 035 $a(PQKBManifestationID)11184389 035 $a(PQKBTitleCode)TC0000201622 035 $a(PQKBWorkID)10246090 035 $a(PQKB)11259110 035 $a(MiAaPQ)EBC416457 035 $a(Au-PeEL)EBL416457 035 $a(CaPaEBR)ebr10275691 035 $a(CaONFJC)MIL268784 035 $a(PPN)152399828 035 $a(EXLCZ)991000000000687231 100 $a20081020d2009 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aMetal amide chemistry$b[electronic resource] /$fMichael Lappert ... [et al.] 210 $aChichester, U.K. $cWiley$dc2009 215 $a1 online resource (371 p.) 300 $aDescription based upon print version of record. 311 $a0-470-72184-7 320 $aIncludes bibliographical references and index. 327 $aMetal Amide Chemistry; Contents; Biographies; Preface; 1 Introduction; 1.1 Scope and Organisation of Subject Matter; 1.2 Developments and Perspectives; 2 Alkali Metal Amides; 2.1 Introduction; 2.2 Lithium Amides; 2.2.1 Introduction; 2.2.2 Monomeric Lithium Amides; 2.2.3 Dimeric Lithium Amides; 2.2.4 Trimeric Lithium Amides; 2.2.5 Tetrameric Lithium Amides; 2.2.6 Higher Aggregate Lithium Amides; 2.2.7 Laddering; 2.2.8 Heterometallic Derivatives; 2.3 Sodium Amides; 2.3.1 Introduction; 2.3.2 Monomeric and Dimeric Sodium Amides; 2.3.3 Higher Aggregate Sodium Amides 327 $a2.3.4 Heterometallic Sodium Amides2.4 Potassium Amides; 2.4.1 Introduction; 2.4.2 Potassium Parent Amides ( NH2 as Ligand); 2.4.3 Potassium Primary and Secondary Amides; 2.4.4 Heterometallic Potassium Amides; 2.5 Rubidium Amides; 2.6 Caesium Amides; References; 3 Beryllium and the Alkaline Earth Metal Amides; 3.1 Introduction; 3.2 Beryllium Amides 403.3 Magnesium Amides; 3.3.1 Introduction; 3.3.2 Monomeric Magnesium Amides; 3.3.3 Dimeric Magnesium Amides; 3.3.4 Higher Aggregates and Related Magnesium Amides; 3.3.5 Heterometallic Magnesium Amides; 3.3.6 Magnesium Inverse Crown Complexes 327 $a3.3.7 Magnesium Imides3.4 Calcium Amides; 3.4.1 Introduction; 3.4.2 Monomeric Calcium Amides; 3.4.3 Dimeric Calcium Amides and Higher Aggregates; 3.4.4 Heterometallic Calcium Amide Derivatives; 3.5 Strontium Amides; 3.5.1 Introduction; 3.5.2 Monomeric Strontium Amides; 3.5.3 Higher Aggregate Strontium Amides; 3.6 Barium Amides; 3.6.1 Introduction; 3.6.2 Monomeric Barium Amides; 3.6.3 Dimeric Barium Amides; 3.6.4 Heterometallic Barium Amides; References; 4 Amides of the Group 3 and Lanthanide Metals; 4.1 Introduction; 4.2 The Pre-1996 Literature: Anwander's Review; 4.2.1 Introduction 327 $a4.2.2 LnIIIComplexes withN-Hydrocarbyl-Amido Ligands4.2.3 LnIIIComplexes having Silylamido Ligands; 4.2.4 Bis(Trimethylsilyl)Amido-LnII Complexes and a CeIVAnalogue; 4.2.5 LnIIIComplexes having Donor-Functionalised Amido Ligands; 4.2.6 Ln Amides as Precursors for Ln Coordination or Organometallic Compounds; 4.2.7 Applications as Materials or Catalysts; 4.3 The Recent (Post-1995) Literature; 4.3.1 Introduction; 4.3.2 LnIIIComplexes withN-Hydrocarbyl Substituted Ligands; 4.3.3 LnIIIComplexes having Silylamido Ligands; 4.3.4 LnII and CeIVAmides 327 $a4.3.5 Ln Complexes having Donor-Functionalised Amido Ligands4.3.6 Ln Amides as Precursors for Ln Coordination or Organometallic Compounds; 4.3.7 Applications as Materials or Catalysts; 4.3.8 Ln Complexes having 1,4-Disubstituted-1,4-Diazabutadiene Ligands, R2-DAD; References; 5 Amides of the Actinide Metals; 5.1 Introduction; 5.2 Neutral Amidouranium(IV) and Thorium(IV) Complexes; 5.2.1 Introduction; 5.2.2 Hydrocarbylamido-AnIVCompounds Free of p-Centred Ligands; 5.2.3 Silylamido-AnIVCompounds Free ofp-Centred Ligands; 5.2.4 AnIVAmides Containingp-Centred Co-ligands; 5.3 Neutral UIIIAmides 327 $a5.4 Neutral Mixed Valence (UIII /UIV ), UII ,U Vand UVIAmides 330 $aWritten by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power's 1980 book "Metal and Metalloid Amides." An introduction to the topic is followed by in-depth discussions of the amide compounds of:alkali metalsalkaline earth metalszinc, cadmium and mercurythe transition metalsgroup 3 and lanthanide metalsgroup 13 metalssilicon and the group 14 metalsgroup 15 metalsthe actinide metals Accompanied by a substantial bibliograp 606 $aAmides 606 $aAlkaline earth metals 606 $aOrganometallic compounds 615 0$aAmides. 615 0$aAlkaline earth metals. 615 0$aOrganometallic compounds. 676 $a547/.042 701 $aLappert$b M. F$0917982 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144377503321 996 $aMetal amide chemistry$92058321 997 $aUNINA