Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis

• Pubblicazione: Weinheim, [Germany] : , : Wiley-VCH, , 1998; ©1998
• Descrizione fisica: 1 online resource (744 p.)
• Disciplina: 547.08
• Soggetto topico: Organosilicon compounds
• Persona (resp. second.): AunerNorbert; WeisJohann
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references at the end of each chapters and indexes.
• Nota di contenuto: Organosilicon Chemistry III, from Molecules to Materials; Contents; I. Fascinating Organosilicon Compounds; Introduction; More Compelling Evidence that Silicon is Better Than Carbon: The Thermal Isomerization of Olefins to Carbenes; NMR and Quantum Chemical Characterization of Silicon-Substituted Carbocations; Matrix Isolation Studies of the Reactions of Silicon Atoms; Cycloaddition Reactions of Dimethylaminomethylsilylene with Dienes and Heterodienes; Do Unsubstituted Silacyclobutadienes Exist?; A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu))2}C6H4-1,2] ; Pyrido[b]- 1 ,3,2λ2-diazasilole: The First Stable Unsymmetrical SilyleneA New Route to Silaheterocycles: Heterobutadiene Cycloaddition; Base Coordination: A Way to Nucleophilic Silylenes?; Isoelectronic Replacement of Si by P+: A Comparative Study of the Structures of the Spirocyclic EII Compounds E[C(PMe2)2(X)]2 (E = Si, Ge, Sn; X = PMe2,SiMes) and a Novel Spirocyclic 10 e-Phosphorus Cation(Pm) P[C(PPh2)2(SiMe3)]2+; The Main Group Carbonyls mi-CO and R2Si-CO: An Ab Initio Study ; Unprecedented Multistep Reactions of Decamethylsilicocene, (Me5Cs)zSi:, with C02, CSZ, COS, RNCS (R = Me, Ph), with CF3CCCF3, and with HMn(C0)5Rearrangement of Bis(hypersilyl)silylene and Related Compounds - An Unusual Way to Three-Membered Rings; Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species; New Silaheterocycles: Formation and Properties; Cycloaddition Reactions of 1,l-Dichloro-2-neopentylsilene with Monoterpenes; Silaspirocycles as Precursors for a 2-Silaallene; Catalytic Carbon-Carbon Hydrogenation of Silicon-Functionalized Olefins ; Dieno- and Enophilicity of Sila-, Germa-, and StannaethenesIminosilanes and Silaamidides: Synthesis and Reactions; Metastable Compounds Containing Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds: Syntheses, Structures and Reactivity; Silole and Germole Dianions and their Dilithium Derivatives - Are they Aromatic?; Supersilylmetal Compounds; Trialkylsilyl Substituted Homobimetallic Phosphanides of the Alkaline Earth Metals as well as Zinc; The Tris(trimethylsily1)silyl Substituent: An Old Hat With A New Feather ; Functionalized Trisilylmethanes and Trisilylsilanes as Precursors of a New Class of Tripodal Amido LigandsMethoxy-bis[tris(trimethylsilyl)silyl]methane: The First Geminal Di(hypersily1) Compound; The Use of the Tris(trimethylsily1)silyl Group in Stabilization of Low Valent Gallium Compounds; Synthesis, Structure, and Reactions of Tris(trimethylsi1yl)silyl Gallanes and Gallates; Novel Pathways in the Reactions of Vinylsilanes with Lithium Metal; New Organosilicon Reagents : Synthesis, Structure, and Reactivity of (Lithiomethyl)(aminomethyl)silanes ; (Phenylthiomethyl)silanes as New Bihnctional Assembling Ligands for the Construction of Heterometallic Complexes
• Sommario/riassunto: Organosilicon Chemistry at its best ...((kursiv))Like its two hugely successful predecessors, the third volume again presents the latest developments in a rapidly developing field of industsrial and academic research. The contributions from approx. 80 internationally renowned experts and researchers in this fascinating part of the rapidly growing field of main group chemistry describe current trends in organosilicon chemistry and provide summaries of the latest (1997!) knowledge in this area. To facilitate access to the ongoing research this volume is split into two par
• Titolo autorizzato: Organosilicon chemistry
• ISBN: 1-281-76470-1; 9786611764708; 3-527-61990-9; 3-527-62074-5
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Tedesco
• Record Nr.: 9910830667103321
• Lo trovi qui: Univ. Federico II