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MARC Lista (tabellare)
Development of new radical cascades and multi-component reactions : application to the synthesis of nitrogen-containing heterocycles / / Marie-Helene Larraufie
Development of new radical cascades and multi-component reactions : application to the synthesis of nitrogen-containing heterocycles / / Marie-Helene Larraufie
Autore Larraufie Marie-Helene
Edizione [1st ed. 2014.]
Pubbl/distr/stampa Cham [Switzerland] : , : Springer, , 2014
Descrizione fisica 1 online resource (xxii, 326 pages) : illustrations (some color)
Disciplina 547.590459
Collana Springer Theses, Recognizing Outstanding Ph.D. Research
Soggetto topico Heterocyclic compounds
Calcium cyanamide
Quinazoline
Guanidine
ISBN 3-319-01324-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto INTRODUCTION -- PART A: N-ACYLCYANAMIDES AS NEW PARTNERS IN RADICAL CASCADES: SYNTHESIS OF POLYCYCLIC QUINAZOLINONES AND GUANIDINES -- THE CYANAMIDE MOIETY, SYNTHESIS AND REACTIVITY -- HOMOLYTIC AROMATIC SUBSTITUTIONS: STATE OF THE ART OF THE MECHANISTIC PROPOSALS -- RESULTS: DEVELOPMENTS OF NEW RADICAL CASCADES WITH N-ACYLCYANAMIDES -- OBJECTIVES OF THE PROJECT -- ADDITION OF ALKYL RADICALS -- ADDITION OF VINYL RADICALS TO N-ACYLCYANAMIDES -- ADDITION OF NITROGEN CENTERED RADICALS -- PREPARATION AND CYCLIZATION OF ALKYL PRECURSORS -- PREPARATION AND CYCLIZATION OF VINYL PRECURSORS -- PREPARATION AND CYCLIZATION OF AZIDE PRECURSORS -- PART B: VISIBLE-LIGHT PHOTOREDUCTIVE CATALYSIS FOR AN ECO-COMPATIBLE GENERATION OF RADICALS -- BIBLIOGRAPHICAL BACKGROUNDS: GENERATION OF RADICALS BY VISIBLE LIGHT PHOTOREDOX CATALYSIS -- PHOTOPHYSICAL PROPERTIES OF TRIS(BIPYRIDYL)RUTHENIUM(II) COMPLEXES -- STATE OF THE ART OF THE SUBSTRATES AMENABLE TO VISIBLE LIGHT PHOTOREDOX CATALYSIS -- RESULTS: VISIBLE LIGHT-INDUCED PHOTOREDUCTIVE GENERATION OF RADICALS FROM EPOXIDES AND AZIRIDINES -- EPOXIDES AS NEW SUBSTRATES FOR VISIBLE-LIGHT TRIGGERED GENERATION OF RADICALS -- SCOPE AND LIMITATIONS OF THE REDUCTIVE RING-OPENING METHODOLOGY -- UTILIZATION OF THE PHOTOGENERATED RADICALS IN CARBON-CARBON BOND FORMATIONS -- SUPPORTING INFORMATION -- GENERAL REMARKS -- GENERAL PROCEDURES -- EPOXIDE, AZIRIDINES AND CYCLOPROPANES PRECURSORS -- REDUCTIVE RING-OPENING PRODUCTS -- ALLYLATION PRODUCTS 246 -- PART C: NEW DEVELOPMENTS IN ARYL-ARYL COUPLINGS VIA PALLADIUM/NORBORNENE DUAL CATALYSIS: SYNTHESIS OF PHENANTHRIDINES AND PHENANTHRENES -- BIBLIOGRAPHICAL BACKGROUND: THE ORTHO EFFECT IN THE CATELLANI REACTION -- THE CATELLANI REACTION -- SYNTHETIC APPLICATIONS OF THE ORTHO EFFECT -- MECHANISTIC EXPLANATIONS FOR THE ORTHO EFFECT -- RESULTS: NEW PARTNERS FOR ORTHO-SUBSTITUTED ARYL IODIDES IN PALLADIUM/NORBORNENE COCATALYSIS -- COUPLING OF ORTHO-SUBSTITUTED ARYL IODIDES AND BROMOBENZYL AMINES: FIRST REPORTED CATELLANI SEQUENCE TERMINATED BY N-ARYL COUPLING WITH UNPROTECTED AMINES -- COUPLING OF ORTHO-SUBSTITUTED ARYL IODIDES AND 2-BROMOPHENYL ACETAMIDES: AN EXCEPTION TO THE ORTHO EFFECT -- SUPPORTING INFORMATION -- GENERAL REMARKS -- COUPLING OF ORTHO-SUBSTITUTED ARYL IODIDES AND BROMOBENZYL AMINES -- COUPLING OF ORTHO-SUBSTITUTED ARYL IODIDES AND 2-BROMOPHENYL ACETAMIDES.
