04705nam 2200625 450 991014427950332120170810191514.01-281-84295-897866118429563-527-61613-63-527-61612-8(CKB)1000000000376628(EBL)482212(OCoLC)723943581(SSID)ssj0000354716(PQKBManifestationID)11925310(PQKBTitleCode)TC0000354716(PQKBWorkID)10314535(PQKB)10780593(MiAaPQ)EBC482212(EXLCZ)99100000000037662820160820h19931993 uy 0engur|n|---|||||txtccrReactivity in molecular crystals /edited by Yuji OhashiTokyo, Japan ;Weinheim, [Germany] :Kodansha :VCH,1993.©19931 online resource (362 p.)Description based upon print version of record.3-527-29098-2 Includes bibliographical references at the end of each chapters and index.Reactivity in Molecular Crystals; List of Contributors; Contents; Preface; 1. THEORETICAL APPROACH; 1.1 Potential Energy Calculations of Crystals; 1.2 A Novel Molecular-Dynamics Method to Predict Molecular Crystal Structures; 2. PHYSICO-CHEMICAL APPROACH; 2.1 Development of a New X-Ray Diffractometer (IPD-WAS) for Rapid Measurement; 2.2 Reaction Process in Solid State Studied by High Resolution Electron Spectromicroscopy; 2.3 Analysis of Charge Transfer Complex Formation in the Solid State by Penning lonilation Electron Spectroscopy2.4 Analysis of Reactive Species by Time Resolved Infrared Reflection Absorption Spectroscopy2.5 Molecular Motion in Clathrate Crystals Analyred by Solid-state NMR Method; 2.6 Asymmetric Structure Analysis for Reaction Centers of a Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy; 2.7 Excitation Energy Transfer Between Metal Complexes in Solids; 3. CRYSTALLINE-STATE REACTION; 3.1 Dynamic Structure Analysis of Crystalline-State Reaction; 3.2 Reversible Intercalation of Guest Molecules in Crystals of Cholic Acid3.3 How can Crystalline Environment Provide Outstanding Chemistry for Diarylcarbenes or Arylnitrenes4. Solid-to- Solid Organic Reactions; 4.1 Introduction; 4.2 Pinacol and Benzylic Acid Rearrangement; 4.3 Baeyer-Villiger Oxidation; 4.4 Reduction with NaBH4; 4.5 Grignard, Reformatsky and Luche Reactions; 4.6 Coupling Reactions; 4.7 Witting-Horner Reaction; 4.8 Aldol Condensation; 4.9 Dehydration, Rearrangement, Chlorination and Etherification of Secondary Alcohols; 4.10 Host-Guest Inclusion Complexation in the Solid State; 5. Streoselective Solid-State Photoreaction5.1 Determining Factors of Molecular Arrangement and Reaction Course in the Crystalline-State Photoreaction of Unsymmetrically Substituted Diolefins5.2 Stereoselectivity in Reactions of Clathrate Crystals; 5.3 Solid-state Photochromism of Tetraphenyldihydro-1,3,5-Triazine and Related Heterocycles; 5.4 Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt Complexes; 6. REACTIVITY AND CRYSTAL STRUCTURE; 6.1 Packing Effect in Solid-State Polymerization of Diethynylbenzene Derivatives by Radiation6.2 High Selective Reaction Deduced by Tunneling Effect in the Crystalline Environment6.3 Formation of Bimolecular Films and Crystal Structure; 6.4 Reactivity and Reaction Pathway of the Sulfur Compounds; 6.5 Stereoselectivity and Molecular Recognition in Double Macrocyclic Inclusion Crystals; IndexDo you need to design syntheses that are* highly selective* fast* enantioselective with quantitative enantiomeric yield? This book describes in detail how best to exploit the enormous synthetic potential of solid state reactions. Written by leading experts, it provides in-depth information on* the theoretical and physico-chemical approach to solid state reactions* solid-to-solid organic reactions* stereoselective solid state photoreactions* reactivity and crystal structureAn ideal companion to Dunitz and Bürgi's 'Structure Correlation', this Molecular crystalsChemical reactionsElectronic books.Molecular crystals.Chemical reactions.548548.85Ōhashi Yūji1941-MiAaPQMiAaPQMiAaPQBOOK9910144279503321Reactivity in molecular crystals2016854UNINA