Green organic reactions / / Gopinathan Anilkumar, Salim Saranya, editors

• Pubblicazione: Singapore : , : Springer, , [2021]; ©2021
• Descrizione fisica: 1 online resource (xx, 338 pages) : illustrations
• Disciplina: 660.0286
• Soggetto topico: Green chemistry; Chemistry, Organic
• Persona (resp. second.): AnilkumarGopinathan; SaranyaSalim
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- Preface -- Contents -- About the Editors -- Abbreviations -- 1 Introduction to Green Chemistry -- 1 Introduction -- 2 History and Origins of Green Chemistry -- 3 Green Chemistry for the Environment -- 4 Green Chemistry and Other Chemistry -- 5 Benefits of Green Chemistry -- 6 Future of Green Chemistry -- 7 Conclusion -- References -- 2 Principles of Green Chemistry -- 1 Introduction -- 2 Basic Concepts of Green Chemistry -- 2.1 Preventing Waste Formation is Better Than Processing after it is Created -- 2.2 Achieve the Maximum Atom Economy -- 2.3 Designing Less Dangerous Chemical Technologies -- 2.4 Chemicals with High Functional Efficiency and Minimum Toxicity should be Designed -- 2.5 Usage of Benign Solvents and Auxiliaries -- 2.6 Increase in Energy Efficiency -- 2.7 Utilization of the Renewable Raw Materials that Are not Exhaustible -- 2.8 Avoid Derivative Processes -- 2.9 Catalysts are more Specialized than Selective Reagents -- 2.10 Designing the Chemical Products so that they do not Settle in the Environment (Biodegradable Materials) -- 2.11 Real-Time Analysis for Pollution Prevention -- 2.12 Reducing the Possibility of Accidents -- 3 Conclusion -- References -- 3 Organic Reactions in Water -- 1 Introduction -- 2 Reactions on Water -- 2.1 Catalyst-Free Reactions on Water -- 2.2 Reactions on Water Using Metal Catalyst -- 3 Organic Reactions in Water: Reactions in Micellar Media -- 3.1 Reactions in Water Directly Promoted by Surfactants -- 3.2 Reactions Promoted by Metals Along with Surfactants -- 4 Design and Synthesis of New Surfactants -- 5 Conclusion -- References -- 4 Microwave-Assisted Amination Reaction: A Green Approach -- 1 Introduction -- 2 Classification -- 2.1 Metal-Catalyzed Amination Reactions -- 2.2 Miscellaneous Reactions -- 3 Conclusion -- References -- 5 Green Reactions Under Solvent-Free Conditions. ; 1 Introduction -- 2 Synthesis of Different Scaffolds Under Solvent-Free Conditions -- 2.1 The Synthesis of α-Aminophosphonate Derivatives -- 2.2 The Synthesis of Pyrimidine Derivatives -- 2.3 The Synthesis of the Pyran Derivatives -- 2.4 The Synthesis of the Pyrrole Derivatives -- 2.5 The Synthesis of the Imidazole Derivatives -- 2.6 The Synthesis of the Propargylamine Derivatives -- 3 Conclusion -- References -- 6 Solid-State Green Organic Reactions -- 1 Introduction -- 2 Solid-State Photochemical Reactions -- 2.1 Norrish Type I Reactions -- 2.2 Norrish Type II Reactions -- 2.3 Solid-State Photochemical [2 + 2] Cycloadditions -- 3 Mechanochemical Synthesis -- 3.1 Introduction to Mechanochemistry -- 3.2 Mechanochemical Synthesis of Heterocycles -- 3.3 Mechanochemical Synthesis of Biological Molecules -- 3.4 Mechanochemical Enantioselective Synthesis: Organocatalysis and Biocatalysis -- 3.5 Mechanochemical Synthesis of Pharmaceuticals -- 3.6 Prebiotic Mechanochemistry -- 3.7 Mechanochemical Synthesis of Nanostructures -- 3.8 Mechanochemical Polymer Chemistry -- 3.9 Mechanochemical Synthesis of Metal-Organic Frameworks -- 4 Reactions Combining Photochemical and Mechanochemical Activation -- 5 Sonochemistry in the Solid State -- 6 Conclusion -- References -- 7 Green in Analytical Chemistry -- 1 Introduction -- 1.1 The Purpose of Analytical Chemistry -- 1.2 Developments in Analytical Chemistry -- 2 The Influence of Green Chemistry on Analytical Chemistry -- 2.1 4S Approach -- 3 Conclusion -- References -- 8 Green in Pharmaceutical Chemistry -- 1 Introduction -- 1.1 Nanochemistry in Pharmaceutical Industry -- 1.2 Biocatalysis in Pharmaceutical Industry -- 1.3 Reactions of "in-Water" and "on-Water" Chemistry -- 1.4 