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Application of SERS for Nanomaterials / / edited by Bing Zhao, Ronald Birke
Application of SERS for Nanomaterials / / edited by Bing Zhao, Ronald Birke
Pubbl/distr/stampa Basel, Switzerland : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022
Descrizione fisica 1 online resource (152 pages)
Disciplina 535.846
Soggetto topico Raman spectroscopy
Raman effect, Surface enhanced
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910674380603321
Basel, Switzerland : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Develop spectroscopy techniques for detection of trace bacteria and biological toxins in foods ... annual report
Develop spectroscopy techniques for detection of trace bacteria and biological toxins in foods ... annual report
Pubbl/distr/stampa Washington, D.C., : U.S. Dept. of Agriculture, Agricultural Research Service
Descrizione fisica : HTML files
Disciplina 363
Soggetto topico Raman effect, Surface enhanced
Spectrum analysis
Pathogenic microorganisms - Detection - United States
Food adulteration and inspection - United States
Nanochemistry
Food adulteration and inspection
Pathogenic microorganisms - Detection
Soggetto genere / forma Periodicals.
ISSN 2153-7577
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Record Nr. UNINA-9910698481003321
Washington, D.C., : U.S. Dept. of Agriculture, Agricultural Research Service
Materiale a stampa
Lo trovi qui: Univ. Federico II
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The dipole-quadrupole theory of surface enhanced Raman scattering [[electronic resource] /] / A.M. Polubotko
The dipole-quadrupole theory of surface enhanced Raman scattering [[electronic resource] /] / A.M. Polubotko
Autore Polubotko A. M
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (146 p.)
Disciplina 535.8/46
Soggetto topico Raman effect, Surface enhanced
Quadrupoles
Soggetto genere / forma Electronic books.
ISBN 1-61324-078-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910465280903321
Polubotko A. M  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
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The dipole-quadrupole theory of surface enhanced Raman scattering [[electronic resource] /] / A.M. Polubotko
The dipole-quadrupole theory of surface enhanced Raman scattering [[electronic resource] /] / A.M. Polubotko
Autore Polubotko A. M
Pubbl/distr/stampa New York, : Nova Science Publishers, c2009
Descrizione fisica 1 online resource (146 p.)
Disciplina 535.8/46
Soggetto topico Raman effect, Surface enhanced
Quadrupoles
ISBN 1-61324-078-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910791802903321
Polubotko A. M  
New York, : Nova Science Publishers, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Frontiers of surface-enhanced raman scattering : single-nanoparticles and single cells / / edited by Yukihiro Ozaki, Katrin Kneipp, Ricardo R Aroca
Frontiers of surface-enhanced raman scattering : single-nanoparticles and single cells / / edited by Yukihiro Ozaki, Katrin Kneipp, Ricardo R Aroca
Pubbl/distr/stampa Chichester, England : , : Wiley, , 2014
Descrizione fisica 1 online resource (367 p.)
