Silicon-based inorganic polymers / / Roger De Jaeger and Mario Gleria, editors

• Pubblicazione: New York, : Nova Science Publishers, c2008
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (516 p.)
• Disciplina: 547/.7
• Soggetto topico: Silicon polymers; Inorganic polymers
• Altri autori: JaegerRoger De GleriaMario
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- SILICON-BASED INORGANICPOLYMERS -- NOTICE TO THE READER -- CONTENTS -- PREFACE -- GENERAL REVIEW ON POLYSILOXANE SYNTHESIS -- ABBREVIATIONS -- INTRODUCTION -- THE ELECTRONIC STRUCTURE OF THE SILOXANE BOND -- REACTIVITY OF THE SILOXANE BOND -- PROPERTIES AND APPLICATIONS -- Thermal and Chemical Stability -- Elastomeric Properties -- Surface Properties -- Dielectric Properties -- Biocompatibility -- High Technology Applications -- Functional Silanes - Precursors to Polysiloxanes -- Industrial Synthesis of Polysiloxanes -- POLYSILOXANES BY POLYCONDENSATION ROUTES -- Hydrolytic Polycondensation of Chlorosilanes -- Hydrolytic Polycondensation of Alkoxysilanes -- Homofunctional Polycondensation of Silanols -- Heterofunctional Condensation Involving Silanol Groups -- Non-Hydrolytic Ways of Siloxane Synthesis -- Electrochemical Synthesis of Oligosiloxanes -- Ring-Opening Polymerization of Cyclosiloxanes -- Non-Equilibrium (Kinetically Controlled) ROP of Cyclosiloxanes -- Anionic Ring Opening Polymerization of Cyclosiloxanes -- Cationic Ring Opening Polymerization of Cyclosiloxanes -- Other Methods of Polymerization of Cyclosiloxanes -- Siloxane Functional Polymers and Copolymers -- Three-Dimensional Polysiloxane Architectures: Silsesquioxanes, Hyperbranched Polymers and Dendrimers -- CLOSING REMARKS -- REFERENCES -- SILICONES IN INDUSTRIAL APPLICATIONS -- ABSTRACT -- 1. INTRODUCTION -- Nomenclature -- Physicochemical Properties -- 2. CHARACTERIZATION OF SILICONES -- Common Methods Applied to the Analysis of Silicones -- Application Specific Methods for the Analysis of Silicones -- 3. SILICONE IN THE FOOD INDUSTRIES -- Polydimethylsiloxanes as Surface-Active Ingredients in Antifoams -- Food and Beverage -- Silicone Lubricating Oil in Food Processing -- 4. SILICONES IN THE PULP AND PAPER INDUSTRY. ; Antifoam in the Pulp-Washing Process or Brownstock Washing -- Silicone Finishes in Tissue Converting -- 5. SILICONES IN THE TEXTILE INDUSTRIES -- Silicones in Fiber Production -- Silicone as Fabric Softeners -- Silicones as Process Aids -- Silicones as Hydrophobic Agents -- Silicones in Fabric Coatings -- 6. SILICONES IN HOUSEHOLD CLEANING APPLICATIONS -- Silicones as Foam Control Agents -- Silicones for Delivering Fabric Care Benefits -- 7. SILICONES IN COATINGS -- Silicones as Performance-Enhancing Additives -- Silicone Resins and Resin Intermediates in Weather-Resistant Paints -- Silicone Resins in High Temperature Paints -- Silicones for Marine Fouling Release Coatings -- 8. SILICONES IN THE CONSTRUCTION INDUSTRY -- Adhesion -- Durability -- Applications -- 9. SILICONE RELEASE COATINGS FOR THE PRESSURE SENSITIVE ADHESIVE INDUSTRY -- Silicone Release Characteristics -- Factors to Consider for Silicone Release Coatings -- Cure Chemistry -- Greater Use of Plastic Release Liners -- 10. SILICONES AS MOLD-MAKING ELASTOMERS -- Process Description -- Mold-Making Elastomers -- Two-Part Silicone Mold-Making Elastomers -- The Art of Mold Making with Two-Part Silicone Elastomers -- Application Fields -- 11. SILICONES IN THE ELECTRONICS INDUSTRIES -- The Relationship of Structural Properties in Electronic Applications -- Electrical Properties of Silicones -- Water Absorption -- Thermal Conductivity -- 12. SILICONES FOR PHOTONICS -- Necessary Properties for Photonics Applications -- 13. SILICONE IN MEDIUM TO HIGH VOLTAGE ELECTRICAL APPLICATIONS -- Silicone Cable End Terminations -- Silicone Insulators -- 14. SILICONES IN TRANSPORTATION: AUTOMOTIVE AND AVIATION -- Land Transportation -- Aviation -- 15. SILICONES IN THE PLASTICS INDUSTRY -- 16. SILICONES IN PERSONAL CARE APPLICATIONS -- Types of Silicones Used in Personal Care Applications. ; Silicone Benefits in Beauty Care Products -- Silicones and Skin Feel -- Volatility of Silicones -- Permeability of Silicones -- 17. MEDICAL APPLICATIONS -- Polydimethylsiloxanes and Biocompatibility -- Medical Devices and Pharmaceuticals -- 18. SILICONE LUBRICANTS IN INDUSTRIAL ASSEMBLY AND MAINTENANCE -- Tribology and Lubrication Mechanism -- Polymeric Lubricant Composition -- Examples of Silicone Lubricant Applications -- 19. ORGANO-FUNCTIONAL SILANES -- Chemistry of Coupling with Organo-Functional Silanes -- Trends and Perspectives -- 20. PLASMA AND SILICONES -- 21. SILICONES AND TOXICOLOGY -- 22. SILICONES AND THEIR IMPACT ON THE ENVIRONMENT -- 23. CONCLUSION -- NOTES -- REFERENCES -- POLYSILOXANES AS TEMPLATES AND BUILDING BLOCKS IN NANOSTRUCTURED MATERIALS -- ABSTRACT -- INTRODUCTION -- FUNCTIONALIZED POLYSILOXANES -- NANOCOMPOSITES -- CLAY NANOCOMPOSITES -- NANOPARTICLES -- FERROFLUIDS -- NANOTUBES -- SOL-GEL -- BIOACTIVITY -- SELF-ASSEMBLED MORPHOLOGIES -- SOFT LITHOGRAPHY -- TEMPLATING -- ION-CONDUCTING AND MEMBRANE APPLICATIONS -- SUMMARY -- REFERENCES -- PHOTOCHEMISTRY OF POLYSILOXANES -- INTRODUCTION -- 1. PHOTOFRAGMENTATION AND OXIDATION OF ORGANOSUBSTITUTED SILOXANE UNITS -- 2. PHOTOCHEMICAL AGING OF SILICONE MATERIALS -- 3. PHOTOREACTION OF CHROMOPHORES BOUND TO A POLYSILOXANE CARRIER -- 3.1. Polysiloxanes with Photodimerizable Pendant Groups -- 3.2. Polysiloxanes with Arylketone Side-Groups as Free Radical Photo-Initiators -- 4 REACTIONS AFFECTING SILOXANE COMPOUNDS TRIGGERED BY A PHOTOCHEMICAL PROCESS -- 4.1. Photopolymerization of Silicone-Based Monomers -- 4.2. Miscellaneous -- 5. CONCLUSION -- ACKNOWLEDGEMENTS -- REFERENCES -- POLYSILANES -- 1. INTRODUCTION -- 2. NOMENCLATURE -- 3. HISTORICAL -- 4. LINEAR POLYSILANES -- 4.1. Synthesis -- 4.2. Functionalization -- 5. STRUCTURE, CONFORMATIONS AND PROPERTIES. ; 5.1. Electronic Structure -- 5.2. Polysilanes in Solution: Conformation, Thermo- and Solvatochromism -- 5.3. Polysilanes in the Solid State: Structure, Phase Transitions andChromisms -- 5.4. Other Chromic Responses to External Stimuli -- 5.5. Photochemical and Chemical Reactions of Polysilanes -- 6. HIGHER ORDER STRUCTURE - OPTICAL ACTIVITY -- 6.1. Polysilane Preferential Screw Sense (PSS) Helicity and Chirality -- 6.2. Temperature-Dependence of Helical Screw Sense and Selectivity -- 6.3. Polysilane Aggregate Chirality -- 6.4. Other Aspects of Polysilane Chirality -- 7. OVERVIEW OF HIGHER DIMENSIONAL SILICON POLYMERS -- 7.1.Polysilynes, (RSi)n -- 7.2. Dendrimer Polysilanes -- 7.3. Ladder and Cage Polysilanes -- 8. CONCLUDING REMARKS -- REFERENCES -- POLYCARBOSILANES -- ABSTRACT -- 1. INTRODUCTION -- 2. POLYCARBOSILANES AS SIC PRECURSORS -- 3. LINEAR POLYCARBOSILANES -- 3.1. Poly(silylenemethylenes) -- 3.2. Poly(silyleneethylenes), Poly(silyleneethenylens) and Poly(silyleneethynylenes) -- 3.3. Polycarbosilanes with (-Si-Cx-)n Units (x > -- 2) in the Main Chain -- 3.4. Polycarbosilanes with (-Six-C-) Units (x > -- 1) in the Main Chain -- REFERENCES -- POLYSILAZANES -- 1. INTRODUCTION -- 2. SYNTHESIS OF POLYSILAZANES -- 2.1. Salt Elimination Reactions -- 2.2. Si-n Coupling without Salt Formation -- 3. SYNTHESIS OF POLYSILAZANES SI/N/C/E (E = B, AL) -- 3.1. Boron-Modified Polysilazanes -- 3.2. Aluminum-Modified Polysilazanes (Polyaluminosilazanes) -- ACKNOWLEDGEMENTS -- REFERENCES -- POLYFERROCENYLSILANE-BASED POLYMER SYSTEMS -- INTRODUCTION AND SCOPE -- THE PARAMOUNT IMPORTANCE OF ROP -- ROP METHODOLOGIES -- SYNTHESIS OF COPOLYMERS - MACROMOLECULAR ARCHITECTURES -- CHEMICAL MODIFICATION -- SELF-ASSEMBLY OF PFS BLOCK COPOLYMERS IN THE SOLID STATE -- SELF-ASSEMBLY OF PFS BLOCK COPOLYMERS IN SELECTIVE SOLVENTS. ; PFS-ASSISTED BLOCK COPOLYMER NANOPATTERNING -- MICROPATTERNING OF RANDOM COPOLYMERS AND HOMOPOLYMERS -- OTHER BLOCK COPOLYMER APPLICATIONS -- PHYSICAL PROPERTIES -- CONCLUSIONS AND PERSPECTIVES -- REFERENCES -- INDEX.
• Titolo autorizzato: Silicon-based inorganic polymers
• ISBN: 1-60876-256-4
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910810125303321
• Lo trovi qui: Univ. Federico II