Advanced inorganic chemistry / F. Albert Cotton ... [et al.] |
Edizione | [6. ed] |
Pubbl/distr/stampa | New York [etc.], : John Wiley & sons, c1999 |
Descrizione fisica | XV, 1355 p. : ill. ; 26 cm |
Disciplina | 546 |
Collana | Wiley interscience publication |
Soggetto topico | Chimica inorganica |
ISBN | 0471199575 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNISANNIO-MIL0429660 |
New York [etc.], : John Wiley & sons, c1999 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. del Sannio | ||
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Advances in functional inorganic materials prepared by wet chemical methods / / edited by Aleksej Zarkov, Aivaras Kareiva and Loreta Tamasauskaite-Tamasiunaite |
Pubbl/distr/stampa | Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022 |
Descrizione fisica | 1 online resource (154 pages) |
Disciplina | 546 |
Soggetto topico |
Chemistry, Inorganic
Chemistry |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910674373003321 |
Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
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Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (388 p.) |
Disciplina | 546 |
Collana | Advances in Inorganic Chemistry |
Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
Soggetto genere / forma | Electronic books. |
ISBN | 0-12-801837-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
Record Nr. | UNINA-9910460523103321 |
Waltham, Massachusetts : , : Academic Press, , 2015 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (388 p.) |
Disciplina | 546 |
Collana | Advances in Inorganic Chemistry |
Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
ISBN | 0-12-801837-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
Record Nr. | UNINA-9910787446903321 |
Waltham, Massachusetts : , : Academic Press, , 2015 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (388 p.) |
Disciplina | 546 |
Collana | Advances in Inorganic Chemistry |
Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
ISBN | 0-12-801837-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
Record Nr. | UNINA-9910814434003321 |
Waltham, Massachusetts : , : Academic Press, , 2015 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
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Advances in inorganic chemistry / editor A. G. Sykes |
Pubbl/distr/stampa | San Diego [etc.] : Academic Press, [198-?] |
Descrizione fisica | volumi : ill. ; 23 cm |
Disciplina | 546 |
Soggetto topico | Chimica inorganica |
ISBN |
0-02-023637-0
0-12-023636-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Vol. 36.- XIII, 503 p. Vol. 37. - VII, 411 p. |
Record Nr. | UNISA-990000179530203316 |
San Diego [etc.] : Academic Press, [198-?] | ||
Materiale a stampa | ||
Lo trovi qui: Univ. di Salerno | ||
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Advances in inorganic chemistry and radiochemistry / Editors H.J. Emeleus, A.G. Sharpe |
Autore | Emeleus, H.J. |
Pubbl/distr/stampa | New York : Academic Press, 1959-1966 |
Disciplina | 546 |
Soggetto non controllato | Chimica inorganica |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-990000988360403321 |
Emeleus, H.J. | ||
New York : Academic Press, 1959-1966 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
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Advances in inorganic chemistry and radiochemistry / Editors: H. J. Emelèus, A. G. Sharpe |
Pubbl/distr/stampa | New York : Academic Press, 19.. |
Descrizione fisica | v. : ill. ; 23 cm |
Disciplina | 546 |
Soggetto non controllato | Chimica inorganica |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNISA-990000100840203316 |
New York : Academic Press, 19.. | ||
Materiale a stampa | ||
Lo trovi qui: Univ. di Salerno | ||
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Advances in Lead-Free Piezoelectric Materials / Jiagang Wu |
Autore | Wu, Jiagang |
Pubbl/distr/stampa | Singapore, : Springer, 2018 |
Descrizione fisica | XI, 522 p. : ill. ; 24 cm |
Disciplina |
621.36(Ingegneria ottica. Ottica applicata)
530.417(Fisica superficiale) 546(Chimica inorganica) 628(Ingegneria ambientale. Sostenibilità dell'ambiente) 620.1(Scienze dei materiali) 530.4175(Film sottili) |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNICAMPANIA-VAN0125736 |
Wu, Jiagang | ||
Singapore, : Springer, 2018 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Vanvitelli | ||
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Advances in Lead-Free Piezoelectric Materials / Jiagang Wu |
Autore | Wu, Jiagang |
Edizione | [Singapore : Springer, 2018] |
Pubbl/distr/stampa | XI, 522 p., : ill. ; 24 cm |
Descrizione fisica | Pubblicazione in formato elettronico |
Disciplina |
621.36(Ingegneria ottica. Ottica applicata)
530.417(Fisica superficiale) 546(Chimica inorganica) 628(Ingegneria ambientale. Sostenibilità dell'ambiente) 620.1(Scienza dei materiali) 530.4175(Film sottili) |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNICAMPANIA-SUN0125736 |
Wu, Jiagang | ||
XI, 522 p., : ill. ; 24 cm | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Vanvitelli | ||
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