Industrial Scale Inhibition : Principles, Design, and Applications

• Autore: Yaagoob Ibrahim Yahia
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2024; ©2024
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (595 pages)
• Disciplina: 660.28304
• Soggetto topico: Chemical engineering; Industrial water supply
• Altri autori: VermaChandrabhan
• Nota di contenuto: Cover -- Title Page -- Copyright -- Contents -- About the Editors -- List of Contributors -- Preface -- Acknowledgments -- Chapter 1 Scales, Scaling, and Antiscalants: Fundamentals, Mechanisms, and Properties -- 1.1 Introduction -- 1.2 Scales -- 1.2.1 Calcium Carbonate -- 1.2.2 Calcium Sulfate -- 1.2.3 Calcium Phosphate -- 1.3 Scaling -- 1.3.1 Initiation -- 1.3.2 Transport Phenomenon -- 1.3.3 Adsorption Process -- 1.3.4 Removal -- 1.3.5 Aging -- 1.3.6 Supersaturation -- 1.3.7 Nucleation -- 1.3.8 Contact or Induction Period -- 1.4 Antiscalant/Chemical Treatment -- 1.5 Antiscalant Mechanism -- 1.6 Antiscalant in Industrial Water‐Circulating Systems -- 1.7 Antiscalants in Oilfield Environments -- 1.8 Overview of Some Plant‐derived and Organic‐based Antiscalants -- 1.9 Conclusion and Future Perspectives -- Acknowledgments -- References -- Chapter 2 Traditional and Eco‐friendly Antiscalants: Advantages and Disadvantages -- 2.1 Introduction -- 2.2 Formation and Hazards of Scale -- 2.2.1 Scale Inhibition Measures -- 2.2.2 Classification of Scale Inhibitors -- 2.2.2.1 Natural Scale Inhibitors -- 2.2.2.2 Polymer Scale Inhibitors -- 2.2.2.3 Eco‐friendly Scale Inhibitor -- 2.2.3 Scale Inhibition Mechanism -- 2.2.3.1 Complex Solubilization -- 2.2.3.2 Dispersion -- 2.2.3.3 Lattice Distortion -- 2.2.3.4 Dissolution Limit Effect -- 2.2.3.5 Strong Polar Group Action -- 2.2.3.6 Regenerative Self‐extrication Membrane Hypothesis -- 2.3 Advantages and Disadvantages of Traditional Impedance Agents -- 2.3.1 Scale Inhibitor for Phosphorus‐containing Polymers -- 2.3.2 Copolymer Scale Inhibitor -- 2.4 Advantages and Disadvantages of Environmentally Friendly Scale Inhibitors -- 2.4.1 PASP and PESA -- 2.4.2 Plant Extracts -- 2.4.3 Carbon Nanoparticle Scale Inhibitor -- 2.4.3.1 Carbon Nanoparticles -- 2.4.3.2 Carbon Nanotubes (CNTs) -- 2.4.3.3 Carbon Quantum Dots (CQDs). ; 2.5 Future Prospects and Challenges -- Acknowledgments -- Declaration of Competing Interest -- References -- Chapter 3 Electrochemistry Basics and Theory of Scaling in Various Electrolytes: Effect of pH and Other Parameters -- 3.1 Introduction to Electrochemistry -- 3.2 Fundamentals of Electrochemistry -- 3.2.1 Electrochemical Processes: Chemical-Electrical Interplay -- 3.2.2 Electrode Potentials and Their Significance -- 3.2.3 Nernst Equation: Linking Potential and Concentration -- 3.2.4 Faraday's Laws and Their Role in Quantitative Electrochemistry -- 3.2.5 Electrolysis Principles -- 3.3 Scaling Phenomena in Electrolytic Systems -- 3.3.1 Understanding Scaling and Its Multifaceted Effects -- 3.3.2 pH as a Key Driver of Scaling: Mechanisms and Implications -- 3.3.3 Temperature's Role in Scaling: Thermal Dynamics and Consequences -- 3.3.4 Impact of Ionic Strength on Scaling and Electrochemical Behavior -- 3.4 pH's Influence on Scaling and Electrochemical Processes -- 3.4.1 pH's Influence on Electrode Kinetics and Reaction Rates -- 3.4.2 pH's Influence on Reaction Rates -- 3.4.3 Proton Activity as a Determinant of Pace -- 3.4.4 The Nernst Equation: Linking pH and Electrode Potential -- 3.4.5 Ion Mobility Variations with pH and Their Electrochemical Consequences -- 3.4.6 pH‐Dependent Deposition Dynamics: Growth, Morphology, and Effects -- 3.5 Temperature