Disciplina 543/.57
Soggetto topico Raman effect, Surface enhanced
Surfaces (Physics)
Raman spectroscopy
Spectrum analysis
ISBN 1-118-70360-X
1-118-70359-6
1-118-70357-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Calculation of Surface-Enhanced Raman Spectra Including Orientational and Stokes Effects Using TDDFT/Mie Theory QM/ED Method; 1.1 Introduction: Combined Quantum Mechanics/ Electrodynamics Methods; 1.2 Computational Details; 1.3 Summary of Model Systems; 1.4 Azimuthal Averaging; 1.5 SERS of Pyridine: Models G, A, B, S, and V; 1.6 Orientation Effects in SERS of Phthalocyanines; 1.7 Two Particle QM/ED Calculations; 1.8 Summary; Acknowledgment; References
Chapter 2 Non-resonant SERS Using the Hottest Hot Spots of Plasmonic Nanoaggregates2.1 Introduction; 2.2 Aggregates of Silver and Gold Nanoparticles and Their Hot Spots; 2.2.1 Evaluation of Plasmonic Nanoaggregates by Vibrational Pumping due to a Non-resonant SERS Process; 2.2.2 Probing Plasmonic Nanoaggregates by Electron Energy Loss Spectroscopy; 2.2.3 Probing Local Fields in Hot Spots by SERS and SEHRS; 2.3 SERS Using Hot Silver Nanoaggregates and Non-resonant NIR Excitation; 2.3.1 SERS Signal vs. Concentration of the Target Molecule
2.3.2 Spectroscopic Potential of Non-resonant SERS Using the Hottest Hot Spots2.4 Summary and Conclusions; References; Chapter 3 Effect of Nanoparticle Symmetry on Plasmonic Fields: Implications for Single-Molecule Raman Scattering; 3.1 Introduction; 3.2 Methodology; 3.3 Plasmon Mode Structure of Nanoparticle Clusters; 3.3.1 Dimers; 3.3.2 Trimers; 3.4 Effect of Plasmon Modes on SMSERS; 3.4.1 Effect of the Spectral Lineshape; 3.4.2 Effect of Multiple Normal Modes; 3.5 Conclusions; Acknowledgment; References
Chapter 4 Experimental Demonstration of Electromagnetic Mechanism of SERS and Quantitative Analysis of SERS Fluctuation Based on the Mechanism4.1 Experimental Demonstration of the EM Mechanism of SERS; 4.1.1 Introduction; 4.1.2 Observations of the EM Mechanism in SERS Spectral Variations; 4.1.3 Observations of the EM Mechanism in the Refractive Index Dependence of SERS Spectra; 4.1.4 Quantitative Evaluation of the EM Mechanism of SERS; 4.1.5 Summary; 4.2 Quantitative Analysis of SERS Fluctuation Based on the EM Mechanism; 4.2.1 Introduction
4.2.2 Intensity and Spectral Fluctuation in SERS and SEF4.2.3 Framework for Analysis of Fluctuation in SERS and SEF; 4.2.4 Analysis of Intensity Fluctuation in SERS and SEF; 4.2.5 Analysis of Spectral Fluctuation in SERS and SEF; 4.2.6 Summary; 4.3 Conclusion; Acknowledgments; References; Chapter 5 Single-Molecule Surface-Enhanced Raman Scattering as a Probe for Adsorption Dynamics on Metal Surfaces; 5.1 Introduction; 5.2 Simultaneous Measurements of Conductance and SERS of a Single-Molecule Junction; 5.3 SERS Observation Using Heterometallic Nanodimers at the Single-Molecule Level
5.4 Conclusion
Record Nr. UNINA-9910140286103321
Chichester, England : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Frontiers of surface-enhanced raman scattering : single-nanoparticles and single cells / / edited by Yukihiro Ozaki, Katrin Kneipp, Ricardo R Aroca
Frontiers of surface-enhanced raman scattering : single-nanoparticles and single cells / / edited by Yukihiro Ozaki, Katrin Kneipp, Ricardo R Aroca
Pubbl/distr/stampa Chichester, England : , : Wiley, , 2014
Descrizione fisica 1 online resource (367 p.)
Disciplina 543/.57
Soggetto topico Raman effect, Surface enhanced
Surfaces (Physics)
Raman spectroscopy
Spectrum analysis
ISBN 1-118-70360-X
1-118-70359-6
1-118-70357-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover; Title Page; Copyright; Contents; List of Contributors; Preface; Chapter 1 Calculation of Surface-Enhanced Raman Spectra Including Orientational and Stokes Effects Using TDDFT/Mie Theory QM/ED Method; 1.1 Introduction: Combined Quantum Mechanics/ Electrodynamics Methods; 1.2 Computational Details; 1.3 Summary of Model Systems; 1.4 Azimuthal Averaging; 1.5 SERS of Pyridine: Models G, A, B, S, and V; 1.6 Orientation Effects in SERS of Phthalocyanines; 1.7 Two Particle QM/ED Calculations; 1.8 Summary; Acknowledgment; References
Chapter 2 Non-resonant SERS Using the Hottest Hot Spots of Plasmonic Nanoaggregates2.1 Introduction; 2.2 Aggregates of Silver and Gold Nanoparticles and Their Hot Spots; 2.2.1 Evaluation of Plasmonic Nanoaggregates by Vibrational Pumping due to a Non-resonant SERS Process; 2.2.2 Probing Plasmonic Nanoaggregates by Electron Energy Loss Spectroscopy; 2.2.3 Probing Local Fields in Hot Spots by SERS and SEHRS; 2.3 SERS Using Hot Silver Nanoaggregates and Non-resonant NIR Excitation; 2.3.1 SERS Signal vs. Concentration of the Target Molecule
2.3.2 Spectroscopic Potential of Non-resonant SERS Using the Hottest Hot Spots2.4 Summary and Conclusions; References; Chapter 3 Effect of Nanoparticle Symmetry on Plasmonic Fields: Implications for Single-Molecule Raman Scattering; 3.1 Introduction; 3.2 Methodology; 3.3 Plasmon Mode Structure of Nanoparticle Clusters; 3.3.1 Dimers; 3.3.2 Trimers; 3.4 Effect of Plasmon Modes on SMSERS; 3.4.1 Effect of the Spectral Lineshape; 3.4.2 Effect of Multiple Normal Modes; 3.5 Conclusions; Acknowledgment; References
Chapter 4 Experimental Demonstration of Electromagnetic Mechanism of SERS and Quantitative Analysis of SERS Fluctuation Based on the Mechanism4.1 Experimental Demonstration of the EM Mechanism of SERS; 4.1.1 Introduction; 4.1.2 Observations of the EM Mechanism in SERS Spectral Variations; 4.1.3 Observations of the EM Mechanism in the Refractive Index Dependence of SERS Spectra; 4.1.4 Quantitative Evaluation of the EM Mechanism of SERS; 4.1.5 Summary; 4.2 Quantitative Analysis of SERS Fluctuation Based on the EM Mechanism; 4.2.1 Introduction
4.2.2 Intensity and Spectral Fluctuation in SERS and SEF4.2.3 Framework for Analysis of Fluctuation in SERS and SEF; 4.2.4 Analysis of Intensity Fluctuation in SERS and SEF; 4.2.5 Analysis of Spectral Fluctuation in SERS and SEF; 4.2.6 Summary; 4.3 Conclusion; Acknowledgments; References; Chapter 5 Single-Molecule Surface-Enhanced Raman Scattering as a Probe for Adsorption Dynamics on Metal Surfaces; 5.1 Introduction; 5.2 Simultaneous Measurements of Conductance and SERS of a Single-Molecule Junction; 5.3 SERS Observation Using Heterometallic Nanodimers at the Single-Molecule Level
5.4 Conclusion
Record Nr. UNINA-9910807373703321
Chichester, England : , : Wiley, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles of surface-enhanced Raman spectroscopy [[electronic resource] ] : and related plasmonic effects / / Eric C. Le Ru and Pablo G. Etchegoin
Principles of surface-enhanced Raman spectroscopy [[electronic resource] ] : and related plasmonic effects / / Eric C. Le Ru and Pablo G. Etchegoin
Autore Le Ru Eric C
Edizione [1st ed.]
Pubbl/distr/stampa Amsterdam ; ; Boston, : Elsevier, 2009
Descrizione fisica 1 online resource (688 p.)
Disciplina 543.57
Altri autori (Persone) EtchegoinPablo G (Pablo Gabriel)
Soggetto topico Raman spectroscopy
Raman effect, Surface enhanced
Plasmons (Physics)
Soggetto genere / forma Electronic books.
