Handbook of organopalladium chemistry for organic synthesis / / edited by Ei-ichi Negishi |
Pubbl/distr/stampa | New York, : Wiley Interscience, c2002 |
Descrizione fisica | 1 online resource (3279 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | NegishiEi-ichi |
Soggetto topico |
Organic compounds - Synthesis
Palladium catalysts |
ISBN |
9786610344611
0-471-47381-2 1-280-34461-X 1-280-36693-1 9786610366934 0-470-35209-4 0-471-46155-5 0-471-21246-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
HANDBOOK OF ORGANOPALLADIUM CHEMISTRY FOR ORGANIC SYNTHESIS Volume 2; CONTENTS; PREFACE; CONTRIBUTORS; ABBREVIATIONS; V PALLADIUM-CATALYZED REACTIONS INVOLVING NUCLEOPHILIC ATTACK ON LIGANDS; V.1 Background for Part V; V.2 Palladium-Catalyzed Nucleophilic Substitution Involving Allylpalladium, Propargylpalladium, and Related Derivatives; V.2.1 The Tsuji-Trost Reaction and Related Carbon-Carbon Bond Formation Reactions; V.2.1.1 Overview of the Palladium-Catalyzed Carbon-Carbon Bond Formation via p-Allylpalladium and Propargylpalladium Intermediates
V.2.1.2 Synthetic Scope of the Tsuji-Trost Reaction with Allylic Halides, Carboxylates, Ethers, and Related Oxygen Nucleophiles as Starting CompoundsV.2.1.3 Palladium-Catalyzed Allylation with Allyl Carbonates; V.2.1.4 Palladium-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of "Ordinary" Ketones, Aldehydes, and Other Carbonyl Compounds; V.2.1.5 Palladium-Catalyzed Substitution Reactions of Alkenyl Epoxides; V.2.1.6 Palladium-Catalyzed Substitution Reactions of Sulfur and Other Heavier Group 16 Atom-Containing Allylic Derivatives V.2.1.7 Palladium-Catalyzed Substitution Reactions of Nitrogen and Other Group 15 Atom-Containing Allylic DerivativesV.2.1.8 Palladium-Catalyzed Substitution Reactions with Propargyl and Related Electrophiles; V.2.1.9 Palladium-Catalyzed Reactions of Soft Carbon Nucleophiles with Dienes, Vinylcyclopropanes, and Related Compounds; V.2.2 Palladium-Catalyzed Allylic, Propargylic, and Allenic Substitution with Nitrogen, Oxygen, and Other Groups 15-17 Heteroatom Nucleophiles V.2.2.1 Palladium-Catalyzed Substitution Reactions of Allylic, Propargylic, and Related Electrophiles with Heteroatom NucleophilesV.2.2.2 C-O and C-N Bond Formation Involving Conjugated Dienes and Allylpalladium Intermediates; V.2.2.3 Use of Alkenes as Precursors to p-Allylpalladium Derivatives in Allylic Substitution with O, N and Other Heteroatom Nucleophiles; V.2.3 Palladium-Catalyzed Allylic, Propargylic, and Allenic Substitution with Hydrogen and Metal Nucleophiles; V.2.3.1 Palladium-Catalyzed Hydrogenolysis of Allyl and Related Derivatives V.2.3.2 Palladium-Catalyzed Deprotection of Allyl-Based Protecting GroupsV.2.3.3 Palladium-Catalyzed Allylic and Related Silylation and Other Metallations; V.2.3.4 Palladium-Catalyzed Reactions of Allyl and Related Derivatives with Organoelectrophiles; V.2.4 Palladium-Catalyzed Asymmetric Allylation and Related Reactions; V.2.5 Other Reactions of Allylpalladium and Related Derivatives; V.2.5.1 Elimination of Allylpalladium and Related Derivatives; V.2.5.2 Cycloaddition Reactions of Allylpalladium and Related Derivatives; V.2.5.3 Rearrangements of Allylpalladium and Related Derivatives V.2.6 Synthesis of Natural Products and Biologically Active Compounds via Allylpalladium and Related Derivatives |
Record Nr. | UNINA-9910146073103321 |
New York, : Wiley Interscience, c2002 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Handbook of organopalladium chemistry for organic synthesis / / edited by Ei-ichi Negishi |
Pubbl/distr/stampa | New York, : Wiley Interscience, c2002 |
Descrizione fisica | 1 online resource (3279 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | NegishiEi-ichi |
Soggetto topico |
Organic compounds - Synthesis
Palladium catalysts |
ISBN |
9786610344611
0-471-47381-2 1-280-34461-X 1-280-36693-1 9786610366934 0-470-35209-4 0-471-46155-5 0-471-21246-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
HANDBOOK OF ORGANOPALLADIUM CHEMISTRY FOR ORGANIC SYNTHESIS Volume 2; CONTENTS; PREFACE; CONTRIBUTORS; ABBREVIATIONS; V PALLADIUM-CATALYZED REACTIONS INVOLVING NUCLEOPHILIC ATTACK ON LIGANDS; V.1 Background for Part V; V.2 Palladium-Catalyzed Nucleophilic Substitution Involving Allylpalladium, Propargylpalladium, and Related Derivatives; V.2.1 The Tsuji-Trost Reaction and Related Carbon-Carbon Bond Formation Reactions; V.2.1.1 Overview of the Palladium-Catalyzed Carbon-Carbon Bond Formation via p-Allylpalladium and Propargylpalladium Intermediates