Reactions Mediated by Ionic Liquid (IL) -- 1.5 Green Synthesis of Pharmaceutically Relevant Compounds -- 1.6 Case Studies. ; 1.7 Miscellaneous Reactions -- 2 Conclusion -- References -- 9 Green Organocatalysis -- 1 Introduction -- 2 Background of Green Organocatalysts -- 3 Classification of Organocatalysis -- 4 Some Examples of Green Organocatalysts -- 4.1 Proline and Its Derivatives -- 4.2 N-Heterocyclic Carbene (NHC) as Organocatalysts -- 4.3 DMAP -- 4.4 MacMillan's Imidazolidinone Organocatalysts -- 4.5 Thiourea -- 5 Conclusion -- References -- 10 Environmentally Benign Organic Solvent: A Green Approach -- 1 Introduction -- 2 Organic Synthesis in Polyethylene Glycol -- 3 Organic Synthesis in Glycerol -- 4 Organic Reactions in Ethanol -- 5 Organic Reactions in Ethyl Lactate -- 6 Organic Synthesis in Gluconic Acid Aqueous Solution -- 7 Conclusion -- References -- 11 Green Chemistry on C-H Activation -- 1 Introduction -- 1.1 Green Chemistry and C-H Bond Activation -- 2 Proposed Mechanisms for C-H Bond Activation -- 3 Classification of Green C-H Activations -- 4 Green Protocols for C-H Bond Activation -- 4.1 Applicable Metals in C-H Activation -- 4.2 Transition Metal-Free C-H Activation -- 4.3 Green Solvent/solvent-Free C-H Activation -- 4.4 Green Oxidant/Oxidant-Free C-H Activation -- 4.5 Direct C-H Functionalization -- 5 Electrochemical C-H Bond Activation -- 6 C-H Bond Activation Under Flow Condition -- 7 Electrochemical C-H Bond Activation Under Flow Condition -- 8 Photocatalytic C-H Bond Activation -- 9 C-H Bond Activation Using Ball Milling and Transition Metal Catalysts -- 10 Conclusion -- References -- 12 Atom Economic Green Organic Reactions -- 1 Introduction -- 1.1 Catalyst-Free Reactions -- 1.2 Water-Assisted Reactions -- 1.3 Pericyclic Reactions -- 1.4 Solvent-Free Reactions -- 1.5 Ionic Liquid-Mediated Reactions -- 1.6 Metal-Free Dehydrogenative Coupling Reactions -- 1.7 Miscellaneous Reactions -- 2 Conclusion -- References. ; 13 Green Nanocatalysts in Organic Synthesis -- 1 Introduction -- 2 Green Nanocatalysis -- 3 Self-Assembled Nanoreactors -- 3.1 Micelles -- 3.2 Polymeric Vesicles -- 3.3 Resorcin[4]arene Hexameric Capsules -- 4 Covalent Nanoreactors -- 4.1 Dendrimers -- 4.2 Nanoparticles -- 5 Other Nanocatalysts -- 6 Conclusion -- References -- 14 Visible Light-Catalyzed Asymmetric Synthesis: A Green Perspective -- 1 Introduction -- 2 Photocatalyzed Asymmetric Synthesis -- 2.1 Sensitizers as Sole Catalysts -- 2.2 Oraganocatalyst-based Dual Catalysis via Intermediate Formation -- 2.3 Asymmetric Induction via Non-Covalent Interactions -- 2.4 Enzyme-Based Approaches -- 3 Conclusion -- References -- 15 The Role of Continuous Flow Processing in the Development of Green Chemical Syntheses -- 1 Introduction -- 2 The Benefits of Continuous Flow Processing in Chemical Syntheses -- 2.1 Excellent Atom Economy and Yields -- 2.2 Waste Minimization -- 2.3 Enhanced Process Safety via Safe Reaction Spaces -- 2.4 The Use of Heterogeneous Catalysis -- 2.5 Process Automation, in-Line Monitoring, Purification and Separation -- 2.6 Multistep Syntheses -- 3 Conclusion -- References -- 16 Green Chemistry of Recoverable Catalysts -- 1 Introduction -- 2 Classification -- 2.1 Metallodendrimers-Dendrimers Supported Catalysts -- 2.2 Fluorous Biphasic Catalyst-PTC -- 2.3 Magnetically Recoverable Metal Nanoparticles -- 2.4 Organic Resin and Polymer-Supported Recoverable Catalysts -- 2.5 Silica-Supported Organocatalysts -- 2.6 Thermomorphic Catalysts -- 3 Conclusion -- References -- 17 Supercritical Fluids as Green Solvents -- 1 Introduction -- 1.1 Supercritical Fluid Extraction (SFE) -- 1.2 Supercritical Fluid Chromatography (SFC) -- 1.3 Supercritical Fluids as Reaction Media -- 1.4 Supercritical Fluid Deposition -- 2 Conclusion -- References.
• Titolo autorizzato: Green organic reactions
• ISBN: 981-336-897-7
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910483215803321
• Lo trovi qui: Univ. Federico II
• Serie: Materials horizons.