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Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction
| Catalysts for fine chemical synthesis [[electronic resource] ] : hydrolysis, oxidation and reduction |
| Autore | Roberts Stanley M |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2003 |
| Descrizione fisica | 1 online resource (245 p.) |
| Disciplina |
660.634
660/.28443 |
| Altri autori (Persone) | PoignantGeraldine |
| Collana | Catalysts For Fine Chemicals Synthesis |
| Soggetto topico |
Catalysts
Chemistry, Organic Enzymes Hydrolysis Organic compounds Oxidation-reduction reaction Synthesis Biomedical Engineering Health & Biological Sciences |
| ISBN |
1-280-27032-2
9786610270323 0-470-36296-0 0-470-85579-7 0-470-85580-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 9 Asymmetric Reduction of Ketones Using Organometallic Catalysts |
| Record Nr. | UNINA-9910831084903321 |
Roberts Stanley M
|
||
| Hoboken, : Wiley, 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for fine chemical synthesis
| Catalysts for fine chemical synthesis |
| Pubbl/distr/stampa | Hoboken, : Wiley |
| Formato | Materiale a stampa |
| Livello bibliografico | Collezione |
| Lingua di pubblicazione | und |
| Record Nr. | UNICAMPANIA-VAN0117656 |
| Hoboken, : Wiley | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Vanvitelli | ||
| ||
Catalysts for fine chemical synthesis
| Catalysts for fine chemical synthesis |
| Pubbl/distr/stampa | Hoboken, : Wiley |
| Formato | Materiale a stampa |
| Livello bibliografico | Collezione |
| Lingua di pubblicazione | und |
| Record Nr. | UNICAMPANIA-VAN00117656 |
| Hoboken, : Wiley | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Vanvitelli | ||
| ||
Catalytic antibodies [[electronic resource]]
| Catalytic antibodies [[electronic resource]] |
| Pubbl/distr/stampa | Chichester ; ; New York, : Wiley, 1991 |
| Descrizione fisica | 1 online resource (272 p.) |
| Disciplina |
591.2
591.293 |
| Collana | Ciba Foundation symposium |
| Soggetto topico |
Monoclonal antibodies
Enzymes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-34772-1
9786612347726 0-470-51410-8 0-470-51411-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CATALYTIC ANTIBODIES; Contents; Introduction; A catalytic antibody uses a multistep kinetic sequence; Structural aspects of antibodies and antibody-antigen complexes; Nuclear magnetic resonance studies of antibody-antigen interactions; Modelling antibody combining sites: a review; Approaches to the design of semisynthetic metal-dependent catalytic antibodies; Construction of combinatorial antibody expression libraries in Escherichia coli; Catalytic antibodies: contributions from engineering and expression in Escherichia coli
The generation of antibody combining sites containing catalytic residuesGeneral discussion I; Screening combinatorial antibody libraries for catalytic acyl transfer reactions; Binding and multiple hydrolytic sites in epitopes recognized by catalytic anti-peptide antibodies; Antibody catalysis of carbon-carbon bond formation; Characterization of the mechanism of action of a catalytic antibody; Catalytic antibodies: a new window on protein chemistry; Expanded transition state analogues; Tritylase antibodies; Final general discussion : How good are catalytic antibodies? Potential uses of catalytic antibodiesSummary; Index of contributors; Subject index |
| Record Nr. | UNINA-9910144297403321 |
| Chichester ; ; New York, : Wiley, 1991 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic antibodies [[electronic resource]]
| Catalytic antibodies [[electronic resource]] |
