Methods and applications of cycloaddition reactions in organic syntheses / / edited by Nagatoshi Nishiwaki

• Pubblicazione: Hoboken, New Jersey : , : Wiley, , 2014
• Descrizione fisica: 1 online resource (673 p.)
• Disciplina: 547/.27
• Soggetto topico: Organic compounds - Synthesis; Ring formation (Chemistry)
• Altri autori: NishiwakiNagatoshi <1963->
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Methods and Applications of Cycloaddition Reactions in Organic Syntheses; Contents; Preface; Contributors; Part I: [2+1] Cycloaddition; 1 [2+1]-Type Cyclopropanation Reactions; 1.1 INTRODUCTION; 1.2 CYCLOPROPANATION REACTION VIA MICHAEL-INDUCED RING CLOSURE REACTION; 1.2.1 Introduction; 1.2.2 Halo-Substituted Nucleophiles in MIRC Reaction; 1.2.3 Ylides for Cyclopropanation; 1.3 SIMMONS-SMITH CYCLOPROPANATION AND RELATED REACTIONS; 1.3.1 Introduction; 1.3.2 The Simmons-Smith Reaction with Zinc Reagents; 1.4 DIAZOALKANES WITH TRANSITION METAL CATALYSTS; 1.4.1 Introduction ; 1.4.2 Rhodium-Catalyzed Reactions1.4.4 Ruthenium-Catalyzed Reactions; 1.4.5 Cobalt- and Iron-Catalyzed Reactions; 1.4.6 Other Transition Metal-Catalyzed Reactions; 1.4.7 Cyclopropanation Without Transition Metal Catalysts; 1.4.8 Cyclopropanation of Dihalocarbenes; 1.5 CYCLOISOMERIZATION WITH TRANSITION METAL CATALYSTS; 1.5.1 Introduction; 1.5.2 Gold Complex-Catalyzed Reactions; 1.5.3 Palladium Complex-Catalyzed Reactions; 1.5.4 Platinum Complex-Catalyzed Reactions; 1.5.5 Ruthenium Complex-Catalyzed Reactions; 1.5.6 Other Metal Complex-Catalyzed Reactions; 1.6 KULINKOVICH REACTIONS ; 1.6.1 Introduction1.6.2 The Kulinkovich Reaction to Esters, Ketones, and Amides; 1.6.3 Kulinkovich Reaction to Nitriles; 1.6.4 Other Ti-Mediated Cyclopropanation Reactions; 1.7 MISCELLANEOUS [2+1]-TYPE OF CYCLOPROPANATION REACTIONS; REFERENCES; 2 N1 Unit Transfer Reaction To C-C Double Bonds; 2.1 INTRODUCTION; 2.2 AZIRIDINATION WITH AZIDES; 2.3 AZIRIDINATION WITH IMINOIODINANES; 2.4 AZIRIDINATION WITH N-HALOAMINE SALTS; 2.5 AZIRIDINATION WITH OTHER N1 UNIT; 2.6 CONCLUSIONS; REFERENCES; Part II: [2+2] Cycloaddition; 3 Lewis Base Catalyzed Asymmetric Formal [2+2] Cycloadditions ; 3.1 INTRODUCTION3.2 β-LACTAMS: FORMAL [2+2] CYCLOADDITIONS INVOLVING IMINES; 3.3 β-LACTONES I: FORMAL [2+2] CYCLOADDITIONS INVOLVING ALDEHYDES/KETONES; 3.4 β-LACTONES II: FORMAL [2+2] CYCLOADDITION OF KETENES LEADING TO KETENE DIMERS; 3.4.1 Introduction or or; 3.4.2 Homodimerization; 3.4.3 Heterodimerization; 3.5 MISCELLANEOUS FORMAL [2+2] ASYMMETRIC CYCLOADDITION PROCESSES; 3.5.1 Other Heterocyclic Classes-Introduction; 3.5.2 Asymmetric Formal [2+2] Cycloadditions; 3.6 CONCLUSIONS; REFERENCES; Part III: [2+2] and [4+2]/[2+2] Cycloaddition; 4 Catalytic [2+2] Cycloaddition of Silyl Enol Ethers ; 4.1 INTRODUCTION4.2 CATALYTIC [2+2] CYCLOADDITION REACTIONS OF SILYL ENOL ETHERS BY LEWIS ACID CATALYST; 4.2.1 Introduction; 4.2.2 Intramolecular [2+2] Cycloaddition Reactions; 4.2.3 Intermolecular [2+2] Cycloaddition Reactions; 4.2.4 Asymmetric Catalytic [2+2] Cycloaddition Reaction with Silyl Enol Ethers; 4.3 CATALYTIC [2+2] CYCLOADDITION REACTIONS OF SILYL ENOL ETHERS BY BRØNSTED ACID; 4.3.1 Catalytic [2+2] Cycloaddition Reactions of Silyl Enol Ethers by Trifluoromethanesulfonimide; 4.3.2 Multigram Syntheses of Cyclobutanes and Cyclobutenes by [2+2] Cycloaddition Reactions ; 4.3.3 Analysis of the Mechanism for [2+2] Cycloaddition Reactions by Trifluoromethanesulfonimide
• Sommario/riassunto: Although these reactions have been studied for a long time, cycloaddition chemistry makes frequent and considerable advances that requires chemists to keep constantly up-to-date with the practices and state-of-the-art. Bringing together the contributions from leading worldwide researchers, Methods and Applications of Cycloaddition Reactions in Organic Syntheses provides a valuable guidebook for synthetic organic chemists involved in chemical research, pharmaceuticals, and materials science to keep organic chemists updated and current in the practices of cycloadditions, a leading class o
• Titolo autorizzato: Methods and applications of cycloaddition reactions in organic syntheses
• ISBN: 1-118-77820-0; 1-118-77817-0; 1-118-77818-9
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910138976903321
• Lo trovi qui: Univ. Federico II