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The chemistry of the carbon-nitrogen double bond
The chemistry of the carbon-nitrogen double bond
Autore Patai Saul
Pubbl/distr/stampa [Place of publication not identified], : Interscience Publishers, 1970
Disciplina 547/.044
Collana Chemistry of functional groups The chemistry of the carbon-nitrogen double bond
Soggetto topico Organonitrogen compounds
Methylenimine
Schiff bases
Imines
Nitrogen
Chemistry, Organic
Elements
Organic Chemicals
Gases
Chemistry
Chemicals and Drugs
Inorganic Chemicals
Natural Science Disciplines
Disciplines and Occupations
Organic Chemistry
Physical Sciences & Mathematics
ISBN 0-470-77825-3
0-470-77120-8
0-470-77134-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISA-996206402603316
Patai Saul  
[Place of publication not identified], : Interscience Publishers, 1970
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
The chemistry of the carbon-nitrogen double bond
The chemistry of the carbon-nitrogen double bond
Autore Patai Saul
Pubbl/distr/stampa [Place of publication not identified], : Interscience Publishers, 1970
Disciplina 547/.044
Collana Chemistry of functional groups The chemistry of the carbon-nitrogen double bond
Soggetto topico Organonitrogen compounds
Methylenimine
Schiff bases
Imines
Nitrogen
Chemistry, Organic
Elements
Organic Chemicals
Gases
Chemistry
Chemicals and Drugs
Inorganic Chemicals
Natural Science Disciplines
Disciplines and Occupations
Organic Chemistry
Physical Sciences & Mathematics
ISBN 0-470-77825-3
0-470-77120-8
0-470-77134-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910139414803321
Patai Saul  
[Place of publication not identified], : Interscience Publishers, 1970
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
The chemistry of the carbon-nitrogen double bond
The chemistry of the carbon-nitrogen double bond
Autore Patai Saul
Pubbl/distr/stampa [Place of publication not identified], : Interscience Publishers, 1970
Disciplina 547/.044
Collana Chemistry of functional groups The chemistry of the carbon-nitrogen double bond
Soggetto topico Organonitrogen compounds
Methylenimine
Schiff bases
Imines
Nitrogen
Chemistry, Organic
Elements
Organic Chemicals
Gases
Chemistry
Chemicals and Drugs
Inorganic Chemicals
Natural Science Disciplines
Disciplines and Occupations
Organic Chemistry
Physical Sciences & Mathematics
ISBN 0-470-77825-3
0-470-77120-8
0-470-77134-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910831099003321
Patai Saul  
[Place of publication not identified], : Interscience Publishers, 1970
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
The chemistry of the carbon-nitrogen double bond
The chemistry of the carbon-nitrogen double bond
Autore Patai Saul
Pubbl/distr/stampa [Place of publication not identified], : Interscience Publishers, 1970
Disciplina 547/.044
Collana Chemistry of functional groups The chemistry of the carbon-nitrogen double bond
Soggetto topico Organonitrogen compounds
Methylenimine
Schiff bases
Imines
Nitrogen
Chemistry, Organic
Elements
Organic Chemicals
Gases
Chemistry
Chemicals and Drugs
Inorganic Chemicals
Natural Science Disciplines
Disciplines and Occupations
Organic Chemistry
Physical Sciences & Mathematics
ISBN 0-470-77825-3
0-470-77120-8
0-470-77134-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910877704203321
Patai Saul  
[Place of publication not identified], : Interscience Publishers, 1970
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Schiff base metal complexes : synthesis and applications / / edited by Pranjit Barman and Anmol Singh
Schiff base metal complexes : synthesis and applications / / edited by Pranjit Barman and Anmol Singh
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH GmbH, , [2023]
Descrizione fisica 1 online resource (224 pages)
