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Handbook of free radical initiators [[electronic resource] /] / E.T. Denisov, T.G. Denisova, T.S. Pokidova
| Handbook of free radical initiators [[electronic resource] /] / E.T. Denisov, T.G. Denisova, T.S. Pokidova |
| Autore | Denisov E. T (Evgeniĭ Timofeevich) |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2003 |
| Descrizione fisica | 1 online resource (903 p.) |
| Disciplina | 541.224 |
| Altri autori (Persone) |
DenisovaTaissa G
PokidovaT. S (Tamara S.) |
| Soggetto topico |
Radicals (Chemistry)
Free radicals (Chemistry) Free radicals (Chemistry) - Mechanism of action |
| ISBN |
1-280-27268-6
9786610272686 0-470-30573-8 0-471-28183-2 0-471-72147-6 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CONTENTS; Preface; Symbols and Abbreviations; 1 Mechanisms of Decomposition of Initiators; 2 Cage Effect; 3 Methods of Study of Initiator Decomposition and Free Radical Generation; 4 Dialkyl Peroxides and Hydroperoxides; 5 Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides; 6 Organic Polyoxides; 7 Azo Compounds; 8 Compounds with weak C-C, N-N, C-N, and N-O Bonds; 9 Parabolic Model of Bimolecular Homolytic Reaction; 10 Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen; 11 Bimolecular Reactions of Free Radical Generation by Ozone
12 Bimolecular Reactions of Hydroperoxides with Free Radical Generation13 Free Radical Generation by Olefins; 14 Initiation by Haloid Molecules and Nitrogen Dioxide; 15 Free Radical Generation by Reactions of Ions with Molecules; 16 Isomerization and Decomposition of Free Radicals; 17 Free Radical Abstraction Reactions; 18 Free Radical Reactions for Hydrogen Transfer and Substitution; 19 Free Radical Addition; 20 Recombination and Disproportionation of Free Radicals; Index |
| Record Nr. | UNINA-9910146086103321 |
Denisov E. T (Evgeniĭ Timofeevich)
|
||
| Hoboken, N.J., : Wiley-Interscience, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of free radical initiators [[electronic resource] /] / E.T. Denisov, T.G. Denisova, T.S. Pokidova
| Handbook of free radical initiators [[electronic resource] /] / E.T. Denisov, T.G. Denisova, T.S. Pokidova |
| Autore | Denisov E. T (Evgeniĭ Timofeevich) |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2003 |
| Descrizione fisica | 1 online resource (903 p.) |
| Disciplina | 541.224 |
| Altri autori (Persone) |
DenisovaTaissa G
PokidovaT. S (Tamara S.) |
| Soggetto topico |
Radicals (Chemistry)
Free radicals (Chemistry) Free radicals (Chemistry) - Mechanism of action |
| ISBN |
1-280-27268-6
9786610272686 0-470-30573-8 0-471-28183-2 0-471-72147-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CONTENTS; Preface; Symbols and Abbreviations; 1 Mechanisms of Decomposition of Initiators; 2 Cage Effect; 3 Methods of Study of Initiator Decomposition and Free Radical Generation; 4 Dialkyl Peroxides and Hydroperoxides; 5 Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides; 6 Organic Polyoxides; 7 Azo Compounds; 8 Compounds with weak C-C, N-N, C-N, and N-O Bonds; 9 Parabolic Model of Bimolecular Homolytic Reaction; 10 Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen; 11 Bimolecular Reactions of Free Radical Generation by Ozone