and Ionic Strength Effects on Scaling -- 3.5.1 Thermal Variability and Scaling Phenomena -- 3.5.2 Role of Ionic Strength in Modulating Scaling -- 3.6 Electrode Material and Its Influence on Scaling -- 3.6.1 Electrode Materials: Selection, Properties, and Impacts -- 3.6.2 Material‐Induced Scaling Effects: Challenges and Solutions -- 3.7 Electrolyte Composition and Current Density: Scaling Implications -- 3.7.1 Electrode Materials: Selection, Properties, and Impacts. ; 3.7.2 Material‐Induced Scaling Effects: Challenges and Solutions -- 3.8 Integrative Understanding of Electrochemical Processes -- 3.8.1 Synthesizing Insights from pH, Temperature, and Key Parameters -- 3.8.2 Synergies and Interactions: A Holistic View of Scaling Phenomena -- 3.9 Conclusion and Future Prospects -- References -- Chapter 4 A Critical Review of Relative Scale Inhibition Performance of Different Alternatives -- 4.1 Introduction -- 4.1.1 Substoichiometric Antiscalants -- 4.1.2 Conventional Mechanisms of Antiscalant‐induced Scale Inhibition and Their Critical Evaluation -- 4.1.3 Nonconventional Hypothesis of Scale Inhibition Mechanism -- 4.1.4 Relative Scale Inhibitors Performance Assessment -- 4.1.5 Other Chemical Methods -- 4.1.6 Nonchemical Alternatives to Antiscalants -- 4.2 Concluding Remarks -- 4.3 Future Perspectives -- Acknowledgment -- References -- Chapter 5 Environmentally Acceptable Antiscalants and Their Hydrolytic Stability -- 5.1 Background of Scales and Antiscalants -- 5.1.1 Antiscalant or Scale Inhibitors -- 5.1.2 Phosphorus‐Based Antiscalants -- 5.1.3 Phosphorus‐Free Antiscalants -- 5.2 Hydrolytic Stability of Scales and Antiscalants -- 5.2.1 Scales -- 5.2.2 Antiscalants -- 5.3 Recent Developments for Environmentally Acceptable Antiscalants and Their Hydrolytic Stability -- 5.3.1 Natural Green Antiscalants -- 5.3.2 Environmentally Degradable Polymers -- 5.3.2.1 Oil and Gas Industries -- 5.3.2.2 Water Treatment Industries -- 5.4 Conclusion -- 5.5 Future Perspective -- Acknowledgements -- References -- Chapter 6 Assessment of Industrial Scale Inhibition: Experimental and Computational Approaches -- 6.1 Introduction -- 6.1.1 Oil and Gas Industry -- 6.1.2 Power Generation Industry -- 6.1.3 Water Treatment Industry -- 6.1.4 Food and Beverage Industry -- 6.1.5 Mining Industry -- 6.1.6 Chemical Industry. ; 6.2 Brief Overview of Experimental and Computational Approaches -- 6.2.1 Experimental Approaches -- 6.2.2 Computational Approaches -- 6.3 Experimental Approaches for Assessing Scale -- 6.4 Computational Approaches for Assessing Scale -- 6.5 Advantages and Disadvantages of Experimental and Computational Approaches -- 6.5.1 Advantages of Experimental Approaches -- 6.5.2 Disadvantages of Experimental Approaches -- 6.5.3 Advantages of Computational Approaches -- 6.5.4 Disadvantages of Computational Approaches -- 6.6 Challenges and Future Outlooks -- 6.7 Conclusion -- References -- Chapter 7 Recent Advancements Toward Phosphorus‐Free Scale Inhibitors: An Eco‐friendly Approach in Industrial Scale Inhibition -- 7.1 Introduction -- 7.2 Scale Inhibitors and Mechanism of Scale Inhibition -- 7.3 Advancements Toward Phosporous‐Free Scale Inhibitors -- 7.4 Summary -- 7.5 Future Perspective -- Acknowledgments -- References -- Chapter 8 Trends in Using Organic Compounds as Scale Inhibitors: Past, Present, and Future Scenarios -- 8.1 Introduction -- 8.2 Classification of Organic Scale Inhibitors -- 8.2.1 Carboxylic Acid Functional Groups of Scale Inhibitors -- 8.2.2 Organophosphorus‐Based Scale Inhibitors -- 8.3 Adsorption Mechanism of Organic Scale Inhibitors in the Oil and Gas Industry -- 8.4 Increasing the Effectiveness of Organic Scale Inhibitors -- 8.5 Technologies of Organic Scale Inhibitor Application in the Oil and Gas Industry -- 8.6 Future Perspective -- 8.7 Conclusion -- References -- Chapter 9 Organic Compounds as Scale Inhibitors -- 9.1 Introduction -- 9.2 Organic Compounds as Scale Inhibitors -- 9.2.1 Organophosphonic Acid as Scale Inhibitor -- 9.2.2 Effect of Functional Groups as Scale Inhibitors -- 9.2.2.1 Effect of Carboxyl Groups on the Performance of Scale Inhibitors. ; 9.2.2.2 The Effect of Sulfonic Acid Group on the Performance of Scale Inhibitors -- 9.2.2.3 The Effect of Hydroxyl Group on the Performance of Scale Inhibitors -- 9.3 New Green Scale Inhibitors -- 9.4 Synergistic Effect Between Functional Groups -- 9.5 Future Prospects and Challenges -- Acknowledgments -- Declaration of Competing Interest -- References -- Chapter 10 Plant Extracts as Scale Inhibitors -- 10.1 Introduction -- 10.2 Plant Extracts -- 10.3 Scale Inhibition Mechanism -- 10.3.1 The Solubilization of Chelation -- 10.3.2 Lattice Distortion -- 10.3.3 Adsorption, Coagulation, and Dispersion -- 10.3.4 Threshold -- 10.4 Plant Extracts to Prevent Carbonate Scale -- 10.5 Plant Extracts to Prevent Sulfate Scale -- 10.6 Future Prospects and Challenges -- Acknowledgments -- Declaration of Competing Interest -- References -- Chapter 11 Carbohydrates as Scale Inhibitors -- 11.1 Introduction -- 11.2 Carbohydrates as Scale Inhibitors -- 11.2.1 Cyclodextrin as Scale Inhibitors in Oilfields -- 11.2.2 Inhibitors of Green Scale Using Carboxymethyl Chitosan in Oil Wells -- 11.2.3 Scale‐Inhibiting Properties of Guar Galactomannan and Konjac Glucomannan -- 11.2.4 As Inhibitors of Green Scale, Guar, and Xanthan Gums -- 11.2.4.1 The Scale Inhibition Mechanism -- 11.2.5 Chitosan and Substituted/Modified Chitosan as Green Scale Inhibitors -- 11.3 Conclusion -- Abbreviations -- Author Contribution Statement -- References -- Chapter 12 Copolymers and Polymers as Scale Inhibitors -- 12.1 Introduction -- 12.2 Copolymer Scale Inhibitor -- 12.3 Polymer Scale Inhibitor -- 12.4 Future Prospects and Challenges -- Acknowledgments -- Declaration of Competing Interest -- References -- Chapter 13 Polymeric and Copolymeric Scale Inhibitors: Trends and Opportunities -- 13.1 Introduction -- 13.2 Copolymers -- 13.3 Polymers -- 13.4 Scale Formation -- 13.5 Scale Inhibitors. ; 13.6 Copolymers as Scale Inhibitors in Industrial Water‐Circulating Systems.
• Sommario/riassunto: This comprehensive guide explores the principles, design, and applications of industrial scale inhibition. Edited by Ibrahim Yahia Yaagoob and Chandrabhan Verma, the book delves into the fundamentals of scale formation and the mechanisms of antiscalants. It covers a wide range of topics including traditional and eco-friendly antiscalants, the impact of various electrolytes, and the relative performance of different scale inhibition alternatives. The book also examines the role of organic compounds, plant extracts, copolymers, polymers, and nanomaterials in scale inhibition. Aimed at professionals and researchers in the fields of chemistry and chemical engineering, it provides insights into recent advancements and experimental approaches in the industry. The text is supported by contributions from experts worldwide, making it a valuable resource for understanding and addressing scale-related challenges in industrial systems.
• Titolo autorizzato: Industrial Scale Inhibition
• ISBN: 9781394191185; 9781394191178
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911019164303321
• Lo trovi qui: Univ. Federico II