| Pubbl/distr/stampa | Chichester ; ; New York, : Wiley, 1991 |
| Descrizione fisica | 1 online resource (272 p.) |
| Disciplina |
591.2
591.293 |
| Collana | Ciba Foundation symposium |
| Soggetto topico |
Monoclonal antibodies
Enzymes |
| ISBN |
1-282-34772-1
9786612347726 0-470-51410-8 0-470-51411-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CATALYTIC ANTIBODIES; Contents; Introduction; A catalytic antibody uses a multistep kinetic sequence; Structural aspects of antibodies and antibody-antigen complexes; Nuclear magnetic resonance studies of antibody-antigen interactions; Modelling antibody combining sites: a review; Approaches to the design of semisynthetic metal-dependent catalytic antibodies; Construction of combinatorial antibody expression libraries in Escherichia coli; Catalytic antibodies: contributions from engineering and expression in Escherichia coli
The generation of antibody combining sites containing catalytic residuesGeneral discussion I; Screening combinatorial antibody libraries for catalytic acyl transfer reactions; Binding and multiple hydrolytic sites in epitopes recognized by catalytic anti-peptide antibodies; Antibody catalysis of carbon-carbon bond formation; Characterization of the mechanism of action of a catalytic antibody; Catalytic antibodies: a new window on protein chemistry; Expanded transition state analogues; Tritylase antibodies; Final general discussion : How good are catalytic antibodies? Potential uses of catalytic antibodiesSummary; Index of contributors; Subject index |
| Record Nr. | UNINA-9910830358603321 |
| Chichester ; ; New York, : Wiley, 1991 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic antibodies
| Catalytic antibodies |
| Pubbl/distr/stampa | Chichester ; ; New York, : Wiley, 1991 |
| Descrizione fisica | 1 online resource (272 p.) |
| Disciplina | 574.2/93 |
| Collana | Ciba Foundation symposium |
| Soggetto topico |
Monoclonal antibodies
Enzymes |
| ISBN |
1-282-34772-1
9786612347726 0-470-51410-8 0-470-51411-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CATALYTIC ANTIBODIES; Contents; Introduction; A catalytic antibody uses a multistep kinetic sequence; Structural aspects of antibodies and antibody-antigen complexes; Nuclear magnetic resonance studies of antibody-antigen interactions; Modelling antibody combining sites: a review; Approaches to the design of semisynthetic metal-dependent catalytic antibodies; Construction of combinatorial antibody expression libraries in Escherichia coli; Catalytic antibodies: contributions from engineering and expression in Escherichia coli
The generation of antibody combining sites containing catalytic residuesGeneral discussion I; Screening combinatorial antibody libraries for catalytic acyl transfer reactions; Binding and multiple hydrolytic sites in epitopes recognized by catalytic anti-peptide antibodies; Antibody catalysis of carbon-carbon bond formation; Characterization of the mechanism of action of a catalytic antibody; Catalytic antibodies: a new window on protein chemistry; Expanded transition state analogues; Tritylase antibodies; Final general discussion : How good are catalytic antibodies? Potential uses of catalytic antibodiesSummary; Index of contributors; Subject index |
| Record Nr. | UNINA-9910876913003321 |
| Chichester ; ; New York, : Wiley, 1991 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic asymmetric synthesis / edited by Iwao Ojima
| Catalytic asymmetric synthesis / edited by Iwao Ojima |
| Autore | Ojima, Iwao |
| Edizione | [3. ed] |
| Pubbl/distr/stampa | Hoboken : Wiley, 2010 |
| Descrizione fisica | XVII, 998 p. ; 24 cm. |
| Disciplina | 547.215 |
| Soggetto topico |
Catalisi
Reazioni chimiche |
| ISBN | 978-0-470-17577-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNIBAS-000033646 |
|
Ojima, Iwao
|
||
| Hoboken : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. della Basilicata | ||
| ||
Catalytic asymmetric synthesis / / edited by Takahiko Akiyama and Iwao Ojima
| Catalytic asymmetric synthesis / / edited by Takahiko Akiyama and Iwao Ojima |
| Edizione | [Fourth edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2022] |
| Descrizione fisica | 1 online resource (909 pages) |
| Disciplina | 541.39 |
| Soggetto topico |
Asymmetric synthesis
Catalysis |
| ISBN |
1-119-73642-0
1-119-73640-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Preface to the First Edition -- List of Contributors -- Part I Asymmetric Organocatalysis -- Chapter 1 Asymmetric Enamine and Iminium Ion Catalysis -- 1.1. Introduction -- 1.2. Representative Organocatalysts -- 1.2.1. Introduction -- 1.2.2. Reactivity of Diphenylprolinol Silyl Ether Catalyst and MacMillan's Catalyst -- 1.2.3. Cinchona Amine-Based Catalysts -- 1.3. Enamine -- 1.3.1. Aldol Reaction -- 1.3.2. Mannich Reaction -- 1.3.3. Other Functionalization of the -Position of Carbonyl Groups -- 1.3.4. Michael Reaction -- 1.3.5. Dienamine and Trienamine as an Intermediate [33] -- 1.4. Iminium Ion -- 1.4.1. Introduction of an Iminium Ion -- 1.4.2. Two Reaction Paths -- 1.4.3. Diels-Alder Type Reaction -- 1.4.4. Michael Reaction -- 1.5. Domino Reaction -- 1.5.1. Introduction of Domino (Cascade and Tandem) Reactions -- 1.5.2. Enders' Work -- 1.6. Domino Reaction and Total Synthesis -- 1.6.1. Steroid Skeleton -- 1.6.2. -Skytanthine and Quinine -- 1.6.3. (+)-Lycoposerramine Z -- 1.6.4. Estradiol Methyl Ether -- 1.6.5. MacMillan's Alkaloid Synthesis -- 1.6.6. Prostaglandin E1 Methyl Ester -- 1.6.7. Corey Lactone -- 1.7. Combination of Two Catalysts -- 1.7.1. Combination of Two Organocatalysts -- 1.7.2. Combination of Organocatalyst and Metal Catalyst -- 1.7.3. Two Chiral Catalysts -- 1.8. Conclusion -- References -- Chapter 2 Asymmetric Acid Organocatalysis -- 2.1. Introduction -- 2.2. Features of Chiral Brønsted Acids -- 2.2.1. Acidity of Chiral Brønsted Acids -- 2.2.2. Mode of Activation of Chiral Phosphoric Acids and Related Compounds -- 2.2.3. Effect of Metal Salts -- 2.3. Nucleophilic Reactions -- 2.3.1. Reactions with Imines and Iminium Salts -- 2.3.2. Reactions with Carbonyl Compounds and Oxonium Salts -- 2.4. Cycloaddition Reactions -- 2.4.1. Diels-Alder Reactions.
2.4.2. Aza-Diels-Alder Reactions -- 2.4.3. Oxa-Diels-Alder Reactions -- 2.4.4. Other Cycloaddition Reactions -- 2.4.5. Nazarov Cyclizations -- 2.5. Michael Reactions -- 2.6. Reduction -- 2.6.1. Reduction of Imines -- 2.6.2. Reduction of Ketones -- 2.6.3. Reduction of Alkenes -- 2.7. Addition to Alkenes -- 2.8. Substitution Reactions -- 2.9. Rearrangement Reactions -- 2.10. Miscellaneous Reactions -- 2.11. Construction of Axially, Planar, and Helically Chiral Compounds -- 2.12. Combination with Transition Metal Catalysts [25-27] -- 2.13. Combination with Photoredox Catalyst -- 2.14. Conclusion -- Acknowledgments -- References -- Chapter 3 Asymmetric Base Organocatalysis -- 3.1. Introduction -- 3.2. Chiral Tertiary Amine Catalysts: Chiral Acid-Base Bifunctional Catalysis -- 3.2.1. Application of Designed Pronucleophiles -- 3.2.2. Carbon-Heteroatom Bond Formations -- 3.2.3. Other Applications -- 3.3. Chiral Guanidine Catalysts -- 3.4. Other Chiral Uncharged Organobase Catalysts: Chiral Organosuperbases -- 3.4.1. Chiral Cyclopropenimine Catalysts -- 3.4.2. Chiral Triaryliminophosphorane Catalysts -- 3.4.3. Chiral P1-Phosphazene Catalysts -- 3.4.4. Chiral Higher-Order Phosphazene Catalysts -- 3.5. Conclusion and Outlook -- References -- Chapter 4 Asymmetric Phase-Transfer and Ion-Pair Organocatalyses -- 4.1. Introduction -- 4.2. Chiral Cation -- 4.2.1. Chiral Cation Phase-Transfer Catalysis -- 4.2.2. Transition-Metal/Chiral Cation Dual Catalysis -- 4.2.3. Cation-Binding Catalysis -- 4.3. Chiral-Anion -- 4.3.1. Iminium -- 4.3.2. Oxocarbenium -- 4.3.3. Carbocation -- 4.3.4. Miscellaneous -- 4.3.5. Chiral-Anion Phase Transfer -- 4.3.6. Transition-Metal/Chiral-Anion Dual Catalysis -- 4.3.7. Anion-Binding Catalysis -- 4.4. Conclusion -- References -- Chapter 5 Asymmetric Peptide Catalysis -- 5.1 Introduction. 5.2 Catalysis by N-Terminal Amino Group of Peptides -- 5.2.1 Enamine Catalysis -- 5.2.2 Iminium Ion Catalysis -- 5.2.3 Other Type of Peptide Catalysts That Utilize Terminal Amino Groups -- 5.3 Catalysis by Side Chain Functional Group on Peptides -- 5.3.1 Histidine-Based Peptide Catalysis -- 5.3.2 Aspartate/Glutamate-Based Peptide Catalysis -- 5.3.3 Arg/Lys-Based Peptide Catalysis -- 5.3.4 Cysteine-Based Peptide Catalysis -- 5.4 Catalysis by Functional Groups Covalently Bound to Peptides -- 5.4.1 Peptide Catalysts That Have Catalytic Center Connected to N-Terminal -- 5.4.2. Peptide Catalysts That Have Catalytic Center on Side Chain of Amino Acid -- 5.5 Peptide Catalysis with Other Types of Catalytic Centers -- 5.6 Conclusion -- References -- Chapter 6 Asymmetric Carbene Catalysis: A Brief Highlight of Developments in the Past Decade -- 6.1. Early Development of Asymmetric NHC Catalysis -- 6.1.1. Early Discoveries on NHC-Mediated Reactions: Benzoin and Related Reactions via Acyl Anion Intermediates -- 6.1.2. Moving from Simple Aldehydes to Enals and -Functionalized Aldehydes: A Key Progress During the First Decade of This Century -- 6.1.3. Remaining Challenges When the Last Decade Started -- 6.2. Activation of Substrates beyond Aldehydes -- 6.2.1. Activations of Stable Carboxylic Esters -- 6.2.2. Activation of Ketenes -- 6.2.3. Activation of Imines -- 6.2.4. Activation of Other Substrates -- 6.3. Single-Electron Transfer Activation and Radical Reactions -- 6.3.1. Oxidation of Aldehydes to Esters -- 6.3.2. Reductive Coupling Reactions Involving Nitroalkenes and Nitrobenzyl Bromides -- 6.3.3. Activation of Enal on -Carbon via SET for Asymmetric Reactions -- 6.3.4. Radical-Radical Coupling via NHC-Catalyzed Activation of Aldehydes -- 6.3.5. Visible-Light-Driven Radical Reactions -- 6.4. NHC as Non-Covalent (Brønsted Base) Catalysts. 6.5. Cooperative Catalysis of NHCs with Other Catalysts -- 6.5.1. Dual Catalysis of NHC Organocatalysts and Transition Metal Catalysts -- 6.5.2. Dual Catalysis of NHC Organocatalysts and Lewis Acid Co-catalysts/Additives -- 6.5.3. Dual Catalysis of NHC Organocatalysts and Brønsted Acids -- 6.5.4. Dual Catalysis of NHC Organocatalysts and Other Catalysts -- 6.6. Synthetic Applications of NHC Catalysis -- 6.6.1. Kinetic Resolution and Desymmetrization -- 6.6.2. NHC Catalysis in Natural Product Synthesis -- 6.7. Summary and Outlook -- References -- Chapter 7 Asymmetric Hypervalent Iodine Catalysis -- 7.1 Introduction -- 7.2 Oxidative Dearomative Coupling of Arenols -- 7.3 Oxidative -Functionalization of Carbonyl Compounds -- 7.4 Oxidative Difunctionalizaiton of Alkenes -- 7.5 Conclusion and Outlook -- References -- Part II Asymmetric Photochemical Reactions and Photoredox Catalysis -- Chapter 8 Asymmetric Visible-Light Photoredox Catalysis -- 8.1. Introduction -- 8.2. Dual Catalysis Approach -- 8.2.1. Lewis Base Catalysis -- 8.2.2. Hydrogen-Bonding Catalysis -- 8.2.3. Brønsted Base Catalysis -- 8.2.4. Brønsted Acid Catalysis -- 8.2.5. Lewis Acid Catalysis -- 8.2.6. Phase-Transfer Catalysis -- 8.3. Single Bifunctional Catalyst Approach -- 8.3.1. Chiral Organophotocatalysts -- 8.3.2. Chiral Organometallic Photocatalysts -- 8.4. Conclusion -- References -- Chapter 9 Asymmetric Photoredox Reactions without Photocatalysts -- 9.1. General Introduction -- 9.2 Photoexcitation of Organocatalytic Intermediates -- 9.2.1 Enamine Catalysis in EDA Complex Photoactivation -- 9.2.2 Phase Transfer Catalysis in EDA Complex Photoactivation -- 9.2.3 Iminium Ion Catalysis in EDA Complex Photoactivation -- 9.2.4 Direct Photoexcitation of Enamines -- 9.2.5 Direct Photoexcitation of Iminium Ions -- 9.3 Photoexcitation of Metal-Based Intermediates. 9.3.1 Use of Chiral Lewis Acids to Form Photoactive Intermediates -- 9.3.2 Photoexcitation of Organometallic Intermediates -- 9.4 Photochemistry and Biocatalysis -- 9.4.1 EDA Complex Photochemistry and Enzymatic Catalysis -- 9.4.2 Direct Photoexcitation Strategies in Enzymatic Catalysis -- 9.5 Methods Based on the Direct Excitation of Substrates -- 9.6 Conclusions -- Acknowledgments -- References -- Chapter 10 Enantioselective Photochemical [2+2] Cycloaddition Reactions -- 10.1. Introduction -- 10.2. Chiral Organocatalysts -- 10.2.1. Xanthone and Thioxanthone -- 10.2.2. Thioureas -- 10.2.3. Brønsted Acids -- 10.2.4. Iminium Ions -- 10.3. Chiral Metal Catalysts -- 10.3.1. Transition Metals and Lanthanides -- 10.3.2. AlBr3-Activated Oxazaborolidines -- 10.4. Dual Catalysis -- 10.4.1. Electron Transfer -- 10.4.2. Energy Transfer -- 10.5. Chiral METAL-ORGANIC Cages -- 10.6. Concluding Remarks -- Acknowledgments -- References -- Part III Asymmetric Synthesis Through C-H Bond Activation -- Chapter 11 Asymmetric C-H Functionalization of C(sp2)-H Bond -- 11.1. Introduction -- 11.2. Palladium Catalysis -- 11.2.1. Phosphorus-Based Ligands -- 11.2.2. Monoprotected Amino Acids as Chiral Ligands -- 11.2.3. Other Ligands -- 11.2.4. Chiral Transient Auxiliary -- 11.2.5. Chiral Auxiliaries -- 11.2.6. Cooperative Catalysis -- 11.2.7. Electrochemical CH Activations -- 11.3. Rhodium Catalysis -- 11.3.1. Chiral Cpx-Based Catalysts -- 11.3.2. In-Situ Generated Chiral Complexes -- 11.3.3. Other Strategies -- 11.4. Iridium Catalysis -- 11.4.1. C-C Bond Formations -- 11.4.2. CH Borylations -- 11.4.3. CH Silylations -- 11.5. Ruthenium Catalysis -- 11.5.1. Chiral Amine as the TDG -- 11.5.2. Chiral Acid -- 11.6. Scandium Catalysis -- 11.7. Nickel Catalysis -- 11.7.1. Formyl C-H Activation -- 11.7.2. Intramolecular Reactions -- 11.7.3. Intermolecular Reactions. 11.8. Cobalt Catalysis. |
| Record Nr. | UNINA-9910580254103321 |
| Hoboken, New Jersey : , : Wiley, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic asymmetric synthesis / / edited by Takahiko Akiyama and Iwao Ojima
| Catalytic asymmetric synthesis / / edited by Takahiko Akiyama and Iwao Ojima |
| Edizione | [Fourth edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2022] |
| Descrizione fisica | 1 online resource (909 pages) |
| Disciplina | 541.39 |
| Soggetto topico |
Asymmetric synthesis
Catalysis |
| ISBN |
1-119-73641-2
1-119-73642-0 1-119-73640-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Preface to the First Edition -- List of Contributors -- Part I Asymmetric Organocatalysis -- Chapter 1 Asymmetric Enamine and Iminium Ion Catalysis -- 1.1. Introduction -- 1.2. Representative Organocatalysts -- 1.2.1. Introduction -- 1.2.2. Reactivity of Diphenylprolinol Silyl Ether Catalyst and MacMillan's Catalyst -- 1.2.3. Cinchona Amine-Based Catalysts -- 1.3. Enamine -- 1.3.1. Aldol Reaction -- 1.3.2. Mannich Reaction -- 1.3.3. Other Functionalization of the -Position of Carbonyl Groups -- 1.3.4. Michael Reaction -- 1.3.5. Dienamine and Trienamine as an Intermediate [33] -- 1.4. Iminium Ion -- 1.4.1. Introduction of an Iminium Ion -- 1.4.2. Two Reaction Paths -- 1.4.3. Diels-Alder Type Reaction -- 1.4.4. Michael Reaction -- 1.5. Domino Reaction -- 1.5.1. Introduction of Domino (Cascade and Tandem) Reactions -- 1.5.2. Enders' Work -- 1.6. Domino Reaction and Total Synthesis -- 1.6.1. Steroid Skeleton -- 1.6.2. -Skytanthine and Quinine -- 1.6.3. (+)-Lycoposerramine Z -- 1.6.4. Estradiol Methyl Ether -- 1.6.5. MacMillan's Alkaloid Synthesis -- 1.6.6. Prostaglandin E1 Methyl Ester -- 1.6.7. Corey Lactone -- 1.7. Combination of Two Catalysts -- 1.7.1. Combination of Two Organocatalysts -- 1.7.2. Combination of Organocatalyst and Metal Catalyst -- 1.7.3. Two Chiral Catalysts -- 1.8. Conclusion -- References -- Chapter 2 Asymmetric Acid Organocatalysis -- 2.1. Introduction -- 2.2. Features of Chiral Brønsted Acids -- 2.2.1. Acidity of Chiral Brønsted Acids -- 2.2.2. Mode of Activation of Chiral Phosphoric Acids and Related Compounds -- 2.2.3. Effect of Metal Salts -- 2.3. Nucleophilic Reactions -- 2.3.1. Reactions with Imines and Iminium Salts -- 2.3.2. Reactions with Carbonyl Compounds and Oxonium Salts -- 2.4. Cycloaddition Reactions -- 2.4.1. Diels-Alder Reactions.
2.4.2. Aza-Diels-Alder Reactions -- 2.4.3. Oxa-Diels-Alder Reactions -- 2.4.4. Other Cycloaddition Reactions -- 2.4.5. Nazarov Cyclizations -- 2.5. Michael Reactions -- 2.6. Reduction -- 2.6.1. Reduction of Imines -- 2.6.2. Reduction of Ketones -- 2.6.3. Reduction of Alkenes -- 2.7. Addition to Alkenes -- 2.8. Substitution Reactions -- 2.9. Rearrangement Reactions -- 2.10. Miscellaneous Reactions -- 2.11. Construction of Axially, Planar, and Helically Chiral Compounds -- 2.12. Combination with Transition Metal Catalysts [25-27] -- 2.13. Combination with Photoredox Catalyst -- 2.14. Conclusion -- Acknowledgments -- References -- Chapter 3 Asymmetric Base Organocatalysis -- 3.1. Introduction -- 3.2. Chiral Tertiary Amine Catalysts: Chiral Acid-Base Bifunctional Catalysis -- 3.2.1. Application of Designed Pronucleophiles -- 3.2.2. Carbon-Heteroatom Bond Formations -- 3.2.3. Other Applications -- 3.3. Chiral Guanidine Catalysts -- 3.4. Other Chiral Uncharged Organobase Catalysts: Chiral Organosuperbases -- 3.4.1. Chiral Cyclopropenimine Catalysts -- 3.4.2. Chiral Triaryliminophosphorane Catalysts -- 3.4.3. Chiral P1-Phosphazene Catalysts -- 3.4.4. Chiral Higher-Order Phosphazene Catalysts -- 3.5. Conclusion and Outlook -- References -- Chapter 4 Asymmetric Phase-Transfer and Ion-Pair Organocatalyses -- 4.1. Introduction -- 4.2. Chiral Cation -- 4.2.1. Chiral Cation Phase-Transfer Catalysis -- 4.2.2. Transition-Metal/Chiral Cation Dual Catalysis -- 4.2.3. Cation-Binding Catalysis -- 4.3. Chiral-Anion -- 4.3.1. Iminium -- 4.3.2. Oxocarbenium -- 4.3.3. Carbocation -- 4.3.4. Miscellaneous -- 4.3.5. Chiral-Anion Phase Transfer -- 4.3.6. Transition-Metal/Chiral-Anion Dual Catalysis -- 4.3.7. Anion-Binding Catalysis -- 4.4. Conclusion -- References -- Chapter 5 Asymmetric Peptide Catalysis -- 5.1 Introduction. 5.2 Catalysis by N-Terminal Amino Group of Peptides -- 5.2.1 Enamine Catalysis -- 5.2.2 Iminium Ion Catalysis -- 5.2.3 Other Type of Peptide Catalysts That Utilize Terminal Amino Groups -- 5.3 Catalysis by Side Chain Functional Group on Peptides -- 5.3.1 Histidine-Based Peptide Catalysis -- 5.3.2 Aspartate/Glutamate-Based Peptide Catalysis -- 5.3.3 Arg/Lys-Based Peptide Catalysis -- 5.3.4 Cysteine-Based Peptide Catalysis -- 5.4 Catalysis by Functional Groups Covalently Bound to Peptides -- 5.4.1 Peptide Catalysts That Have Catalytic Center Connected to N-Terminal -- 5.4.2. Peptide Catalysts That Have Catalytic Center on Side Chain of Amino Acid -- 5.5 Peptide Catalysis with Other Types of Catalytic Centers -- 5.6 Conclusion -- References -- Chapter 6 Asymmetric Carbene Catalysis: A Brief Highlight of Developments in the Past Decade -- 6.1. Early Development of Asymmetric NHC Catalysis -- 6.1.1. Early Discoveries on NHC-Mediated Reactions: Benzoin and Related Reactions via Acyl Anion Intermediates -- 6.1.2. Moving from Simple Aldehydes to Enals and -Functionalized Aldehydes: A Key Progress During the First Decade of This Century -- 6.1.3. Remaining Challenges When the Last Decade Started -- 6.2. Activation of Substrates beyond Aldehydes -- 6.2.1. Activations of Stable Carboxylic Esters -- 6.2.2. Activation of Ketenes -- 6.2.3. Activation of Imines -- 6.2.4. Activation of Other Substrates -- 6.3. Single-Electron Transfer Activation and Radical Reactions -- 6.3.1. Oxidation of Aldehydes to Esters -- 6.3.2. Reductive Coupling Reactions Involving Nitroalkenes and Nitrobenzyl Bromides -- 6.3.3. Activation of Enal on -Carbon via SET for Asymmetric Reactions -- 6.3.4. Radical-Radical Coupling via NHC-Catalyzed Activation of Aldehydes -- 6.3.5. Visible-Light-Driven Radical Reactions -- 6.4. NHC as Non-Covalent (Brønsted Base) Catalysts. 6.5. Cooperative Catalysis of NHCs with Other Catalysts -- 6.5.1. Dual Catalysis of NHC Organocatalysts and Transition Metal Catalysts -- 6.5.2. Dual Catalysis of NHC Organocatalysts and Lewis Acid Co-catalysts/Additives -- 6.5.3. Dual Catalysis of NHC Organocatalysts and Brønsted Acids -- 6.5.4. Dual Catalysis of NHC Organocatalysts and Other Catalysts -- 6.6. Synthetic Applications of NHC Catalysis -- 6.6.1. Kinetic Resolution and Desymmetrization -- 6.6.2. NHC Catalysis in Natural Product Synthesis -- 6.7. Summary and Outlook -- References -- Chapter 7 Asymmetric Hypervalent Iodine Catalysis -- 7.1 Introduction -- 7.2 Oxidative Dearomative Coupling of Arenols -- 7.3 Oxidative -Functionalization of Carbonyl Compounds -- 7.4 Oxidative Difunctionalizaiton of Alkenes -- 7.5 Conclusion and Outlook -- References -- Part II Asymmetric Photochemical Reactions and Photoredox Catalysis -- Chapter 8 Asymmetric Visible-Light Photoredox Catalysis -- 8.1. Introduction -- 8.2. Dual Catalysis Approach -- 8.2.1. Lewis Base Catalysis -- 8.2.2. Hydrogen-Bonding Catalysis -- 8.2.3. Brønsted Base Catalysis -- 8.2.4. Brønsted Acid Catalysis -- 8.2.5. Lewis Acid Catalysis -- 8.2.6. Phase-Transfer Catalysis -- 8.3. Single Bifunctional Catalyst Approach -- 8.3.1. Chiral Organophotocatalysts -- 8.3.2. Chiral Organometallic Photocatalysts -- 8.4. Conclusion -- References -- Chapter 9 Asymmetric Photoredox Reactions without Photocatalysts -- 9.1. General Introduction -- 9.2 Photoexcitation of Organocatalytic Intermediates -- 9.2.1 Enamine Catalysis in EDA Complex Photoactivation -- 9.2.2 Phase Transfer Catalysis in EDA Complex Photoactivation -- 9.2.3 Iminium Ion Catalysis in EDA Complex Photoactivation -- 9.2.4 Direct Photoexcitation of Enamines -- 9.2.5 Direct Photoexcitation of Iminium Ions -- 9.3 Photoexcitation of Metal-Based Intermediates. 