ISBN 1-282-16909-2
9786612169090
0-08-093155-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front cover; Half title; Title; Copyright page; Table of Contents; Preface; Notations, units and other conventions; Chapter 1. A quick overview of surface-enhanced Raman spectroscopy; What is SERS? -- Basic principles; SERS probes and SERS substrates; SERS substrates; SERS probes; Example; Other important aspects of SERS; SERS enhancements; Sample preparation and metal/probe interaction; Main characteristics of the SERS signals; Related techniques; Related areas; Applications of SERS; Raman with improved sensitivity; SERS vs fluorescence spectroscopy; Applications specific to SERS
The current status of SERS Brief history of SERS; Where is SERS now?; Current `hot topics'; Overview of the book content; General outline of the book; General `spirit' of the book; Different reading plans; Chapter 2. Raman spectroscopy and related optical techniques; A brief introduction; The discovery of the Raman effect; Some applications of Raman spectroscopy; Raman spectroscopy instrumentation; Optical spectroscopy of molecules; The energy levels of molecules; Spectroscopic units and conversions; Optical absorption; Emission and luminescence; Scattering processes
The concept of cross-section The Raman cross-sections; Examples of Raman cross-sections; Mechanical analogs; Absorption and fluorescence spectroscopy; Optical absorption and UV/Vis spectroscopy; Fluorescence spectroscopy; Photo-bleaching; Phenomenological approach to Raman scattering; Dipolar emission in vacuum; The concepts of polarizability and induced dipole; The linear optical polarizability; The Raman polarizability; The local field correction; Polarizabilities and scattering cross-sections; Final remarks on the phenomenological description; Vibrations and the Raman tensor
General considerations A primer on vibrational analysis; The Raman tensor; Link to the Raman polarizability; Limitations of the classical approach; A brief overview of related Raman scattering processes; Quantum (or semi-classical) approach to Raman scattering; Justification of the classical approach; The quantization of vibrations; The full expressions for the Raman cross-section; The anti-Stokes to Stokes ratio; Advanced aspects of vibrations in molecules; More on vibrational analysis; More on symmetries and Raman selection rules; Modeling of molecular structure and vibrations; Summary
Chapter 3. Introduction to plasmons and plasmonics Plasmonics and SERS; The optical properties of noble metals; The Drude model of the optical response; The optical properties of real metals; Non-local optical properties; What makes the metal--light interaction so special?; What are plasmons?; The plasmon confusion; Definition and history; The relation between plasmons and the dielectric function; Electromagnetic modes in infinite systems; Electromagnetic modes of a system of material bodies; Classification of electromagnetic modes; Other properties of electromagnetic modes
Summary and discussion
Record Nr. UNINA-9910454144803321
Le Ru Eric C  
Amsterdam ; ; Boston, : Elsevier, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles of surface-enhanced Raman spectroscopy [[electronic resource] ] : and related plasmonic effects / / Eric C. Le Ru and Pablo G. Etchegoin
Principles of surface-enhanced Raman spectroscopy [[electronic resource] ] : and related plasmonic effects / / Eric C. Le Ru and Pablo G. Etchegoin
Autore Le Ru Eric C
Edizione [1st ed.]
Pubbl/distr/stampa Amsterdam ; ; Boston, : Elsevier, 2009
Descrizione fisica 1 online resource (688 p.)
Disciplina 543.57
Altri autori (Persone) EtchegoinPablo G (Pablo Gabriel)
Soggetto topico Raman spectroscopy
Raman effect, Surface enhanced
Plasmons (Physics)
ISBN 1-282-16909-2
9786612169090
0-08-093155-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front cover; Half title; Title; Copyright page; Table of Contents; Preface; Notations, units and other conventions; Chapter 1. A quick overview of surface-enhanced Raman spectroscopy; What is SERS? -- Basic principles; SERS probes and SERS substrates; SERS substrates; SERS probes; Example; Other important aspects of SERS; SERS enhancements; Sample preparation and metal/probe interaction; Main characteristics of the SERS signals; Related techniques; Related areas; Applications of SERS; Raman with improved sensitivity; SERS vs fluorescence spectroscopy; Applications specific to SERS
The current status of SERS Brief history of SERS; Where is SERS now?; Current `hot topics'; Overview of the book content; General outline of the book; General `spirit' of the book; Different reading plans; Chapter 2. Raman spectroscopy and related optical techniques; A brief introduction; The discovery of the Raman effect; Some applications of Raman spectroscopy; Raman spectroscopy instrumentation; Optical spectroscopy of molecules; The energy levels of molecules; Spectroscopic units and conversions; Optical absorption; Emission and luminescence; Scattering processes
The concept of cross-section The Raman cross-sections; Examples of Raman cross-sections; Mechanical analogs; Absorption and fluorescence spectroscopy; Optical absorption and UV/Vis spectroscopy; Fluorescence spectroscopy; Photo-bleaching; Phenomenological approach to Raman scattering; Dipolar emission in vacuum; The concepts of polarizability and induced dipole; The linear optical polarizability; The Raman polarizability; The local field correction; Polarizabilities and scattering cross-sections; Final remarks on the phenomenological description; Vibrations and the Raman tensor
General considerations A primer on vibrational analysis; The Raman tensor; Link to the Raman polarizability; Limitations of the classical approach; A brief overview of related Raman scattering processes; Quantum (or semi-classical) approach to Raman scattering; Justification of the classical approach; The quantization of vibrations; The full expressions for the Raman cross-section; The anti-Stokes to Stokes ratio; Advanced aspects of vibrations in molecules; More on vibrational analysis; More on symmetries and Raman selection rules; Modeling of molecular structure and vibrations; Summary
Chapter 3. Introduction to plasmons and plasmonics Plasmonics and SERS; The optical properties of noble metals; The Drude model of the optical response; The optical properties of real metals; Non-local optical properties; What makes the metal--light interaction so special?; What are plasmons?; The plasmon confusion; Definition and history; The relation between plasmons and the dielectric function; Electromagnetic modes in infinite systems; Electromagnetic modes of a system of material bodies; Classification of electromagnetic modes; Other properties of electromagnetic modes
Summary and discussion
Record Nr. UNINA-9910782540003321
Le Ru Eric C  
Amsterdam ; ; Boston, : Elsevier, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Surface enhanced Raman spectroscopy : analytical, biophysical and life science applications / / edited by Sebastian Schlücker
Surface enhanced Raman spectroscopy : analytical, biophysical and life science applications / / edited by Sebastian Schlücker
Edizione [4th ed.]
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2011]
Descrizione fisica 1 online resource (355 p.)