Record Nr. UNINA-9910298659303321
Larraufie Marie-Helene  
Cham [Switzerland] : , : Springer, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Autore Armarego W. L. F
Edizione [99th ed.]
Pubbl/distr/stampa New York, : Interscience Publishers, 1967
Descrizione fisica 1 online resource (564 p.)
Disciplina 547/.59/05
Altri autori (Persone) BrownD. J
Collana The chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
Soggetto genere / forma Electronic books.
ISBN 1-282-30711-8
9786612307119
0-470-18691-7
0-470-18839-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; Tables; I. Introduction; 1. History; 2. Nomenclature; 3. The Dual Character of Quinazolines; 4. General Summary of Quinazoline Chemistry; A. Syntheses; a. Primary Syntheses; b. Secondary Syntheses; B. The Heightened Reactivity of 2- and 4-Alkyl Groups; C. Addition and Substitution Reactions, and Nucleophilic Metathesis; D. N-Oxides; E. Tautomerism; F. Oxidation and Reduction; G. Rearrangements; H. Biological Activity in Quinazolines; 5. Tables; Introduction; 6. References; II. Quinazoline; 1. Synthesis of Quinazoline; 2. Physical Properties
II.1. Quinazoline and 3-Alkyl Derivatives A. Theoretical Aspects; B. Spectra; a. Ultraviolet Spectra; b. Phosphorescence Spectra; c. Infrared Spectra; d. Proton Magnetic Resonance Spectra; e. Mass Spectra; C. Covalent Hydration; a. Covalent Hydration in Quinazoline; b. Effect of Substituents in the Pyrimidine Ring on Covalent Hydration; (i) Effect of substituents in position 4; (ii) Effect of saubstituenta in position 2; c. Effect Substituents in the Benzene Ring on Covalent Hydration; II.2. Electronic Effects and Hydration in 2-Substituted Quinazoline Cations
II.3. Ionization and Covalent Hydration of Quinazolines in Water at 20°II.4. Ionization Constants of Substituted Quinazolines in Water at 20°; D. Polarography; 3. Chemical Reactivity of Quinazoline; A. Hydrolysis, Oxidation, and Reduction; B. Electrophilic and Nucleophilic Substitution, and Alkylation; C. Addition Reactions; 4. References; III. C-Alkyl- and C-Arylquinazolines; 1. Methods of Preparation; A. Bischler's Synthesis; B. Oxidation of 3, 4-Dihydroquinazolines; C. Decarboxylation of Acids; D. From N'-ToIuene-p-sulphonylydrazino Derivatives; E. From Imidoyl Chlorides and Nitriles
F. From Aryl Diazonium Salts and NitrilesG. From 4-Chloro or 4-cyanoquinazolines and Grignard Reagents; H. From Chloro- or Cyanoquinazolines and Substances with an Active Methylene Group; I. Reidel's Synthesis; J. Miscellaneous; 2. Properties; A. Physical Properties; B. Chemical Properties; a. The Heightened Reactivity of 2- and 4-Methyl Groups; b. Oxidation and Reduction; c. Electrophilic Substitution; d. Alkylation; e. Reactivity of the Substituted Carbon Atoms Attached to C(2)and C(4); 3. Tables; III.1. 2-Alkyl- and Aryl- (including Heteroaryl-) quinazolines
III.2. 4-Alkyl- and Aryl- (including Heteroaryl-) quinazolineaIII.3. 2,4-Disubstituted Alkyl- and Arylquinazolines; III.4. Alkylquinazolines Substituted in the Benzene Ring; III.5. Alkyl- and Arylquinazolines Substituted in Both Rings; III.6. Miscellaneous Alkyl- and Arylquinazolines (including Quina-zolinium Salts}; 4. References; IV. Oxoquinazolines and 5-, 6-, 7-, and 8-Hydroxyquinazolines; 1. 2-Oxoquinazolines; A. Preparation; B. Properties; 2. 3,4- and 1,4-Dihydro-4-oxoquinasolines; A. Preparation of 3,4-Dihydro-4-oxoquinszolines; a. Niementowski's Synthesis
b. Cyclization of o-Amidobenzamides
Record Nr. UNINA-9910144282403321
Armarego W. L. F  
New York, : Interscience Publishers, 1967
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Autore Armarego W. L. F
Edizione [99th ed.]
Pubbl/distr/stampa New York, : Interscience Publishers, 1967
Descrizione fisica 1 online resource (564 p.)
Disciplina 547/.59/05
Altri autori (Persone) BrownD. J
Collana The chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30711-8
9786612307119
0-470-18691-7
0-470-18839-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; Tables; I. Introduction; 1. History; 2. Nomenclature; 3. The Dual Character of Quinazolines; 4. General Summary of Quinazoline Chemistry; A. Syntheses; a. Primary Syntheses; b. Secondary Syntheses; B. The Heightened Reactivity of 2- and 4-Alkyl Groups; C. Addition and Substitution Reactions, and Nucleophilic Metathesis; D. N-Oxides; E. Tautomerism; F. Oxidation and Reduction; G. Rearrangements; H. Biological Activity in Quinazolines; 5. Tables; Introduction; 6. References; II. Quinazoline; 1. Synthesis of Quinazoline; 2. Physical Properties
II.1. Quinazoline and 3-Alkyl Derivatives A. Theoretical Aspects; B. Spectra; a. Ultraviolet Spectra; b. Phosphorescence Spectra; c. Infrared Spectra; d. Proton Magnetic Resonance Spectra; e. Mass Spectra; C. Covalent Hydration; a. Covalent Hydration in Quinazoline; b. Effect of Substituents in the Pyrimidine Ring on Covalent Hydration; (i) Effect of substituents in position 4; (ii) Effect of saubstituenta in position 2; c. Effect Substituents in the Benzene Ring on Covalent Hydration; II.2. Electronic Effects and Hydration in 2-Substituted Quinazoline Cations
II.3. Ionization and Covalent Hydration of Quinazolines in Water at 20°II.4. Ionization Constants of Substituted Quinazolines in Water at 20°; D. Polarography; 3. Chemical Reactivity of Quinazoline; A. Hydrolysis, Oxidation, and Reduction; B. Electrophilic and Nucleophilic Substitution, and Alkylation; C. Addition Reactions; 4. References; III. C-Alkyl- and C-Arylquinazolines; 1. Methods of Preparation; A. Bischler's Synthesis; B. Oxidation of 3, 4-Dihydroquinazolines; C. Decarboxylation of Acids; D. From N'-ToIuene-p-sulphonylydrazino Derivatives; E. From Imidoyl Chlorides and Nitriles
F. From Aryl Diazonium Salts and NitrilesG. From 4-Chloro or 4-cyanoquinazolines and Grignard Reagents; H. From Chloro- or Cyanoquinazolines and Substances with an Active Methylene Group; I. Reidel's Synthesis; J. Miscellaneous; 2. Properties; A. Physical Properties; B. Chemical Properties; a. The Heightened Reactivity of 2- and 4-Methyl Groups; b. Oxidation and Reduction; c. Electrophilic Substitution; d. Alkylation; e. Reactivity of the Substituted Carbon Atoms Attached to C(2)and C(4); 3. Tables; III.1. 2-Alkyl- and Aryl- (including Heteroaryl-) quinazolines
III.2. 4-Alkyl- and Aryl- (including Heteroaryl-) quinazolineaIII.3. 2,4-Disubstituted Alkyl- and Arylquinazolines; III.4. Alkylquinazolines Substituted in the Benzene Ring; III.5. Alkyl- and Arylquinazolines Substituted in Both Rings; III.6. Miscellaneous Alkyl- and Arylquinazolines (including Quina-zolinium Salts}; 4. References; IV. Oxoquinazolines and 5-, 6-, 7-, and 8-Hydroxyquinazolines; 1. 2-Oxoquinazolines; A. Preparation; B. Properties; 2. 3,4- and 1,4-Dihydro-4-oxoquinasolines; A. Preparation of 3,4-Dihydro-4-oxoquinszolines; a. Niementowski's Synthesis
b. Cyclization of o-Amidobenzamides
Record Nr. UNISA-996202924503316
Armarego W. L. F  
New York, : Interscience Publishers, 1967
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Autore Armarego W. L. F
Edizione [99th ed.]
Pubbl/distr/stampa New York, : Interscience Publishers, 1967
Descrizione fisica 1 online resource (564 p.)
Disciplina 547/.59/05
Altri autori (Persone) BrownD. J
Collana The chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30711-8
9786612307119
0-470-18691-7
0-470-18839-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; Tables; I. Introduction; 1. History; 2. Nomenclature; 3. The Dual Character of Quinazolines; 4. General Summary of Quinazoline Chemistry; A. Syntheses; a. Primary Syntheses; b. Secondary Syntheses; B. The Heightened Reactivity of 2- and 4-Alkyl Groups; C. Addition and Substitution Reactions, and Nucleophilic Metathesis; D. N-Oxides; E. Tautomerism; F. Oxidation and Reduction; G. Rearrangements; H. Biological Activity in Quinazolines; 5. Tables; Introduction; 6. References; II. Quinazoline; 1. Synthesis of Quinazoline; 2. Physical Properties
II.1. Quinazoline and 3-Alkyl Derivatives A. Theoretical Aspects; B. Spectra; a. Ultraviolet Spectra; b. Phosphorescence Spectra; c. Infrared Spectra; d. Proton Magnetic Resonance Spectra; e. Mass Spectra; C. Covalent Hydration; a. Covalent Hydration in Quinazoline; b. Effect of Substituents in the Pyrimidine Ring on Covalent Hydration; (i) Effect of substituents in position 4; (ii) Effect of saubstituenta in position 2; c. Effect Substituents in the Benzene Ring on Covalent Hydration; II.2. Electronic Effects and Hydration in 2-Substituted Quinazoline Cations
II.3. Ionization and Covalent Hydration of Quinazolines in Water at 20°II.4. Ionization Constants of Substituted Quinazolines in Water at 20°; D. Polarography; 3. Chemical Reactivity of Quinazoline; A. Hydrolysis, Oxidation, and Reduction; B. Electrophilic and Nucleophilic Substitution, and Alkylation; C. Addition Reactions; 4. References; III. C-Alkyl- and C-Arylquinazolines; 1. Methods of Preparation; A. Bischler's Synthesis; B. Oxidation of 3, 4-Dihydroquinazolines; C. Decarboxylation of Acids; D. From N'-ToIuene-p-sulphonylydrazino Derivatives; E. From Imidoyl Chlorides and Nitriles
F. From Aryl Diazonium Salts and NitrilesG. From 4-Chloro or 4-cyanoquinazolines and Grignard Reagents; H. From Chloro- or Cyanoquinazolines and Substances with an Active Methylene Group; I. Reidel's Synthesis; J. Miscellaneous; 2. Properties; A. Physical Properties; B. Chemical Properties; a. The Heightened Reactivity of 2- and 4-Methyl Groups; b. Oxidation and Reduction; c. Electrophilic Substitution; d. Alkylation; e. Reactivity of the Substituted Carbon Atoms Attached to C(2)and C(4); 3. Tables; III.1. 2-Alkyl- and Aryl- (including Heteroaryl-) quinazolines
III.2. 4-Alkyl- and Aryl- (including Heteroaryl-) quinazolineaIII.3. 2,4-Disubstituted Alkyl- and Arylquinazolines; III.4. Alkylquinazolines Substituted in the Benzene Ring; III.5. Alkyl- and Arylquinazolines Substituted in Both Rings; III.6. Miscellaneous Alkyl- and Arylquinazolines (including Quina-zolinium Salts}; 4. References; IV. Oxoquinazolines and 5-, 6-, 7-, and 8-Hydroxyquinazolines; 1. 2-Oxoquinazolines; A. Preparation; B. Properties; 2. 3,4- and 1,4-Dihydro-4-oxoquinasolines; A. Preparation of 3,4-Dihydro-4-oxoquinszolines; a. Niementowski's Synthesis
b. Cyclization of o-Amidobenzamides
Record Nr. UNINA-9910643715403321
Armarego W. L. F  
New York, : Interscience Publishers, 1967
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Autore Armarego W. L. F
Edizione [99th ed.]
Pubbl/distr/stampa New York, : Interscience Publishers, 1967
Descrizione fisica 1 online resource (564 p.)
Disciplina 547/.59/05
Altri autori (Persone) BrownD. J
Collana The chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30711-8
9786612307119
0-470-18691-7
0-470-18839-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; Tables; I. Introduction; 1. History; 2. Nomenclature; 3. The Dual Character of Quinazolines; 4. General Summary of Quinazoline Chemistry; A. Syntheses; a. Primary Syntheses; b. Secondary Syntheses; B. The Heightened Reactivity of 2- and 4-Alkyl Groups; C. Addition and Substitution Reactions, and Nucleophilic Metathesis; D. N-Oxides; E. Tautomerism; F. Oxidation and Reduction; G. Rearrangements; H. Biological Activity in Quinazolines; 5. Tables; Introduction; 6. References; II. Quinazoline; 1. Synthesis of Quinazoline; 2. Physical Properties
II.1. Quinazoline and 3-Alkyl Derivatives A. Theoretical Aspects; B. Spectra; a. Ultraviolet Spectra; b. Phosphorescence Spectra; c. Infrared Spectra; d. Proton Magnetic Resonance Spectra; e. Mass Spectra; C. Covalent Hydration; a. Covalent Hydration in Quinazoline; b. Effect of Substituents in the Pyrimidine Ring on Covalent Hydration; (i) Effect of substituents in position 4; (ii) Effect of saubstituenta in position 2; c. Effect Substituents in the Benzene Ring on Covalent Hydration; II.2. Electronic Effects and Hydration in 2-Substituted Quinazoline Cations
II.3. Ionization and Covalent Hydration of Quinazolines in Water at 20°II.4. Ionization Constants of Substituted Quinazolines in Water at 20°; D. Polarography; 3. Chemical Reactivity of Quinazoline; A. Hydrolysis, Oxidation, and Reduction; B. Electrophilic and Nucleophilic Substitution, and Alkylation; C. Addition Reactions; 4. References; III. C-Alkyl- and C-Arylquinazolines; 1. Methods of Preparation; A. Bischler's Synthesis; B. Oxidation of 3, 4-Dihydroquinazolines; C. Decarboxylation of Acids; D. From N'-ToIuene-p-sulphonylydrazino Derivatives; E. From Imidoyl Chlorides and Nitriles
F. From Aryl Diazonium Salts and NitrilesG. From 4-Chloro or 4-cyanoquinazolines and Grignard Reagents; H. From Chloro- or Cyanoquinazolines and Substances with an Active Methylene Group; I. Reidel's Synthesis; J. Miscellaneous; 2. Properties; A. Physical Properties; B. Chemical Properties; a. The Heightened Reactivity of 2- and 4-Methyl Groups; b. Oxidation and Reduction; c. Electrophilic Substitution; d. Alkylation; e. Reactivity of the Substituted Carbon Atoms Attached to C(2)and C(4); 3. Tables; III.1. 2-Alkyl- and Aryl- (including Heteroaryl-) quinazolines
III.2. 4-Alkyl- and Aryl- (including Heteroaryl-) quinazolineaIII.3. 2,4-Disubstituted Alkyl- and Arylquinazolines; III.4. Alkylquinazolines Substituted in the Benzene Ring; III.5. Alkyl- and Arylquinazolines Substituted in Both Rings; III.6. Miscellaneous Alkyl- and Arylquinazolines (including Quina-zolinium Salts}; 4. References; IV. Oxoquinazolines and 5-, 6-, 7-, and 8-Hydroxyquinazolines; 1. 2-Oxoquinazolines; A. Preparation; B. Properties; 2. 3,4- and 1,4-Dihydro-4-oxoquinasolines; A. Preparation of 3,4-Dihydro-4-oxoquinszolines; a. Niementowski's Synthesis
b. Cyclization of o-Amidobenzamides
Record Nr. UNINA-9910830530203321
Armarego W. L. F  
New York, : Interscience Publishers, 1967
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Fused pyrimidines . Part I Quinazolines [[electronic resource] /] / W.L.F. Armarego; edited by D.J. Brown
Autore Armarego W. L. F
Edizione [99th ed.]
Pubbl/distr/stampa New York, : Interscience Publishers, 1967
Descrizione fisica 1 online resource (564 p.)
Disciplina 547/.59/05
Altri autori (Persone) BrownD. J
Collana The chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30711-8
9786612307119
0-470-18691-7
0-470-18839-1
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; Tables; I. Introduction; 1. History; 2. Nomenclature; 3. The Dual Character of Quinazolines; 4. General Summary of Quinazoline Chemistry; A. Syntheses; a. Primary Syntheses; b. Secondary Syntheses; B. The Heightened Reactivity of 2- and 4-Alkyl Groups; C. Addition and Substitution Reactions, and Nucleophilic Metathesis; D. N-Oxides; E. Tautomerism; F. Oxidation and Reduction; G. Rearrangements; H. Biological Activity in Quinazolines; 5. Tables; Introduction; 6. References; II. Quinazoline; 1. Synthesis of Quinazoline; 2. Physical Properties
II.1. Quinazoline and 3-Alkyl Derivatives A. Theoretical Aspects; B. Spectra; a. Ultraviolet Spectra; b. Phosphorescence Spectra; c. Infrared Spectra; d. Proton Magnetic Resonance Spectra; e. Mass Spectra; C. Covalent Hydration; a. Covalent Hydration in Quinazoline; b. Effect of Substituents in the Pyrimidine Ring on Covalent Hydration; (i) Effect of substituents in position 4; (ii) Effect of saubstituenta in position 2; c. Effect Substituents in the Benzene Ring on Covalent Hydration; II.2. Electronic Effects and Hydration in 2-Substituted Quinazoline Cations
II.3. Ionization and Covalent Hydration of Quinazolines in Water at 20°II.4. Ionization Constants of Substituted Quinazolines in Water at 20°; D. Polarography; 3. Chemical Reactivity of Quinazoline; A. Hydrolysis, Oxidation, and Reduction; B. Electrophilic and Nucleophilic Substitution, and Alkylation; C. Addition Reactions; 4. References; III. C-Alkyl- and C-Arylquinazolines; 1. Methods of Preparation; A. Bischler's Synthesis; B. Oxidation of 3, 4-Dihydroquinazolines; C. Decarboxylation of Acids; D. From N'-ToIuene-p-sulphonylydrazino Derivatives; E. From Imidoyl Chlorides and Nitriles
F. From Aryl Diazonium Salts and NitrilesG. From 4-Chloro or 4-cyanoquinazolines and Grignard Reagents; H. From Chloro- or Cyanoquinazolines and Substances with an Active Methylene Group; I. Reidel's Synthesis; J. Miscellaneous; 2. Properties; A. Physical Properties; B. Chemical Properties; a. The Heightened Reactivity of 2- and 4-Methyl Groups; b. Oxidation and Reduction; c. Electrophilic Substitution; d. Alkylation; e. Reactivity of the Substituted Carbon Atoms Attached to C(2)and C(4); 3. Tables; III.1. 2-Alkyl- and Aryl- (including Heteroaryl-) quinazolines
III.2. 4-Alkyl- and Aryl- (including Heteroaryl-) quinazolineaIII.3. 2,4-Disubstituted Alkyl- and Arylquinazolines; III.4. Alkylquinazolines Substituted in the Benzene Ring; III.5. Alkyl- and Arylquinazolines Substituted in Both Rings; III.6. Miscellaneous Alkyl- and Arylquinazolines (including Quina-zolinium Salts}; 4. References; IV. Oxoquinazolines and 5-, 6-, 7-, and 8-Hydroxyquinazolines; 1. 2-Oxoquinazolines; A. Preparation; B. Properties; 2. 3,4- and 1,4-Dihydro-4-oxoquinasolines; A. Preparation of 3,4-Dihydro-4-oxoquinszolines; a. Niementowski's Synthesis
b. Cyclization of o-Amidobenzamides
Record Nr. UNINA-9910840726103321
Armarego W. L. F  
New York, : Interscience Publishers, 1967
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Autore Brown D. J
Pubbl/distr/stampa New York, : J. Wiley, c1996
Descrizione fisica 1 online resource (760 p.)
Disciplina 547.593
547/.59/05
547/.593
Collana Chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
Soggetto genere / forma Electronic books.
ISBN 1-282-30612-X
9786612306129
0-470-18795-6
0-470-18894-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; CHAPTER 1. PRIMARY SYNTHESES; 1.1 From a Single Benzene Substrate; 1.1.1 By Formation of the 1,2-Bond; 1.1.2 By Formation of the 1,Sa-Bond; 1.1.3 By Formation of the 2,3-Bond; 1.1.3.1. From o-Acylaminobenzamides; 1.1.3.2 From o-Acylaminobenzamide Oximes; 1.1.3.3 From o-(A1koxycarbonylamino)-benzamides; 1.1.3.4 From o-Ureidobenzamides; 1.1.3.5 From o-(Benzylideneamino)benz-amides; 1.1.3.6 From o-Acylaminobenzonitriles; 1.1.3.7 From o-(Substituted Methylene-amin0)benzonitriles; 1.1.3.8 From o-(Acylamino)benzaldehyde Hydrazones and Related Substrates
1.1.3.9 From Miscellaneous Substrates1.1.4 By Formation of the 3,4-Bond; 1.1.4.1 From o-Ureidobenzoic Acids; 1.1.4.2 From o-Ureidobenzoic Esters; 1.1.4.3 From o-Ureidobenzoyl Chlorides or o-Ureidobenzamides; 1.1.4.4 From o-Ureidobenzonitriles; 1.1.4.5 From o- U reidobenzaldehyde Derivatives and Related Substrates; 1.1.4.6 From o-(Aminomethy1eneamino)-benzoic Acids, Esters, or Amides; 1.1.4.7 From Miscellaneous Substrates; 1.1.5 By Formation of the 4,4a-Bond; 1.2 From a Benzene Substrate and Ancillary Synthon(s); 1.2.1 Where the Synthon Supplies N1; 1.2.2 Where the Synthon Supplies C2
1.2.2.1 The Use of Carboxylic Acids and Related Synthons1.2.2.2 The Use of Carbonic Acid-Derived Synthons; 1.2.3 Where the Synthon Supplies N3; 1.2.3.1 With o-Acylaminobenzoic Acids as Substrates; 1.2.3.2 With o-Acylaminobenzoic Esters as Substrates; 1.2.3.3 With o-Acylaminobenzonitriles as Substrates; 1.2.3.4 With o-Acylaminobenzaldehydes or Related Ketones as Substrates; 1.2.3.5 With o-(Alkoxycarbony1amino)-benzoic Esters or Related Ketones as Substrates; 1.2.3.6 With o-(Substituted Methylene-amino)benzoic Esters or Related Ketones as Substrates
1.2.3.7 With o-(Substituted Methylene-amin0)benzonitriles as Substrates1.2.3.8 With o-Isocyanatobenzoyl Chlorides as Substrates; 1.2.3.9 With o-Isocyanatobenzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.10 With o-Cyanoamino- or o-Ureido-benzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.11 With Miscellaneous Substrates; 1.2.4 Where the Synthon Supplies C4; 1.2.5 Where the Synthon(s) Supply N1 + C2; 1.2.6 Where the Synthon(s) Supply C2 + N3; 1.2.6.1 With o-Aminobenzoic Acids as Substrates; 1.2.6.2 With o-Aminobenzoic Esters as Substrates
1.2.6.3 With o-Aminobenzarnides as Substrates1.2.6.4 With o-Arninobenzonitriles as Substrates; 1.2.6.5 With o-Aminobenzaldehydes or Related Ketones as Substrates; 1.2.6.6 With Miscellaneous o-Disubstitu-ted Benzenes as Substrates; 1.2.7 Where the Synthon(s) Supply N3 + C4; 1.2.7.1 With N-Acylanilines as Substrates; 1.2.7.2 With N-(α-Chloromethy1ene)ani-lines or Related Compounds as Substrates; 1.2.7.3 With Other Aniline Derivatives as Substrates; 1.2.8 Where the Synthon(s) Supply N1+C2 + N3; 1.2.8.1 With o-Halogeno or o-Alkoxyben-zonitriles as Substrates
1.2.8.2 With o-Substituted Benzoic Esters or Related Compounds as Substrates
Record Nr. UNINA-9910144284903321
Brown D. J  
New York, : J. Wiley, c1996
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Autore Brown D. J
Pubbl/distr/stampa New York, : J. Wiley, c1996
Descrizione fisica 1 online resource (760 p.)
Disciplina 547.593
547/.59/05
547/.593
Collana Chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30612-X
9786612306129
0-470-18795-6
0-470-18894-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; CHAPTER 1. PRIMARY SYNTHESES; 1.1 From a Single Benzene Substrate; 1.1.1 By Formation of the 1,2-Bond; 1.1.2 By Formation of the 1,Sa-Bond; 1.1.3 By Formation of the 2,3-Bond; 1.1.3.1. From o-Acylaminobenzamides; 1.1.3.2 From o-Acylaminobenzamide Oximes; 1.1.3.3 From o-(A1koxycarbonylamino)-benzamides; 1.1.3.4 From o-Ureidobenzamides; 1.1.3.5 From o-(Benzylideneamino)benz-amides; 1.1.3.6 From o-Acylaminobenzonitriles; 1.1.3.7 From o-(Substituted Methylene-amin0)benzonitriles; 1.1.3.8 From o-(Acylamino)benzaldehyde Hydrazones and Related Substrates
1.1.3.9 From Miscellaneous Substrates1.1.4 By Formation of the 3,4-Bond; 1.1.4.1 From o-Ureidobenzoic Acids; 1.1.4.2 From o-Ureidobenzoic Esters; 1.1.4.3 From o-Ureidobenzoyl Chlorides or o-Ureidobenzamides; 1.1.4.4 From o-Ureidobenzonitriles; 1.1.4.5 From o- U reidobenzaldehyde Derivatives and Related Substrates; 1.1.4.6 From o-(Aminomethy1eneamino)-benzoic Acids, Esters, or Amides; 1.1.4.7 From Miscellaneous Substrates; 1.1.5 By Formation of the 4,4a-Bond; 1.2 From a Benzene Substrate and Ancillary Synthon(s); 1.2.1 Where the Synthon Supplies N1; 1.2.2 Where the Synthon Supplies C2
1.2.2.1 The Use of Carboxylic Acids and Related Synthons1.2.2.2 The Use of Carbonic Acid-Derived Synthons; 1.2.3 Where the Synthon Supplies N3; 1.2.3.1 With o-Acylaminobenzoic Acids as Substrates; 1.2.3.2 With o-Acylaminobenzoic Esters as Substrates; 1.2.3.3 With o-Acylaminobenzonitriles as Substrates; 1.2.3.4 With o-Acylaminobenzaldehydes or Related Ketones as Substrates; 1.2.3.5 With o-(Alkoxycarbony1amino)-benzoic Esters or Related Ketones as Substrates; 1.2.3.6 With o-(Substituted Methylene-amino)benzoic Esters or Related Ketones as Substrates
1.2.3.7 With o-(Substituted Methylene-amin0)benzonitriles as Substrates1.2.3.8 With o-Isocyanatobenzoyl Chlorides as Substrates; 1.2.3.9 With o-Isocyanatobenzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.10 With o-Cyanoamino- or o-Ureido-benzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.11 With Miscellaneous Substrates; 1.2.4 Where the Synthon Supplies C4; 1.2.5 Where the Synthon(s) Supply N1 + C2; 1.2.6 Where the Synthon(s) Supply C2 + N3; 1.2.6.1 With o-Aminobenzoic Acids as Substrates; 1.2.6.2 With o-Aminobenzoic Esters as Substrates
1.2.6.3 With o-Aminobenzarnides as Substrates1.2.6.4 With o-Arninobenzonitriles as Substrates; 1.2.6.5 With o-Aminobenzaldehydes or Related Ketones as Substrates; 1.2.6.6 With Miscellaneous o-Disubstitu-ted Benzenes as Substrates; 1.2.7 Where the Synthon(s) Supply N3 + C4; 1.2.7.1 With N-Acylanilines as Substrates; 1.2.7.2 With N-(α-Chloromethy1ene)ani-lines or Related Compounds as Substrates; 1.2.7.3 With Other Aniline Derivatives as Substrates; 1.2.8 Where the Synthon(s) Supply N1+C2 + N3; 1.2.8.1 With o-Halogeno or o-Alkoxyben-zonitriles as Substrates
1.2.8.2 With o-Substituted Benzoic Esters or Related Compounds as Substrates
Record Nr. UNINA-9910830529703321
Brown D. J  
New York, : J. Wiley, c1996
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Quinazolines Supplement I [[electronic resource] /] / D.J. Brown
Autore Brown D. J
Pubbl/distr/stampa New York, : J. Wiley, c1996
Descrizione fisica 1 online resource (760 p.)
Disciplina 547.593
547/.59/05
547/.593
Collana Chemistry of heterocyclic compounds
Soggetto topico Quinazoline
Heterocyclic compounds
ISBN 1-282-30612-X
9786612306129
0-470-18795-6
0-470-18894-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINAZOLINES; Contents; CHAPTER 1. PRIMARY SYNTHESES; 1.1 From a Single Benzene Substrate; 1.1.1 By Formation of the 1,2-Bond; 1.1.2 By Formation of the 1,Sa-Bond; 1.1.3 By Formation of the 2,3-Bond; 1.1.3.1. From o-Acylaminobenzamides; 1.1.3.2 From o-Acylaminobenzamide Oximes; 1.1.3.3 From o-(A1koxycarbonylamino)-benzamides; 1.1.3.4 From o-Ureidobenzamides; 1.1.3.5 From o-(Benzylideneamino)benz-amides; 1.1.3.6 From o-Acylaminobenzonitriles; 1.1.3.7 From o-(Substituted Methylene-amin0)benzonitriles; 1.1.3.8 From o-(Acylamino)benzaldehyde Hydrazones and Related Substrates
1.1.3.9 From Miscellaneous Substrates1.1.4 By Formation of the 3,4-Bond; 1.1.4.1 From o-Ureidobenzoic Acids; 1.1.4.2 From o-Ureidobenzoic Esters; 1.1.4.3 From o-Ureidobenzoyl Chlorides or o-Ureidobenzamides; 1.1.4.4 From o-Ureidobenzonitriles; 1.1.4.5 From o- U reidobenzaldehyde Derivatives and Related Substrates; 1.1.4.6 From o-(Aminomethy1eneamino)-benzoic Acids, Esters, or Amides; 1.1.4.7 From Miscellaneous Substrates; 1.1.5 By Formation of the 4,4a-Bond; 1.2 From a Benzene Substrate and Ancillary Synthon(s); 1.2.1 Where the Synthon Supplies N1; 1.2.2 Where the Synthon Supplies C2
1.2.2.1 The Use of Carboxylic Acids and Related Synthons1.2.2.2 The Use of Carbonic Acid-Derived Synthons; 1.2.3 Where the Synthon Supplies N3; 1.2.3.1 With o-Acylaminobenzoic Acids as Substrates; 1.2.3.2 With o-Acylaminobenzoic Esters as Substrates; 1.2.3.3 With o-Acylaminobenzonitriles as Substrates; 1.2.3.4 With o-Acylaminobenzaldehydes or Related Ketones as Substrates; 1.2.3.5 With o-(Alkoxycarbony1amino)-benzoic Esters or Related Ketones as Substrates; 1.2.3.6 With o-(Substituted Methylene-amino)benzoic Esters or Related Ketones as Substrates
1.2.3.7 With o-(Substituted Methylene-amin0)benzonitriles as Substrates1.2.3.8 With o-Isocyanatobenzoyl Chlorides as Substrates; 1.2.3.9 With o-Isocyanatobenzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.10 With o-Cyanoamino- or o-Ureido-benzoic Esters and Related Ketones or Nitriles as Substrates; 1.2.3.11 With Miscellaneous Substrates; 1.2.4 Where the Synthon Supplies C4; 1.2.5 Where the Synthon(s) Supply N1 + C2; 1.2.6 Where the Synthon(s) Supply C2 + N3; 1.2.6.1 With o-Aminobenzoic Acids as Substrates; 1.2.6.2 With o-Aminobenzoic Esters as Substrates
1.2.6.3 With o-Aminobenzarnides as Substrates1.2.6.4 With o-Arninobenzonitriles as Substrates; 1.2.6.5 With o-Aminobenzaldehydes or Related Ketones as Substrates; 1.2.6.6 With Miscellaneous o-Disubstitu-ted Benzenes as Substrates; 1.2.7 Where the Synthon(s) Supply N3 + C4; 1.2.7.1 With N-Acylanilines as Substrates; 1.2.7.2 With N-(α-Chloromethy1ene)ani-lines or Related Compounds as Substrates; 1.2.7.3 With Other Aniline Derivatives as Substrates; 1.2.8 Where the Synthon(s) Supply N1+C2 + N3; 1.2.8.1 With o-Halogeno or o-Alkoxyben-zonitriles as Substrates
1.2.8.2 With o-Substituted Benzoic Esters or Related Compounds as Substrates
Record Nr. UNINA-9910840725503321
Brown D. J  
New York, : J. Wiley, c1996
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui