03334nam 22006255 450 991029865740332120200630153348.04-431-54928-510.1007/978-4-431-54928-4(CKB)3710000000168306(EBL)1783684(SSID)ssj0001295491(PQKBManifestationID)11719468(PQKBTitleCode)TC0001295491(PQKBWorkID)11344039(PQKB)10533974(MiAaPQ)EBC1783684(DE-He213)978-4-431-54928-4(PPN)179927841(EXLCZ)99371000000016830620140707d2014 u| 0engur|n|---|||||txtccrIron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation[electronic resource] /by Arimasa Matsumoto1st ed. 2014.Tokyo :Springer Japan :Imprint: Springer,2014.1 online resource (84 p.)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053"Doctoral Thesis accepted by The University of Tokyo, Japan".1-322-17358-3 4-431-54927-7 Includes bibliographical references at the end of each chapters.General Introduction -- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium -- Summary and Perspectives.Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5053Organometallic chemistry MetalsOrganometallic Chemistryhttps://scigraph.springernature.com/ontologies/product-market-codes/C19020Metallic Materialshttps://scigraph.springernature.com/ontologies/product-market-codes/Z16000Organometallic chemistry .Metals.Organometallic Chemistry.Metallic Materials.541.395Matsumoto Arimasaauthttp://id.loc.gov/vocabulary/relators/aut1063348MiAaPQMiAaPQMiAaPQBOOK9910298657403321Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation2531900UNINA