Autore	Pu Lin <1965->
Pubbl/distr/stampa	London, : Imperial College Press, c2010
Descrizione fisica	1 online resource (346 p.)
Disciplina	547
Soggetto topico	Chirality Asymmetric synthesis Molecular theory
Soggetto genere / forma	Electronic books.
ISBN	1-282-75993-0 9786612759932 1-84816-412-2
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers 2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc 3.7.3. Synthesis of the Monomeric Model Compound of the Minor-Groove Poly(BINOL) to Catalyze the Dialkylzinc Addition to Aldehydes10b,c3.7.4. Converting the Highly Enantioselective Mono(BINOL) Catalyst to a Highly Enantioselective Poly(BINOL) Catalyst for the Asymmetric Organozinc Additions10; 3.8. Asymmetric Reduction of Prochiral Ketones Catalyzed by the Chiral BINOL Monomer and Polymer Catalysts; 3.9. Asymmetric Epoxidation of α, β-UnsaturatedKetones Catalyzed by the Minor- and Major-GroovePoly(BINOL)s 3.9.1. Asymmetric Epoxidation of α,β-Unsaturated Ketonesin the Presence of a Stoichiometric Amount of theMajor-Groove Poly(BINOL)s, Diethylzincand Oxygen
Record Nr.	UNINA-9910456159103321

Autore	Pu Lin <1965->
Edizione	[1st ed.]
Pubbl/distr/stampa	London, : Imperial College Press, c2010
Descrizione fisica	1 online resource (346 p.)
Disciplina	547
Soggetto topico	Chirality Asymmetric synthesis Molecular theory
ISBN	9786612759932 9781282759930 1282759930 9781848164123 1848164122
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers 2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc 3.7.3. Synthesis of the Monomeric Model Compound of the Minor-Groove Poly(BINOL) to Catalyze the Dialkylzinc Addition to Aldehydes10b,c3.7.4. Converting the Highly Enantioselective Mono(BINOL) Catalyst to a Highly Enantioselective Poly(BINOL) Catalyst for the Asymmetric Organozinc Additions10; 3.8. Asymmetric Reduction of Prochiral Ketones Catalyzed by the Chiral BINOL Monomer and Polymer Catalysts; 3.9. Asymmetric Epoxidation of α, β-UnsaturatedKetones Catalyzed by the Minor- and Major-GroovePoly(BINOL)s 3.9.1. Asymmetric Epoxidation of α,β-Unsaturated Ketonesin the Presence of a Stoichiometric Amount of theMajor-Groove Poly(BINOL)s, Diethylzincand Oxygen
Record Nr.	UNINA-9911090468703321

Autore	Zewail Ahmed H
Pubbl/distr/stampa	London, : Imperial College Press
Descrizione fisica	1 online resource (360 p.)
Disciplina	570.28/25
Altri autori (Persone)	ThomasJ. M (John Meurig)
Soggetto topico	Electron microscopy Hyperspace Space and time Three-dimensional imaging
Soggetto genere / forma	Electronic books.
ISBN	1-282-75991-4 9786612759918 1-84816-391-6
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Acknowledgements; Preface; Contents; 1. Historical Perspectives: From Camera Obscura to 4D Imaging; References; 2. Concepts of Coherence: Optics, Diffraction, and Imaging; 2.1 Coherence - A Simplified Prelude; 2.2 Optical Coherence and Decoherence; 2.3 Coherence in Diffraction; 2.3.1 Rayleigh criterion and resolution; 2.3.2 Diffraction from atoms and molecules; 2.4 Coherence and Diffraction in Crystallography; 2.5 Coherence in Imaging; 2.5.1 Basic concepts; 2.5.2 Coherence of the source, lateral and temporal; 2.5.3 Imaging in electron microscopy; 2.6 Instrumental Factors Limiting Coherence References 3. From 2D to 3D Structural Imaging: Salient Concepts; 3.1 2D and 3D Imaging; 3.2 Electron Crystallography: Combining Diffraction and Imaging; 3.3 High-Resolution Scanning Transmission Electron Microscopy; 3.3.1 Use of STEM for electron tomography of inorganic materials; 3.4 Biological and Other Organic Materials; 3.4.1 Macromolecular architecture visualized by cryo-electron tomography; 3.5 Electron-Energy-Loss Spectroscopy and Imaging by Energy-Filtered TEM; 3.5.1 Combined EELS and ET in cellular biology; 3.6 Electron Holography; References 4. Applications of 2D and 3D Imaging and Related Techniques 4.1 Introduction; 4.2 Real-Space Crystallography via HRTEM and HRSTEM; 4.2.1 Encapsulated nanocrystalline structures; 4.2.2 Nanocrystalline catalyst particles of platinum; 4.2.3 Microporous catalysts and molecular sieves; 4.2.4 Other zeolite structures; 4.2.5 Structures of complex catalytic oxides solved by HRSTEM; 4.2.6 The value of electron diffraction in solving 3D structures; 4.3 Electron Tomography; 4.4 Electron Holography; 4.5 Electron Crystallography; 4.5.1 Other complex inorganic structures; 4.5.2 Complex biological structures 4.6 Electron-Energy-Loss Spectroscopy and Imaging 4.7 Atomic Resolution in an Environmental TEM; 4.7.1 Atomic-scale electron microscopy at ambient pressure by exploiting the technology of microelectromechanical systems; References; 5. 4D Electron Imaging in Space and Time: Principles; 5.1 Atomic-Scale Resolution in Time; 5.1.1 Matter particle-wave duality; 5.1.2 Analogy with light; 5.1.3 Classical atoms: Wave packets; 5.1.4 Paradigm case study: Two atoms; 5.2 From Stop-Motion Photography to Ultrafast Imaging; 5.2.1 High-speed shutters; 5.2.2 Stroboscopy; 5.2.3 Ultrafast techniques 5.2.4 Ultrafast lasers 5.3 Single-Electron Imaging; 5.3.1 Coherence of ultrafast packets; 5.3.2 The double-slit experiment revisited; 5.3.3 Ultrafast versus fast imaging; 5.3.4 The velocity mismatch and attosecond regime; 5.4 4D Microscopy: Brightness, Coherence and Degeneracy; 5.4.1 Coherence volume and degeneracy; 5.4.2 Brightness and degeneracy; 5.4.3 Coherence and Contrast; 5.4.4 Contrast, dose, and resolution; Further Reading; References; 6. 4D Ultrafast Electron Imaging: Developments and Applications; 6.1 Developments at Caltech - A Brief History; 6.2 Instruments and Techniques 6.3 Structure, Morphology, and Mechanics
Record Nr.	UNINA-9910455871903321

Autore	Espinosa, Angela
Pubbl/distr/stampa	London : Imperial College Press, 2011
Descrizione fisica	XXVII, 361 p. : ill. ; 24 cm
Disciplina	338.927
Altri autori (Persone)	Walker, Jon
Collana	World Scientific series on complexity science
Soggetto non controllato	Sviluppo sostenibile Ambiente naturale - Gestione
ISBN	978-1-84816-527-4
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Record Nr.	UNINA-990009464320403321

Autore	Chandrasekhar, S.
Pubbl/distr/stampa	London : Imperial College Press, c2001
Descrizione fisica	2 v. (x, 1428 p.) : ill. ; 27 cm
Soggetto non controllato	Astronomia Astrofisica Cosmologia
ISBN	1-86094-208-3
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Record Nr.	UNINA-990001486430403321