Disciplina 543.57
Altri autori (Persone) SchlückerSebastian
Collana THEi Wiley ebooks
Soggetto topico Raman spectroscopy
Raman effect, Surface enhanced
ISBN 3-527-63275-1
3-527-63276-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Surface Enhanced Raman Spectroscopy; Contents; Preface; List of Contributors; 1 Basic Electromagnetic Theory of SERS; 1.1 Introduction; 1.2 Plasmon Resonances and Field Enhancements; 1.2.1 Optical Properties of Simple Metals; 1.2.2 Planar Surfaces; 1.2.3 The Metallic Cylinder (2D) and Sphere (3D); 1.2.3.1 The Electrostatic Approximation; 1.2.3.2 Localized Surface Plasmon Resonances of the Cylinder; 1.2.3.3 Localized Surface Plasmon Resonances of the Sphere; 1.2.3.4 Local Field Enhancements; 1.2.4 Size Effects; 1.2.5 Shape Effects; 1.2.6 Interacting Objects and Gaps
1.2.6.1 Coupled Plasmon Resonances1.2.6.2 Tip-Enhanced Raman Scattering (TERS); 1.2.7 Choice of Metal; 1.2.7.1 Gold versus Silver; 1.2.7.2 Other Coinage and Transition Metals; 1.3 Field Enhancement Distribution and Localization; 1.3.1 Electromagnetic Hot Spots; 1.3.2 Long-Tail Distribution of Enhancements; 1.4 Electromagnetic Model for the SERS and Fluorescence Enhancement Factors; 1.4.1 Enhanced Absorption; 1.4.2 Comparison of Raman and Fluorescence Processes; 1.4.3 The |E|4 Approximation to SERS Enhancement Factors; 1.4.4 Fluorescence Quenching and Enhancement
1.4.5 Comparison of SERS and Fluorescence Enhancements1.4.6 Other Forms of Enhancements; 1.5 The Magnitude of the SERS Enhancement Factor in Typical Cases; 1.6 Conclusions; References; 2 Nanoparticle SERS Substrates; 2.1 Introduction; 2.2 Preparation and Stability of Metal Nanoparticle Colloidal SERS Substrates; 2.2.1 Colloidal Spherical Metal Nanoparticles; 2.2.1.1 Chemical Reaction for Metal Nanoparticle Preparation; 2.2.1.2 Laser Ablation and Photoreduction for Metal Nanoparticle Preparation; 2.2.1.3 Size Effect of SERS Signal on Metal Nanoparticles
2.2.1.4 Near-Infrared (NIR) Excitation for SERS on Metal Nanoparticles2.2.1.5 Stability of the Metal Nanoparticle Colloids; 2.2.2 Aggregation of Metal Nanoparticles; 2.2.3 Bimetallic Nanoparticle SERS Substrate; 2.2.4 Nanoparticles with Various Shapes; 2.3 Characterization of Nanoparticle-Based SERS Substrates; 2.4 Nanoparticles on the Unfunctionalized Solid Surface as SERS Substrates; 2.5 Conclusion and Outlook; References; 3 Quantitative SERS Methods; 3.1 Introduction; 3.2 SERS Media; 3.3 Stability and Shelf Life; 3.4 Reproducibility and Internal Standards; 3.5 Selectivity; 3.6 Conclusion
References4 Single-Molecule- and Trace Detection by SERS; 4.1 Introduction; 4.1.1 SERS; 4.1.2 The Two Regimes: Ensemble and Trace/SM; 4.1.3 Requirements for SM-SERS; 4.2 Experiments and Results; 4.2.1 The Langmuir-Blodgett Method for SM-SERRS; 4.2.2 LB SM-SERRS to Biologically Relevant Systems; 4.2.3 Experimental Details; 4.2.4 Single-Molecule Examples; 4.2.4.1 Tagged Phospholipid; 4.2.4.2 R18, Octadecyl Rhodamine B; 4.3 Conclusions; References; 5 Detection of Persistent Organic Pollutants by Using SERS Sensors Based on Organically Functionalized Ag Nanoparticles; 5.1 Introduction
5.2 Inclusion Hosts
Record Nr. UNINA-9910139004503321
Weinheim, Germany : , : Wiley-VCH, , [2011]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Surface enhanced Raman spectroscopy : analytical, biophysical and life science applications / / edited by Sebastian Schlücker
Surface enhanced Raman spectroscopy : analytical, biophysical and life science applications / / edited by Sebastian Schlücker
Edizione [4th ed.]
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2011]
Descrizione fisica 1 online resource (355 p.)