Disciplina 541.2242
Soggetto topico Schiff bases
ISBN 3-527-83947-X
3-527-83945-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Copyright -- Contents -- Preface -- Part I Introduction -- Chapter 1 Historical Background -- 1.1 Introduction -- 1.2 Theories of Coordinate Bond -- 1.2.1 Valence Bond Theory -- 1.2.2 Crystal Field Theory -- 1.2.3 Molecular Orbital Theory -- 1.2.4 Ligand Field Theory -- References -- Chapter 2 Classification -- 2.1 Ligands -- 2.2 Schiff Base -- 2.3 Types of Schiff Base -- 2.3.1 Salen‐type Ligands -- 2.3.2 Salophen‐type Ligands -- 2.3.3 Hydrazone‐type Ligands -- 2.3.4 Thiosemicarbazone/Carbazone‐type Ligands -- 2.3.5 Heterocyclic Schiff Bases -- 2.4 Different Bonding Modes of Schiff Bases -- 2.4.1 Monodentate -- 2.4.2 Bidentate -- 2.4.3 Tridentate -- 2.4.4 Tetradentate -- 2.4.5 Pentadentate -- 2.4.6 Hexadentate -- References -- Chapter 3 Different Routes of Synthesis -- 3.1 Formation of Schiff Bases -- 3.1.1 Direct Ligand Synthesis -- 3.1.2 Template Synthesis -- 3.1.3 Rearrangement of Heterocycles (Oxazoles, Thiazoles, etc.) -- References -- Chapter 4 Schiff Base Metal Complexes -- References -- Chapter 5 Effect of Different Parameters on Schiff Base and their Metal Complex -- 5.1 Ionic Charge -- 5.2 Ionic Size -- 5.3 Nature of Central Metal Ions -- 5.4 Nature of the Ligand -- 5.4.1 Basic Character of the Ligand -- 5.4.2 Size and Charge of the Ligand -- 5.4.3 Concentration of Ligand -- 5.4.4 Substitution Effect -- 5.4.5 Chelating Effect -- 5.4.6 Nature of Solvent -- 5.4.7 Crystal Field Effect -- 5.4.8 Thermodynamic and Kinetic Effect -- References -- Chapter 6 Thioether and Chiral Schiff Base -- 6.1 Thioether Schiff Base -- 6.2 Chiral Schiff Base -- References -- Part II Synthesis -- Chapter 7 General Routes of Synthesis -- 7.1 Introduction -- 7.2 Mechanism of the Synthesis of Schiff Base Ligand -- 7.3 Problems Found in Conventional Method - Hydrolysis of C N Bond -- References.
Chapter 8 Different Route of Synthesis of Schiff Base‐Metal Complexes -- 8.1 Introduction -- 8.2 Different Chemical Routes -- 8.2.1 Preparation of Schiff's Bases via Aerobic Oxidative Synthesis -- 8.2.2 Synthesis of Schiff Bases via Addition of Organometallic Reagents to Cyanides -- 8.2.3 Reaction of Phenol with Nitriles to Form SB -- 8.2.4 Reaction of Metal Amides to Ketone to Form SB -- 8.2.5 Reaction of Nitroso Compounds with Active Hydrogen Compounds -- 8.2.6 Dehydrogenation of Amines -- 8.2.7 Oxidation of Metal Amines to Form SB -- 8.2.8 Reduction of Carbon-Nitrogen Compounds -- 8.2.9 Synthesis of SB from Ketals -- 8.2.10 SB Synthesis by Using Hydrazoic Acid -- 8.2.11 SB Synthesis by Using Sodium Hypochlorite -- 8.2.12 Preparation of N‐metallo Imines -- 8.2.13 Preparation of N‐metallo Imines (Metal & -- equals -- B, Al, Si, Sn) -- 8.2.13.1 Preparation of N‐boryl and N‐aluminum Imines -- 8.2.13.2 Preparation of N‐silylimines via -- 8.2.13.3 Preparation of N‐tin Imines -- 8.3 Different Methods -- 8.3.1 Classical or Conventional Method -- 8.3.2 Microwave Irradiation Method -- 8.3.3 Water as Solvent Method -- 8.3.4 Grindstone Technique -- 8.3.5 Ultrasonic Method -- 8.3.6 Green Method Using Green Catalyst -- References -- Chapter 9 Synthesis and Mechanism of Schiff Base‐Metal Complexes -- 9.1 Introduction -- 9.2 Synthesis of Schiff Bases Metal Complexes -- 9.2.1 Synthesis of Ligand Followed by Complexation -- 9.2.2 One‐Step Process or Template Synthesis -- 9.3 Synthesis of Some of the Schiff Base Metal Complexes -- References -- Chapter 10 Synthesis and Mechanism of Chiral and Achiral Schiff Base and Their Metal Complexes -- 10.1 Introduction -- 10.2 Synthesis of Chiral and Achiral SB Ligand -- 10.3 Synthesis of Chiral SB Metal Complexes -- 10.4 Chiral Schiff Bases of Titanium, Zirconium, and Vanadium.