12 Bimolecular Reactions of Hydroperoxides with Free Radical Generation13 Free Radical Generation by Olefins; 14 Initiation by Haloid Molecules and Nitrogen Dioxide; 15 Free Radical Generation by Reactions of Ions with Molecules; 16 Isomerization and Decomposition of Free Radicals; 17 Free Radical Abstraction Reactions; 18 Free Radical Reactions for Hydrogen Transfer and Substitution; 19 Free Radical Addition; 20 Recombination and Disproportionation of Free Radicals; Index |
| Record Nr. | UNINA-9910830244303321 |
|
Denisov E. T (Evgeniĭ Timofeevich)
|
||
| Hoboken, N.J., : Wiley-Interscience, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of free radical initiators / / E.T. Denisov, T.G. Denisova, T.S. Pokidova
| Handbook of free radical initiators / / E.T. Denisov, T.G. Denisova, T.S. Pokidova |
| Autore | Denisov E. T (Evgenii Timofeevich) |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2003 |
| Descrizione fisica | 1 online resource (903 p.) |
| Disciplina | 541.2/24 |
| Altri autori (Persone) |
DenisovaTaissa G
PokidovaT. S (Tamara S.) |
| Soggetto topico |
Radicals (Chemistry)
Free radicals (Chemistry) Free radicals (Chemistry) - Mechanism of action |
| ISBN |
1-280-27268-6
9786610272686 0-470-30573-8 0-471-28183-2 0-471-72147-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CONTENTS; Preface; Symbols and Abbreviations; 1 Mechanisms of Decomposition of Initiators; 2 Cage Effect; 3 Methods of Study of Initiator Decomposition and Free Radical Generation; 4 Dialkyl Peroxides and Hydroperoxides; 5 Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides; 6 Organic Polyoxides; 7 Azo Compounds; 8 Compounds with weak C-C, N-N, C-N, and N-O Bonds; 9 Parabolic Model of Bimolecular Homolytic Reaction; 10 Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen; 11 Bimolecular Reactions of Free Radical Generation by Ozone
12 Bimolecular Reactions of Hydroperoxides with Free Radical Generation13 Free Radical Generation by Olefins; 14 Initiation by Haloid Molecules and Nitrogen Dioxide; 15 Free Radical Generation by Reactions of Ions with Molecules; 16 Isomerization and Decomposition of Free Radicals; 17 Free Radical Abstraction Reactions; 18 Free Radical Reactions for Hydrogen Transfer and Substitution; 19 Free Radical Addition; 20 Recombination and Disproportionation of Free Radicals; Index |
| Record Nr. | UNINA-9910877258803321 |
|
Denisov E. T (Evgenii Timofeevich)
|
||
| Hoboken, N.J., : Wiley-Interscience, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Radicals in organic synthesis : formation of carbon-carbon bonds / Bernd Giese
| Radicals in organic synthesis : formation of carbon-carbon bonds / Bernd Giese |
| Autore | Giese, Bernd |
| Pubbl/distr/stampa | Oxford : Pergamon Press, c1986 |
| Descrizione fisica | xiii, 294 p. : ill. ; 24 cm |
| Disciplina | 547.2 |
| Collana | Organic chemistry series ; 5 |
| Soggetto topico |
Chemistry, Organic - Synthesis
Chemistry, physical organic Free radicals (Chemistry) Organic compounds - Synthesis Radicals (Chemistry) Reactivity (Chemistry) |
| ISBN | 0080324940 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003550739707536 |
|
Giese, Bernd