Disciplina 543.57
Altri autori (Persone) SchlückerSebastian
Collana THEi Wiley ebooks
Soggetto topico Raman spectroscopy
Raman effect, Surface enhanced
ISBN 3-527-63275-1
3-527-63276-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Surface Enhanced Raman Spectroscopy; Contents; Preface; List of Contributors; 1 Basic Electromagnetic Theory of SERS; 1.1 Introduction; 1.2 Plasmon Resonances and Field Enhancements; 1.2.1 Optical Properties of Simple Metals; 1.2.2 Planar Surfaces; 1.2.3 The Metallic Cylinder (2D) and Sphere (3D); 1.2.3.1 The Electrostatic Approximation; 1.2.3.2 Localized Surface Plasmon Resonances of the Cylinder; 1.2.3.3 Localized Surface Plasmon Resonances of the Sphere; 1.2.3.4 Local Field Enhancements; 1.2.4 Size Effects; 1.2.5 Shape Effects; 1.2.6 Interacting Objects and Gaps
1.2.6.1 Coupled Plasmon Resonances1.2.6.2 Tip-Enhanced Raman Scattering (TERS); 1.2.7 Choice of Metal; 1.2.7.1 Gold versus Silver; 1.2.7.2 Other Coinage and Transition Metals; 1.3 Field Enhancement Distribution and Localization; 1.3.1 Electromagnetic Hot Spots; 1.3.2 Long-Tail Distribution of Enhancements; 1.4 Electromagnetic Model for the SERS and Fluorescence Enhancement Factors; 1.4.1 Enhanced Absorption; 1.4.2 Comparison of Raman and Fluorescence Processes; 1.4.3 The |E|4 Approximation to SERS Enhancement Factors; 1.4.4 Fluorescence Quenching and Enhancement
1.4.5 Comparison of SERS and Fluorescence Enhancements1.4.6 Other Forms of Enhancements; 1.5 The Magnitude of the SERS Enhancement Factor in Typical Cases; 1.6 Conclusions; References; 2 Nanoparticle SERS Substrates; 2.1 Introduction; 2.2 Preparation and Stability of Metal Nanoparticle Colloidal SERS Substrates; 2.2.1 Colloidal Spherical Metal Nanoparticles; 2.2.1.1 Chemical Reaction for Metal Nanoparticle Preparation; 2.2.1.2 Laser Ablation and Photoreduction for Metal Nanoparticle Preparation; 2.2.1.3 Size Effect of SERS Signal on Metal Nanoparticles
2.2.1.4 Near-Infrared (NIR) Excitation for SERS on Metal Nanoparticles2.2.1.5 Stability of the Metal Nanoparticle Colloids; 2.2.2 Aggregation of Metal Nanoparticles; 2.2.3 Bimetallic Nanoparticle SERS Substrate; 2.2.4 Nanoparticles with Various Shapes; 2.3 Characterization of Nanoparticle-Based SERS Substrates; 2.4 Nanoparticles on the Unfunctionalized Solid Surface as SERS Substrates; 2.5 Conclusion and Outlook; References; 3 Quantitative SERS Methods; 3.1 Introduction; 3.2 SERS Media; 3.3 Stability and Shelf Life; 3.4 Reproducibility and Internal Standards; 3.5 Selectivity; 3.6 Conclusion
References4 Single-Molecule- and Trace Detection by SERS; 4.1 Introduction; 4.1.1 SERS; 4.1.2 The Two Regimes: Ensemble and Trace/SM; 4.1.3 Requirements for SM-SERS; 4.2 Experiments and Results; 4.2.1 The Langmuir-Blodgett Method for SM-SERRS; 4.2.2 LB SM-SERRS to Biologically Relevant Systems; 4.2.3 Experimental Details; 4.2.4 Single-Molecule Examples; 4.2.4.1 Tagged Phospholipid; 4.2.4.2 R18, Octadecyl Rhodamine B; 4.3 Conclusions; References; 5 Detection of Persistent Organic Pollutants by Using SERS Sensors Based on Organically Functionalized Ag Nanoparticles; 5.1 Introduction
5.2 Inclusion Hosts
Record Nr. UNINA-9910827041203321
Weinheim, Germany : , : Wiley-VCH, , [2011]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui