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Alternative solvents for green chemistry / / Francesca M. Kerton, Ray Marriott
| Alternative solvents for green chemistry / / Francesca M. Kerton, Ray Marriott |
| Autore | Kerton Francesca M |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Cambridge, UK : , : RSC Publishing, , [2013] |
| Descrizione fisica | 1 online resource (365 p.) |
| Disciplina | 541.3482 |
| Altri autori (Persone) | MarriottRay |
| Collana | RSC green chemistry series |
| Soggetto topico |
Solvents - Environmental aspects
Solvents |
| ISBN |
1-68015-818-X
1-84973-682-0 1-78262-613-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | 01-1_ASGC_title pages.pdf; 02-5_preface.pdf; 03-9_Contents.pdf; 04-blank.pdf; 05-1_rsabook26chapter1.pdf; 06-31_rsabook26chapter2.pdf; 07-51_rsabook26chapter3.pdf; 08-82_rsabook26chapter4.pdf; 09-115_rsabook26chapter5.pdf; 10-149_rsabook26chapter6.pdf; 11-175_rsabook26chapter7.pdf; 12-210_rsabook26chapter8.pdf; 13-242_rsabook26chapter9.pdf; 14-262_rsabook26chapter10.pdf; 15-285_rsabook26chapter11.pdf; 16-305_rsabook26chapter12.pdf; 17-325_Index.pdf |
| Record Nr. | UNINA-9910164946403321 |
Kerton Francesca M
|
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| Cambridge, UK : , : RSC Publishing, , [2013] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Control techniques guidelines : industrial cleaning solvents
| Control techniques guidelines : industrial cleaning solvents |
| Edizione | [[Final revision].] |
| Pubbl/distr/stampa | RTP, NC : , : Sector Policies and Programs Division, Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, , 2006 |
| Descrizione fisica | 1 online resource (approximately 294 pages) : illustrations |
| Soggetto topico |
Solvents - Environmental aspects
Volatile organic compounds - Standards - United States Industries - Environmental aspects Air quality - Standards - United States Air - Pollution - Law and legislation - United States Pollution prevention - United States Air - Pollution - Law and legislation Air quality - Standards |
| Soggetto genere / forma | Handbooks and manuals. |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Control techniques guidelines |
| Record Nr. | UNINA-9910715001603321 |
| RTP, NC : , : Sector Policies and Programs Division, Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, , 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Control techniques guidelines : industrial cleaning solvents (draft)
| Control techniques guidelines : industrial cleaning solvents (draft) |
| Edizione | [Draft.] |
| Pubbl/distr/stampa | Research Triangle Park, NC : , : U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Sector Policy and Programs Division, , 2006 |
| Descrizione fisica | 1 online resource (approximately 227 pages) : illustrations |
| Soggetto topico |
Solvents - Environmental aspects
Volatile organic compounds - Standards - United States Industries - Environmental aspects Air quality - Standards - United States Air - Pollution - Law and legislation - United States Pollution prevention - United States |
| Soggetto genere / forma | Handbooks and manuals. |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Control techniques guidelines |
| Record Nr. | UNINA-9910715135303321 |
| Research Triangle Park, NC : , : U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Sector Policy and Programs Division, , 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami
| Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
| Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
| Descrizione fisica | 1 online resource (202 p.) |
| Disciplina |
547.2
660.2844 660/.2844 |
| Altri autori (Persone) | MikamiKoichi |
| Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
| Record Nr. | UNINA-9910143316403321 |
| Ames, Iowa, : Blackwell Pub., 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami
| Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
| Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
| Descrizione fisica | 1 online resource (202 p.) |
| Disciplina |
547.2
660.2844 660/.2844 |
| Altri autori (Persone) | MikamiKoichi |
| Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
| ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
| Record Nr. | UNISA-996213064903316 |
| Ames, Iowa, : Blackwell Pub., 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami
| Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
| Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
| Descrizione fisica | 1 online resource (202 p.) |
| Disciplina |
547.2
660.2844 660/.2844 |
| Altri autori (Persone) | MikamiKoichi |
| Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
| ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
| Record Nr. | UNINA-9910830948203321 |
| Ames, Iowa, : Blackwell Pub., 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green reaction media in organic synthesis / / edited by Koichi Mikami
| Green reaction media in organic synthesis / / edited by Koichi Mikami |
| Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
| Descrizione fisica | 1 online resource (202 p.) |
| Disciplina | 660/.2844 |
| Altri autori (Persone) | MikamiKoichi |
| Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
| ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
| Record Nr. | UNINA-9910877880603321 |
| Ames, Iowa, : Blackwell Pub., 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNINA-9910145417103321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNISA-996203979703316 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström
| Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
| Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
| ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
| Classificazione |
35.52
35.51 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
| Record Nr. | UNINA-9910830256103321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
