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Titolo: | Reactivity in molecular crystals / / edited by Yuji Ohashi |
Pubblicazione: | Tokyo, Japan ; ; Weinheim, [Germany] : , : Kodansha : , : VCH, , 1993 |
©1993 | |
Descrizione fisica: | 1 online resource (362 p.) |
Disciplina: | 548 |
548.85 | |
Soggetto topico: | Molecular crystals |
Chemical reactions | |
Soggetto genere / forma: | Electronic books. |
Persona (resp. second.): | ŌhashiYūji <1941-> |
Note generali: | Description based upon print version of record. |
Nota di bibliografia: | Includes bibliographical references at the end of each chapters and index. |
Nota di contenuto: | Reactivity in Molecular Crystals; List of Contributors; Contents; Preface; 1. THEORETICAL APPROACH; 1.1 Potential Energy Calculations of Crystals; 1.2 A Novel Molecular-Dynamics Method to Predict Molecular Crystal Structures; 2. PHYSICO-CHEMICAL APPROACH; 2.1 Development of a New X-Ray Diffractometer (IPD-WAS) for Rapid Measurement; 2.2 Reaction Process in Solid State Studied by High Resolution Electron Spectromicroscopy; 2.3 Analysis of Charge Transfer Complex Formation in the Solid State by Penning lonilation Electron Spectroscopy |
2.4 Analysis of Reactive Species by Time Resolved Infrared Reflection Absorption Spectroscopy2.5 Molecular Motion in Clathrate Crystals Analyred by Solid-state NMR Method; 2.6 Asymmetric Structure Analysis for Reaction Centers of a Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy; 2.7 Excitation Energy Transfer Between Metal Complexes in Solids; 3. CRYSTALLINE-STATE REACTION; 3.1 Dynamic Structure Analysis of Crystalline-State Reaction; 3.2 Reversible Intercalation of Guest Molecules in Crystals of Cholic Acid | |
3.3 How can Crystalline Environment Provide Outstanding Chemistry for Diarylcarbenes or Arylnitrenes4. Solid-to- Solid Organic Reactions; 4.1 Introduction; 4.2 Pinacol and Benzylic Acid Rearrangement; 4.3 Baeyer-Villiger Oxidation; 4.4 Reduction with NaBH4; 4.5 Grignard, Reformatsky and Luche Reactions; 4.6 Coupling Reactions; 4.7 Witting-Horner Reaction; 4.8 Aldol Condensation; 4.9 Dehydration, Rearrangement, Chlorination and Etherification of Secondary Alcohols; 4.10 Host-Guest Inclusion Complexation in the Solid State; 5. Streoselective Solid-State Photoreaction | |
5.1 Determining Factors of Molecular Arrangement and Reaction Course in the Crystalline-State Photoreaction of Unsymmetrically Substituted Diolefins5.2 Stereoselectivity in Reactions of Clathrate Crystals; 5.3 Solid-state Photochromism of Tetraphenyldihydro-1,3,5-Triazine and Related Heterocycles; 5.4 Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt Complexes; 6. REACTIVITY AND CRYSTAL STRUCTURE; 6.1 Packing Effect in Solid-State Polymerization of Diethynylbenzene Derivatives by Radiation | |
6.2 High Selective Reaction Deduced by Tunneling Effect in the Crystalline Environment6.3 Formation of Bimolecular Films and Crystal Structure; 6.4 Reactivity and Reaction Pathway of the Sulfur Compounds; 6.5 Stereoselectivity and Molecular Recognition in Double Macrocyclic Inclusion Crystals; Index | |
Sommario/riassunto: | Do you need to design syntheses that are* highly selective* fast* enantioselective with quantitative enantiomeric yield? This book describes in detail how best to exploit the enormous synthetic potential of solid state reactions. Written by leading experts, it provides in-depth information on* the theoretical and physico-chemical approach to solid state reactions* solid-to-solid organic reactions* stereoselective solid state photoreactions* reactivity and crystal structureAn ideal companion to Dunitz and Bürgi's 'Structure Correlation', this |
Titolo autorizzato: | Reactivity in molecular crystals |
ISBN: | 1-281-84295-8 |
9786611842956 | |
3-527-61613-6 | |
3-527-61612-8 | |
Formato: | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione: | Inglese |
Record Nr.: | 9910144279503321 |
Lo trovi qui: | Univ. Federico II |
Opac: | Controlla la disponibilità qui |