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| Oxford : Pergamon Press, c1986 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Rate constants for reactions of aliphatic carbon-centered radicals in aqueous solution [[electronic resource] /] / Alberta B. Ross and Pedatsur Neta
| Rate constants for reactions of aliphatic carbon-centered radicals in aqueous solution [[electronic resource] /] / Alberta B. Ross and Pedatsur Neta |
| Autore | Ross Alberta B |
| Pubbl/distr/stampa | Washington, [D.C.] : , : U.S. Dept. of Commerce, National Bureau of Standards, , 1982 |
| Descrizione fisica | v, 96 pages ; ; 28 cm |
| Altri autori (Persone) | NetaPedatsur |
| Collana | NSRDS-NBS |
| Soggetto topico |
Chemical kinetics
Radicals (Chemistry) |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910697864303321 |
|
Ross Alberta B
|
||
| Washington, [D.C.] : , : U.S. Dept. of Commerce, National Bureau of Standards, , 1982 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rate constants for reactions of inorganic radicals in aqueous solution [[electronic resource] /] / Alberta B. Ross and Pedatsur Neta
| Rate constants for reactions of inorganic radicals in aqueous solution [[electronic resource] /] / Alberta B. Ross and Pedatsur Neta |
| Autore | Ross Alberta B |
| Pubbl/distr/stampa | Washington, [D.C.] : , : U.S. Dept. of Commerce, National Bureau of Standards, , 1979 |
| Descrizione fisica | v, 55 pages ; ; 26 cm |
| Altri autori (Persone) | NetaPedatsur |
| Collana | NSRDS-NBS |
| Soggetto topico |
Chemical kinetics
Radicals (Chemistry) |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910697865003321 |
|
Ross Alberta B
|
||
| Washington, [D.C.] : , : U.S. Dept. of Commerce, National Bureau of Standards, , 1979 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Stabilization of free radicals at low temperatures : summary of the NBS program / / edited by Arnold M. Bass and H.P. Broida
| Stabilization of free radicals at low temperatures : summary of the NBS program / / edited by Arnold M. Bass and H.P. Broida |
| Autore | Bass Arnold M (Arnold Marvin), <1922-> |
| Pubbl/distr/stampa | Washington, D.C. : , : U.S. Dept. of the Commerce, National Bureau of Standards : , : G.P.O., , 1960 |
| Descrizione fisica | 1 online resource (iii, 120 pages) : illustrations |
| Disciplina | 541.368 |
| Collana | NBS monograph |
| Soggetto topico |
Low temperatures
Radicals (Chemistry) |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Stabilization of free radicals at low temperatures |
| Record Nr. | UNINA-9910712909303321 |
|
Bass Arnold M (Arnold Marvin), <1922->
|
||
| Washington, D.C. : , : U.S. Dept. of the Commerce, National Bureau of Standards : , : G.P.O., , 1960 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel
| Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel |
| Autore | Curran Dennis P. |
| Pubbl/distr/stampa | Weinheim, Germany : , : VCH, , 1996 |
| Descrizione fisica | 1 online resource (294 p.) |
| Disciplina |
541.223
547.139 |
| Soggetto topico |
Free radical reactions
Radicals (Chemistry) Stereochemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-84273-7
9786611842734 3-527-61523-7 3-527-61522-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Stereochemistry of Radical Reactions; Table of Contents; Chapter 1 Radical Reactions in Organic Synthesis; 1.1 Introduction; 1.2 Principles of Radical Reactions; 1.2.1 General Considerations; 1.2.2 Medium and Temperature Effects; 1.2.3 Stereochemical Features of Carbon-Centered Radicals; 1.2.4 Reactions of Radicals; 1.3 Methods to Conduct Radical Reactions; 1.3.1 Chain Methods; 1.3.1.1 Tributyltin and Tris(trimethylsilyl)silicon Hydride; 1.3.1.2 Allyltributylstannane; 1.3.1.3 Atom and Group Transfer Reactions; 1.3.1.4 Thiohydroxamates; 1.3.2 Non-Chain Methods
1.4 Comparisons of Stereoselective Radical Reactions with Ionic and Pericyclic AnalogsReferences; Chapter 2 Substrate Control: Radical Cyclizations; 2.1 Introduction; 2.2 Face-Selective Radical Cyclizations to Multiple Bonds; 2.2.1 Butenyl and Related Radical Cyclizations; 2.2.2 Pentenyl and Related Radical Cyclizations; 2.2.3 Hexenyl and Related Radical Cyclizations; 2.2.3.1 5-Exo Cyclizations, the Beckwith-Houk Transition State Model; 2.2.3.2 Stereoselectivities of Acyclic Hexenyl Radicals; 2.2.3.3 Stereoselectivities in Cyclic Systems; 2.2.3.4 6-Endo Cyclizations 2.2.4 Heptenyl and Related Radical Cyclizations2.2.5 Higher Cyclizations; 2.2.6 Radicals Bearing Stereocenters Outside the Cyclizing Unit; 2.3 Stereocontrol in Cyclization/Fragmentation Sequences; 2.4 Group-Selective Cyclizations; 2.4.1 Two Acceptors/One Precursor; 2.4.2 Two Precursors/One Acceptor; 2.5 Cyclizations under Thermodynamic Control; 2.6 Cyclization by Intramolecular Homolytic Substitution; References; Chapter 3 Substrate Control: Cyclic Systems; 3.1 Cyclic Radicals; 3.1.1 Three- and Four-Membered Cyclic Radicals; 3.1.2 Five-Membered Cyclic Radicals; 3.1.2.1 Endocyclic Substituents 3.1.2.2 Exocyclic Substituents3.1.2.3 Additive and Medium Effects; 3.1.2.4 Multiple Substitution; 3.1.3 Six-Membered Cyclic Radicals; 3.1.3.1 Steric Effect of Substituents; 3.1.3.2 Stereoelectronic Effects; 3.1.3.3 Exocyclic Substituents; 3.1.3.4 Medium Effects; 3.1.3.5 Multiple Substitution; 3.2 Cyclic Radical Traps; References; Chapter 4 Substrate Control: Acyclic Systems; 4.1 Acyclic Radicals; 4.1.1 Allylic Strain Effects: Ester-Substituted Radicals; 4.1.1.1 Effect of Polar Substituents; 4.1.1.2 Hydrogen Bond and Complexation Effects 4.1.1.3 Effect of Substituents at the Prostereogenic Center4.1.2 Allylic Strain-Inducing Substituents; 4.1.3 The Felkin-Anh Rule for Radicals; 4.1.3.1 Complexation Effects; 4.1.4 Sulfoxides and Phosphine Oxides; 4.2 Acyclic Radical Traps; References; Chapter 5 Chiral Auxiliary Control; 5.1 General Considerations; 5.1.1 Radical Addition; 5.1.2 Atom and Group Transfer Reactions; 5.2 Auxiliary Group Attached to the Radical Center; 5.2.1 Radical Stabilization by Delocalization; 5.2.2 Structure and Dynamics of Radicals a to Amides; 5.2.3 Amide Chiral Auxiliaries for Acyclic Free Radical Reactions 5.2.3.1 C2 Symmetry |
| Record Nr. | UNINA-9910144280703321 |
|
Curran Dennis P.
|
||
| Weinheim, Germany : , : VCH, , 1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel
| Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel |
| Autore | Curran Dennis P. |
| Pubbl/distr/stampa | Weinheim, Germany : , : VCH, , 1996 |
| Descrizione fisica | 1 online resource (294 p.) |
| Disciplina |
541.223
547.139 |
| Soggetto topico |
Free radical reactions
Radicals (Chemistry) Stereochemistry |
| ISBN |
1-281-84273-7
9786611842734 3-527-61523-7 3-527-61522-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Stereochemistry of Radical Reactions; Table of Contents; Chapter 1 Radical Reactions in Organic Synthesis; 1.1 Introduction; 1.2 Principles of Radical Reactions; 1.2.1 General Considerations; 1.2.2 Medium and Temperature Effects; 1.2.3 Stereochemical Features of Carbon-Centered Radicals; 1.2.4 Reactions of Radicals; 1.3 Methods to Conduct Radical Reactions; 1.3.1 Chain Methods; 1.3.1.1 Tributyltin and Tris(trimethylsilyl)silicon Hydride; 1.3.1.2 Allyltributylstannane; 1.3.1.3 Atom and Group Transfer Reactions; 1.3.1.4 Thiohydroxamates; 1.3.2 Non-Chain Methods
1.4 Comparisons of Stereoselective Radical Reactions with Ionic and Pericyclic AnalogsReferences; Chapter 2 Substrate Control: Radical Cyclizations; 2.1 Introduction; 2.2 Face-Selective Radical Cyclizations to Multiple Bonds; 2.2.1 Butenyl and Related Radical Cyclizations; 2.2.2 Pentenyl and Related Radical Cyclizations; 2.2.3 Hexenyl and Related Radical Cyclizations; 2.2.3.1 5-Exo Cyclizations, the Beckwith-Houk Transition State Model; 2.2.3.2 Stereoselectivities of Acyclic Hexenyl Radicals; 2.2.3.3 Stereoselectivities in Cyclic Systems; 2.2.3.4 6-Endo Cyclizations 2.2.4 Heptenyl and Related Radical Cyclizations2.2.5 Higher Cyclizations; 2.2.6 Radicals Bearing Stereocenters Outside the Cyclizing Unit; 2.3 Stereocontrol in Cyclization/Fragmentation Sequences; 2.4 Group-Selective Cyclizations; 2.4.1 Two Acceptors/One Precursor; 2.4.2 Two Precursors/One Acceptor; 2.5 Cyclizations under Thermodynamic Control; 2.6 Cyclization by Intramolecular Homolytic Substitution; References; Chapter 3 Substrate Control: Cyclic Systems; 3.1 Cyclic Radicals; 3.1.1 Three- and Four-Membered Cyclic Radicals; 3.1.2 Five-Membered Cyclic Radicals; 3.1.2.1 Endocyclic Substituents 3.1.2.2 Exocyclic Substituents3.1.2.3 Additive and Medium Effects; 3.1.2.4 Multiple Substitution; 3.1.3 Six-Membered Cyclic Radicals; 3.1.3.1 Steric Effect of Substituents; 3.1.3.2 Stereoelectronic Effects; 3.1.3.3 Exocyclic Substituents; 3.1.3.4 Medium Effects; 3.1.3.5 Multiple Substitution; 3.2 Cyclic Radical Traps; References; Chapter 4 Substrate Control: Acyclic Systems; 4.1 Acyclic Radicals; 4.1.1 Allylic Strain Effects: Ester-Substituted Radicals; 4.1.1.1 Effect of Polar Substituents; 4.1.1.2 Hydrogen Bond and Complexation Effects 4.1.1.3 Effect of Substituents at the Prostereogenic Center4.1.2 Allylic Strain-Inducing Substituents; 4.1.3 The Felkin-Anh Rule for Radicals; 4.1.3.1 Complexation Effects; 4.1.4 Sulfoxides and Phosphine Oxides; 4.2 Acyclic Radical Traps; References; Chapter 5 Chiral Auxiliary Control; 5.1 General Considerations; 5.1.1 Radical Addition; 5.1.2 Atom and Group Transfer Reactions; 5.2 Auxiliary Group Attached to the Radical Center; 5.2.1 Radical Stabilization by Delocalization; 5.2.2 Structure and Dynamics of Radicals a to Amides; 5.2.3 Amide Chiral Auxiliaries for Acyclic Free Radical Reactions 5.2.3.1 C2 Symmetry |
| Record Nr. | UNISA-996202137603316 |
|
Curran Dennis P.
|
||
| Weinheim, Germany : , : VCH, , 1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel
| Stereochemistry of radical reactions : concepts, guidelines, and synthetic applications / / Dennis P. Curran, Ned A. Porter, Bernd Giese ; with a foreword by Ernest L. Eliel |
| Autore | Curran Dennis P. |
| Pubbl/distr/stampa | Weinheim, Germany : , : VCH, , 1996 |
| Descrizione fisica | 1 online resource (294 p.) |
| Disciplina |
541.223
547.139 |
| Soggetto topico |
Free radical reactions
Radicals (Chemistry) Stereochemistry |
| ISBN |
1-281-84273-7
9786611842734 3-527-61523-7 3-527-61522-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Stereochemistry of Radical Reactions; Table of Contents; Chapter 1 Radical Reactions in Organic Synthesis; 1.1 Introduction; 1.2 Principles of Radical Reactions; 1.2.1 General Considerations; 1.2.2 Medium and Temperature Effects; 1.2.3 Stereochemical Features of Carbon-Centered Radicals; 1.2.4 Reactions of Radicals; 1.3 Methods to Conduct Radical Reactions; 1.3.1 Chain Methods; 1.3.1.1 Tributyltin and Tris(trimethylsilyl)silicon Hydride; 1.3.1.2 Allyltributylstannane; 1.3.1.3 Atom and Group Transfer Reactions; 1.3.1.4 Thiohydroxamates; 1.3.2 Non-Chain Methods
1.4 Comparisons of Stereoselective Radical Reactions with Ionic and Pericyclic AnalogsReferences; Chapter 2 Substrate Control: Radical Cyclizations; 2.1 Introduction; 2.2 Face-Selective Radical Cyclizations to Multiple Bonds; 2.2.1 Butenyl and Related Radical Cyclizations; 2.2.2 Pentenyl and Related Radical Cyclizations; 2.2.3 Hexenyl and Related Radical Cyclizations; 2.2.3.1 5-Exo Cyclizations, the Beckwith-Houk Transition State Model; 2.2.3.2 Stereoselectivities of Acyclic Hexenyl Radicals; 2.2.3.3 Stereoselectivities in Cyclic Systems; 2.2.3.4 6-Endo Cyclizations 2.2.4 Heptenyl and Related Radical Cyclizations2.2.5 Higher Cyclizations; 2.2.6 Radicals Bearing Stereocenters Outside the Cyclizing Unit; 2.3 Stereocontrol in Cyclization/Fragmentation Sequences; 2.4 Group-Selective Cyclizations; 2.4.1 Two Acceptors/One Precursor; 2.4.2 Two Precursors/One Acceptor; 2.5 Cyclizations under Thermodynamic Control; 2.6 Cyclization by Intramolecular Homolytic Substitution; References; Chapter 3 Substrate Control: Cyclic Systems; 3.1 Cyclic Radicals; 3.1.1 Three- and Four-Membered Cyclic Radicals; 3.1.2 Five-Membered Cyclic Radicals; 3.1.2.1 Endocyclic Substituents 3.1.2.2 Exocyclic Substituents3.1.2.3 Additive and Medium Effects; 3.1.2.4 Multiple Substitution; 3.1.3 Six-Membered Cyclic Radicals; 3.1.3.1 Steric Effect of Substituents; 3.1.3.2 Stereoelectronic Effects; 3.1.3.3 Exocyclic Substituents; 3.1.3.4 Medium Effects; 3.1.3.5 Multiple Substitution; 3.2 Cyclic Radical Traps; References; Chapter 4 Substrate Control: Acyclic Systems; 4.1 Acyclic Radicals; 4.1.1 Allylic Strain Effects: Ester-Substituted Radicals; 4.1.1.1 Effect of Polar Substituents; 4.1.1.2 Hydrogen Bond and Complexation Effects 4.1.1.3 Effect of Substituents at the Prostereogenic Center4.1.2 Allylic Strain-Inducing Substituents; 4.1.3 The Felkin-Anh Rule for Radicals; 4.1.3.1 Complexation Effects; 4.1.4 Sulfoxides and Phosphine Oxides; 4.2 Acyclic Radical Traps; References; Chapter 5 Chiral Auxiliary Control; 5.1 General Considerations; 5.1.1 Radical Addition; 5.1.2 Atom and Group Transfer Reactions; 5.2 Auxiliary Group Attached to the Radical Center; 5.2.1 Radical Stabilization by Delocalization; 5.2.2 Structure and Dynamics of Radicals a to Amides; 5.2.3 Amide Chiral Auxiliaries for Acyclic Free Radical Reactions 5.2.3.1 C2 Symmetry |
| Record Nr. | UNINA-9910830960003321 |
|
Curran Dennis P.
|
||
| Weinheim, Germany : , : VCH, , 1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