10.5 Chiral Schiff Bases of Main Group Metals -- 10.5.1 Manganese and Chromium Schiff Bases -- 10.5.2 Iron and Ruthenium Schiff Base Complexes -- 10.5.3 Cobalt, Nickel, Copper, and Zinc Schiff Base Complexes -- 10.5.4 Lanthanide Metal Schiff Bases -- 10.5.5 Silicon and Tin Metal Schiff Bases -- References -- Chapter 11 Synthesis and Mechanism of Thioether: Schiff Base and Their Metal Complexes -- 11.1 Introduction -- 11.2 Chemical Synthesis Procedures -- 11.2.1 Procedure for the Synthesis of Thioether‐Containing Schiff Base -- References -- Chapter 12 Computational Chemistry -- 12.1 Introduction -- 12.2 Application of DFT in the Field of Schiff Base and Their Metal Complexes -- References -- Part III Application -- Chapter 13 General Applications of Schiff Bases and Their Metal Complexes -- 13.1 Catalyst -- 13.2 Biological and Medicinal Importance -- 13.2.1 Antibacterial Activity -- 13.2.2 Anticancer and Anti‐inflammatory Agent -- 13.2.3 Antifungal Activity -- 13.2.4 As a Drug in a Number of Diseases -- 13.3 Coatings -- 13.4 Analytical Chemistry -- 13.5 Dyes -- 13.6 Semi‐conducting Materials -- 13.7 Solar System -- 13.8 Photocatalyst -- 13.9 Polymer Chemistry -- 13.10 Agrochemical Industry -- References -- Chapter 14 Application in Pharmacological Field -- 14.1 Introduction -- 14.2 Antimicrobial Activity -- 14.2.1 Schiff Bases Against Gram‐Positive Bacteria -- 14.2.2 Schiff Bases Against Gram‐Negative Bacteria -- 14.3 Antifungal Activity of Schiff Bases -- 14.4 Anticancer Activity of Schiff Bases and Their Metal Complexes -- 14.4.1 In Vitro Activity -- 14.4.2 In Vivo Activity -- 14.5 Antidyslipidemic and Antioxidant Activity -- 14.6 Anthelmintic Activity -- 14.7 Antitubercular Activity -- 14.8 Antidepressant Activity -- 14.9 Anticonvulsant Activity -- 14.10 Antioxidant Activity -- 14.11 Antiviral Activity.
14.12 Anti‐inflammatory and Analgesic Activities -- References -- Chapter 15 Application as Catalyst -- 15.1 Introduction -- 15.2 Coupling Reaction -- 15.3 Polymerization Reaction -- 15.4 Oxidation Reaction -- 15.5 Epoxidation Reaction -- 15.6 Ring‐Opening Epoxidation Reaction -- 15.7 Cyclopropanation Reaction -- 15.8 Hydrosilylation Reaction -- 15.9 Hydrogenation Reaction -- 15.10 Aldol Reaction -- 15.11 Michael Addition Reaction -- 15.12 Annulation Reaction -- 15.13 Diels-Alder Reaction -- 15.14 Click Reaction -- 15.15 Mannich Reaction -- 15.16 Ene Reaction -- 15.17 Summary -- References -- Chapter 16 Application as Drug‐Delivery System -- References -- Chapter 17 Chemosensors/Bioimaging Applications -- 17.1 Introduction -- 17.1.1 Chemosensing -- 17.1.1.1 Explosives Sensing -- 17.1.1.2 Oxygen Sensing -- 17.1.1.3 High pH Sensing -- 17.1.1.4 Other Porphyrinoid‐based Chemosensors and Chemodosimeters -- 17.1.1.5 Metal Sensing -- 17.2 Chemosensors -- 17.2.1 Fluorescence ON‐OFF -- 17.2.1.1 Tiny Molecules Chemosensors -- 17.2.1.2 Supramolecular Chemosensors -- 17.2.1.3 QDs‐based Chemosensors -- 17.2.1.4 Fluorescent Nanomaterial‐based Chemosensors -- 17.2.2 OFF‐ON Chemosensors -- 17.2.2.1 Rhodamine‐based Sensors -- 17.2.2.2 Coumarin‐based Sensors -- 17.2.2.3 BODIPY‐based Sensors -- 17.2.3 Ratiometric Fluorescent Chemosensors -- 17.2.3.1 Pyrene‐based Chemosensors -- 17.2.3.2 Fluorophore Hybridization Chemosensors -- 17.2.3.3 Dual‐emission Fluorescent Nanoparticles -- 17.2.4 Rhodamine‐based Sensors -- 17.2.4.1 Fluorescent Bioimaging of CK in HeLa cells -- 17.2.4.2 Mice Bioimaging Experiments -- 17.2.5 Fluorescent Chemosensor for AcO− Detection -- 17.2.6 CN− and Al3+ Chemosensor for Bioimaging -- 17.3 Conclusion -- References -- Chapter 18 Application in Industrial Field -- 18.1 Introduction -- 18.2 Current Status in India -- 18.3 Conclusion -- References.
Index -- EULA.
Record Nr. UNINA-9910830038303321
Weinheim, Germany : , : Wiley-VCH GmbH, , [2023]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui