Analytical Thermodynamics

• Autore: Li Dongqing
• Pubblicazione: Cham : , : Springer, , 2025; ©2025
• Edizione: 2nd ed.
• Descrizione fisica: 1 online resource (302 pages)
• Disciplina: 621.4021
• Nota di contenuto: Intro -- Preface for the Second Edition -- Preface for the First Edition -- References -- Contents -- About the Author -- 1 Basics of Analytical Thermodynamics -- 1.1 Definitions -- 1.2 Postulates -- 1.3 Fundamental Equations -- 1.4 Euler Equation and Gibbs-Duhem Equation -- 1.5 Simple Equilibrium Conditions -- 1.6 Extreme Principles of Equilibrium States -- 1.7 Legendre Transformations -- 1.8 Thermodynamic Potentials -- 1.9 Minimum Principles of Thermodynamic Potentials/Free Energies -- 1.10 Applications of Minimum Principle of Thermodynamic Potentials -- 1.11 Maxwell Relations -- 1.12 Thermodynamic Characteristics of Dielectric Media-Application of Maxwell Relations -- 1.13 Introduction to Thermodynamic Stability -- 1.14 Phase Change and Clapeyron Equation -- 1.15 Chemical Potentials -- 1.16 Boiling Temperature and Freezing Temperature of Dilute Solutions -- 1.17 Gibbs Phase Rule -- 1.18 Introduction to High-Order Phase Change -- 2 Modelling Homogeneous and Heterogeneous Systems -- 2.1 Simple Elastic Solid -- 2.2 Simple Electrolyte Solution Systems -- 2.3 Systems in Gravitational Field and in Centrifugal Field -- How to Model a System in a Gravitational Field and in a Centrifugal Field -- How to Determine the Equilibrium Conditions -- 2.4 Electrolyte Solution in Electric Field as a Non-uniform System -- 3 Thermodynamics of Interfaces and Three-Phase Contact Lines -- 3.1 Liquid-Fluid Interfaces and Three-Phase Contact Lines -- Liquid-Fluid Interfaces or Surfaces -- 3.2 Thermodynamics of Surfaces -- 3.3 Thermodynamics of Three-Phase Contact Lines -- 3.4 Equilibrium Conditions of Droplets and Bubbles -- 3.5 Equilibrium Conditions of Sessile Drops -- Introduction to Wetting Phenomena -- Surface Tension and Surface Stress -- Sessile Drop on a Flat Horizontal Surface -- A Sessile Drop in a Crevice/Cavity. ; 3.6 Contact Angles of a Sessile Drop on Heterogeneous Surfaces and on Rough Surfaces -- Contact Angle of a Sessile Drop on a Smooth but Heterogeneous Surface -- Contact Angle of a Sessile Drop on a Homogeneous but Rough Surface -- 3.7 From Laplace Equation to Capillary Rise and Meniscus Shape -- Capillary Rise in a Vertical Capillary -- Capillary Rise at a Vertical Wall -- Capillary Rise and the Meniscus Shape with an Inclined Plate -- A Liquid Bridge Between Two Parallel Plates -- 3.8 Curvature Effects on Equilibrium Pressure and Temperature -- Curvature Effect on Equilibrium Vapor Pressure Around a Drop -- Curvature Effect on Equilibrium Pressure in a Bubble -- Curvature Effect on Equilibrium Temperature -- Curvature Effect on Surface Tension -- 3.9 Equilibrium of Capillary Systems with an Elastic Liquid-Vapor Interface -- Thermodynamic Model -- Mechanical Equilibrium Conditions -- Case 1: Spherical Surface -- Case 2: Capillary Rise on a Vertical Plate -- 3.10 Heterogeneous Nucleation of Droplets -- 3.11 Solute Effect on Equilibrium Vapor Pressure -- 3.12 Solute Effect on Equilibrium Radius of Droplets -- 3.13 Heterogeneous Bubble Nucleation in a Dilute Solution -- 3.14 Equilibrium Condition of a Bubble in a Uniform Electric Field -- 3.15 Effects of Applied Electrical Field on Contact Angles (Electro-wetting Phenomenon) -- 3.16 Effects of Electric Double Layer on Contact Angle -- 3.17 Modelling Surface Processes by Using Surface Free Energy -- Surface Free Energy -- Cohesion -- Adhesion -- Merge of Two Oil Droplets in Water -- Film Breakage and Droplet Formation on a Solid Surface -- 4 Second Law of Engineering Thermodynamics -- 4.1 Irreversible Processes -- 4.2 Limitation of First Law of Thermodynamics -- 4.3 Second Law and Equations -- 4.4 The Second Law Requirement on Thermal Cycles -- 4.5 Applying Second Law Equation to a Human Body. ; 5 Solutions of Selected Home-Work Questions -- 5.1 Solutions of Home Work of Chap. 1 -- 5.2 Solutions of Home Work of Chap. 2 -- 5.3 Solutions of Home Work of Chap. 3.
• Sommario/riassunto: This second edition presents an enriched and expanded exploration of the fundamental principles of thermodynamics tailored for graduate-level studies. Drawing on over three decades of academic teaching experience, the author has refined the content, making it more accessible and comprehensive. Chapter 1 has been restructured for clarity, delineating "Legendre Transformation" and "Thermodynamic Potentials" into separate sections, while the treatment of "Chemical Potentials" has been significantly augmented, encompassing two-component ideal gas mixtures and a re-derivation of chemical potentials for dilute solutions. Additionally, the section on thermodynamic stability now boasts enhanced explanations and illustrative figures. Chapter 2 introduces a groundbreaking section, "Electrolyte Solution in Electric Field as a Non-Uniform System," providing fresh insights into unexplored realms. Chapter 3, now enriched with several new sections, delves into topics such as "Contact Angles on Heterogeneous Surfaces and Rough Surfaces," "Elastic Liquid-Fluid Interface," "Curvature Effect on Surface Tension," "Solute Effect on Equilibrium Pressure," and "Heterogeneous Bubble Nucleation in a Dilute Solution." Chapter 4 features new elucidations and discussions aimed at bolstering comprehension, while the entirely new Chapter 5 offers solutions to selected homework and exam questions, adding a practical dimension to the theoretical framework. This edition, encompassing approximately 50% new content, expands the book by 131 pages, rendering it an even more invaluable resource for professors instructing advanced thermodynamics and graduate students delving into this intricate subject matter.
• Titolo autorizzato: Analytical Thermodynamics
• ISBN: 9783031714009; 9783031713996
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910983320903321
• Lo trovi qui: Univ. Federico II