9.3.1 Use of Chiral Lewis Acids to Form Photoactive Intermediates -- 9.3.2 Photoexcitation of Organometallic Intermediates -- 9.4 Photochemistry and Biocatalysis -- 9.4.1 EDA Complex Photochemistry and Enzymatic Catalysis -- 9.4.2 Direct Photoexcitation Strategies in Enzymatic Catalysis -- 9.5 Methods Based on the Direct Excitation of Substrates -- 9.6 Conclusions -- Acknowledgments -- References -- Chapter 10 Enantioselective Photochemical [2+2] Cycloaddition Reactions -- 10.1. Introduction -- 10.2. Chiral Organocatalysts -- 10.2.1. Xanthone and Thioxanthone -- 10.2.2. Thioureas -- 10.2.3. Brønsted Acids -- 10.2.4. Iminium Ions -- 10.3. Chiral Metal Catalysts -- 10.3.1. Transition Metals and Lanthanides -- 10.3.2. AlBr3-Activated Oxazaborolidines -- 10.4. Dual Catalysis -- 10.4.1. Electron Transfer -- 10.4.2. Energy Transfer -- 10.5. Chiral METAL-ORGANIC Cages -- 10.6. Concluding Remarks -- Acknowledgments -- References -- Part III Asymmetric Synthesis Through C-H Bond Activation -- Chapter 11 Asymmetric C-H Functionalization of C(sp2)-H Bond -- 11.1. Introduction -- 11.2. Palladium Catalysis -- 11.2.1. Phosphorus-Based Ligands -- 11.2.2. Monoprotected Amino Acids as Chiral Ligands -- 11.2.3. Other Ligands -- 11.2.4. Chiral Transient Auxiliary -- 11.2.5. Chiral Auxiliaries -- 11.2.6. Cooperative Catalysis -- 11.2.7. Electrochemical CH Activations -- 11.3. Rhodium Catalysis -- 11.3.1. Chiral Cpx-Based Catalysts -- 11.3.2. In-Situ Generated Chiral Complexes -- 11.3.3. Other Strategies -- 11.4. Iridium Catalysis -- 11.4.1. C-C Bond Formations -- 11.4.2. CH Borylations -- 11.4.3. CH Silylations -- 11.5. Ruthenium Catalysis -- 11.5.1. Chiral Amine as the TDG -- 11.5.2. Chiral Acid -- 11.6. Scandium Catalysis -- 11.7. Nickel Catalysis -- 11.7.1. Formyl C-H Activation -- 11.7.2. Intramolecular Reactions -- 11.7.3. Intermolecular Reactions. 11.8. Cobalt Catalysis. |
| Record Nr. | UNINA-9910677532303321 |
| Hoboken, New Jersey : , : Wiley, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic asymmetric synthesis / / edited by Iwao Ojima
| Catalytic asymmetric synthesis / / edited by Iwao Ojima |
| Edizione | [3rd ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (1018 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | OjimaIwao <1945-> |
| Soggetto topico |
Asymmetric synthesis
Catalysis Síntesi asimètrica Catàlisi |
| Soggetto genere / forma | Llibres electrònics |
| ISBN |
1-118-67844-3
1-282-49173-3 9786612491733 0-470-58424-6 0-470-58423-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CATALYTIC ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Preface to the Second Edition; Preface to the First Edition; Contributors; 1 Catalytic Asymmetric Synthesis in Nonconventional Media/Conditions; 2 Asymmetric Organocatalysis; 2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO, and Photoredox Activation; 2B Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules; 2C Asymmetric Phase-Transfer and Ion Pair Catalysis; 3 Chiral Lewis Acids and Brønsted Acids in Asymmetric Synthesis; 4 Asymmetric Synthesis through C-H Activation
5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions6 Enzyme-Catalyzed Asymmetric Synthesis; 7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation; 8 Asymmetric Carbon-Carbon Bond-Forming Reactions; 8A Catalytic Asymmetric Conjugate Addition; 8B Enantioselective Allylic Substitutions with Carbon Nucleophiles; 8C Asymmetric Carbometallation and Carbocyclizations; 8D Asymmetric Ene Reactions and Cycloadditions; 8E Catalytic Enantioselective Olefin Metathesis Reactions; 9 Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds and Related Reactions; 10 Asymmetric Carbonylations 11 Asymmetric Oxidations and Related Reactions12 Asymmetric Amplification and Autocatalysis; 13 Asymmetric Polymerization; Index |
| Record Nr. | UNINA-9910140615303321 |
| Hoboken, NJ, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
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