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Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2009
Descrizione fisica 1 online resource (872 p.)
Disciplina 546.24
546/.24
Altri autori (Persone) OlahGeorge A <1927-2017> (George Andrew)
Soggetto topico Superacids
Soggetto genere / forma Electronic books
ISBN 1-282-11300-3
9786612113000
0-470-42160-6
0-470-42154-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto SUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements
1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids
2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid
2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride
2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4)
2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides
Record Nr. UNINA-9910145961603321
Hoboken, N.J., : Wiley, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2009
Descrizione fisica 1 online resource (872 p.)
Disciplina 546.24
546/.24
Altri autori (Persone) OlahGeorge A <1927-2017> (George Andrew)
Soggetto topico Superacids
ISBN 1-282-11300-3
9786612113000
0-470-42160-6
0-470-42154-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto SUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements
1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids
2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid
2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride
2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4)
2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides
Record Nr. UNINA-9910830452603321
Hoboken, N.J., : Wiley, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Superacid chemistry / / George A. Olah ... [et al.]
Superacid chemistry / / George A. Olah ... [et al.]
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2009
Descrizione fisica 1 online resource (872 p.)
Disciplina 546/.24
Altri autori (Persone) OlahGeorge A <1927-> (George Andrew)
Soggetto topico Superacids
ISBN 9786612113000
9781282113008
1282113003
9780470421604
0470421606
9780470421543
0470421541
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto SUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements
1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids
2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid
2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride
2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4)
2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides
Record Nr. UNINA-9911019529603321
Hoboken, N.J., : Wiley, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui