Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation [[electronic resource] /] / by Arimasa Matsumoto
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| Autore: |
Matsumoto Arimasa
|
| Titolo: |
Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation [[electronic resource] /] / by Arimasa Matsumoto
|
| Pubblicazione: | Tokyo : , : Springer Japan : , : Imprint : Springer, , 2014 |
| Edizione: | 1st ed. 2014. |
| Descrizione fisica: | 1 online resource (84 p.) |
| Disciplina: | 541.395 |
| Soggetto topico: | Organometallic chemistry |
| Metals | |
| Organometallic Chemistry | |
| Metallic Materials | |
| Note generali: | "Doctoral Thesis accepted by The University of Tokyo, Japan". |
| Nota di bibliografia: | Includes bibliographical references at the end of each chapters. |
| Nota di contenuto: | General Introduction -- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium -- Summary and Perspectives. |
| Sommario/riassunto: | Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society. |
| Titolo autorizzato: | Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation |
| ISBN: | 4-431-54928-5 |
| Formato: | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione: | Inglese |
| Record Nr.: | 9910298657403321 |
| Lo trovi qui: | Univ. Federico II |
| Opac: | Controlla la disponibilità qui |
Serie:
Springer Theses, Recognizing Outstanding Ph.D. Research, . 2190-5053