V.2.1.2 Synthetic Scope of the Tsuji-Trost Reaction with Allylic Halides, Carboxylates, Ethers, and Related Oxygen Nucleophiles as Starting CompoundsV.2.1.3 Palladium-Catalyzed Allylation with Allyl Carbonates; V.2.1.4 Palladium-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of "Ordinary" Ketones, Aldehydes, and Other Carbonyl Compounds; V.2.1.5 Palladium-Catalyzed Substitution Reactions of Alkenyl Epoxides; V.2.1.6 Palladium-Catalyzed Substitution Reactions of Sulfur and Other Heavier Group 16 Atom-Containing Allylic Derivatives V.2.1.7 Palladium-Catalyzed Substitution Reactions of Nitrogen and Other Group 15 Atom-Containing Allylic DerivativesV.2.1.8 Palladium-Catalyzed Substitution Reactions with Propargyl and Related Electrophiles; V.2.1.9 Palladium-Catalyzed Reactions of Soft Carbon Nucleophiles with Dienes, Vinylcyclopropanes, and Related Compounds; V.2.2 Palladium-Catalyzed Allylic, Propargylic, and Allenic Substitution with Nitrogen, Oxygen, and Other Groups 15-17 Heteroatom Nucleophiles V.2.2.1 Palladium-Catalyzed Substitution Reactions of Allylic, Propargylic, and Related Electrophiles with Heteroatom NucleophilesV.2.2.2 C-O and C-N Bond Formation Involving Conjugated Dienes and Allylpalladium Intermediates; V.2.2.3 Use of Alkenes as Precursors to p-Allylpalladium Derivatives in Allylic Substitution with O, N and Other Heteroatom Nucleophiles; V.2.3 Palladium-Catalyzed Allylic, Propargylic, and Allenic Substitution with Hydrogen and Metal Nucleophiles; V.2.3.1 Palladium-Catalyzed Hydrogenolysis of Allyl and Related Derivatives V.2.3.2 Palladium-Catalyzed Deprotection of Allyl-Based Protecting GroupsV.2.3.3 Palladium-Catalyzed Allylic and Related Silylation and Other Metallations; V.2.3.4 Palladium-Catalyzed Reactions of Allyl and Related Derivatives with Organoelectrophiles; V.2.4 Palladium-Catalyzed Asymmetric Allylation and Related Reactions; V.2.5 Other Reactions of Allylpalladium and Related Derivatives; V.2.5.1 Elimination of Allylpalladium and Related Derivatives; V.2.5.2 Cycloaddition Reactions of Allylpalladium and Related Derivatives; V.2.5.3 Rearrangements of Allylpalladium and Related Derivatives V.2.6 Synthesis of Natural Products and Biologically Active Compounds via Allylpalladium and Related Derivatives |
Record Nr. | UNINA-9910676659203321 |
New York, : Wiley Interscience, c2002 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Handbook of palladium-catalyzed organic reactions [[electronic resource] ] : synthetic aspects and catalytic cycles / / J.-L. Malleron, J.-C. Fiaud and J.-Y. Legros |
Autore | Malleron Jean-Luc |
Pubbl/distr/stampa | San Diego, : Academic Press, c1997 |
Descrizione fisica | 1 online resource (319 p.) |
Disciplina | 547.1395 |
Altri autori (Persone) |
FiaudJ. C
LegrosJ.-Y (Jean-Yves) MalleronJean-Luc |
Soggetto topico |
Chemistry, Inorganic
Palladium catalysts |
Soggetto genere / forma | Electronic books. |
ISBN |
1-281-74939-7
9786611749392 0-08-053314-0 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Handbook of Palladium-Catalyzed Organic Reactions: Synthetic Aspects and Catalytic Cycles; Copyright Page; Table of Contents; Foreword; Abbreviations; I- Introduction; II- Graphical abstracts of reaction numbers (RXN); III- Reactions catalysed by palladium complexes; RXN1 Cross-Coupling of Organometallics with RX Derivatives; RXN2 Cross-Coupling of Organometallics with RCOX Derivatives; RXN3 Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives; RXN4 Cross-Coupling of Terminal Alkynes with RX Derivatives; RXN5 Intermolecular HECK Reaction
RXN6 Intramolecular HECK ReactionRXN7 Intramolecular Coupling of Di(Vinyl Halides); RXN8 Tandem HECK-Anion Capture Process of Alkenes, Alkynes, Allenes and Dienes; RXN9 Tandem HECK-Anion Capture Process of Norbornene and Related Compounds; RXN10 Tandem Arylsulfonation-Cyclization Process; RXN11 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Alkenes, Allenes and Alkynes; RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides; RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and Yne-Aryl Halides RXN14 Hydroarylation and Hydrovinylation of Alkenes and AlkynesRXN15 Reduction of Alkenes; RXN16 Semihydrogenation of Alkynes and 1,3-Dienes; RXN17 Hydroboration, Hydrogermylation, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes and Enynes; RXN18 Hydroselenation of Alkynes; RXN19 1,4- Disilylation of Conjugated Enones; RXN20 Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes; RXN21 Tandem Carbonylation-Arylation with Alkynes; RXN22 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions; RXN23 1,2-Dimetallation of Isonitriles RXN24 1,2-Dimetallation of Allenes or 1,3-DienesRXN25 Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst; RXN26 Homocoupling of Aryl and Vinyl Derivatives; RXN27 Codimerization of Alkynes; RXN28 Codimerization of Terminal Alkynes with Allenes; RXN29 Codimerization of Alkynes and Allyl Halides; RXN30 Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane; RXN31 Rearrangement of α-Hydroxy Diazo Compounds; RXN32 Substitution, Addition and Elimination on Pro-π-Allyl Substrates; RXN33 [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives RXN34 1,3-Diene Monoepoxide RearrangementRXN35 Ring Extension of Cyclobutane Derivatives; RXN36 [3+2], [3+4], [3+6], [1+2] Cycloadditions; RXN37 Intramolecular Ene-Like Reactions; RXN38 Cyclization of Hexatrienolate Derivatives; RXN39 Amination or Amidation of Alkenes; RXN40 Alkoxylation of Alkenes and Alkynes; RXN41 Acetalization of Alkenes; RXN42 Allylic Acyloxylation of Cycloalkenes; RXN43 Tandem Acyloxylation-Cyclization of 1,5-Dienes; RXN44 Tandem Acyloxychlorination-Cyclization of 1,6-Dienes; RXN45 1,4-Acyloxychlorination of 1,3-Dienes RXN46 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions |
Record Nr. | UNINA-9910457966203321 |
Malleron Jean-Luc | ||
San Diego, : Academic Press, c1997 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Handbook of palladium-catalyzed organic reactions [[electronic resource] ] : synthetic aspects and catalytic cycles / / J.-L. Malleron, J.-C. Fiaud and J.-Y. Legros |
Autore | Malleron Jean-Luc |
Pubbl/distr/stampa | San Diego, : Academic Press, c1997 |
Descrizione fisica | 1 online resource (319 p.) |
Disciplina | 547.1395 |
Altri autori (Persone) |
FiaudJ. C
LegrosJ.-Y (Jean-Yves) MalleronJean-Luc |
Soggetto topico |
Chemistry, Inorganic
Palladium catalysts |
ISBN |
1-281-74939-7
9786611749392 0-08-053314-0 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Handbook of Palladium-Catalyzed Organic Reactions: Synthetic Aspects and Catalytic Cycles; Copyright Page; Table of Contents; Foreword; Abbreviations; I- Introduction; II- Graphical abstracts of reaction numbers (RXN); III- Reactions catalysed by palladium complexes; RXN1 Cross-Coupling of Organometallics with RX Derivatives; RXN2 Cross-Coupling of Organometallics with RCOX Derivatives; RXN3 Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives; RXN4 Cross-Coupling of Terminal Alkynes with RX Derivatives; RXN5 Intermolecular HECK Reaction
RXN6 Intramolecular HECK ReactionRXN7 Intramolecular Coupling of Di(Vinyl Halides); RXN8 Tandem HECK-Anion Capture Process of Alkenes, Alkynes, Allenes and Dienes; RXN9 Tandem HECK-Anion Capture Process of Norbornene and Related Compounds; RXN10 Tandem Arylsulfonation-Cyclization Process; RXN11 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Alkenes, Allenes and Alkynes; RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides; RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and Yne-Aryl Halides RXN14 Hydroarylation and Hydrovinylation of Alkenes and AlkynesRXN15 Reduction of Alkenes; RXN16 Semihydrogenation of Alkynes and 1,3-Dienes; RXN17 Hydroboration, Hydrogermylation, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes and Enynes; RXN18 Hydroselenation of Alkynes; RXN19 1,4- Disilylation of Conjugated Enones; RXN20 Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes; RXN21 Tandem Carbonylation-Arylation with Alkynes; RXN22 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions; RXN23 1,2-Dimetallation of Isonitriles RXN24 1,2-Dimetallation of Allenes or 1,3-DienesRXN25 Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst; RXN26 Homocoupling of Aryl and Vinyl Derivatives; RXN27 Codimerization of Alkynes; RXN28 Codimerization of Terminal Alkynes with Allenes; RXN29 Codimerization of Alkynes and Allyl Halides; RXN30 Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane; RXN31 Rearrangement of α-Hydroxy Diazo Compounds; RXN32 Substitution, Addition and Elimination on Pro-π-Allyl Substrates; RXN33 [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives RXN34 1,3-Diene Monoepoxide RearrangementRXN35 Ring Extension of Cyclobutane Derivatives; RXN36 [3+2], [3+4], [3+6], [1+2] Cycloadditions; RXN37 Intramolecular Ene-Like Reactions; RXN38 Cyclization of Hexatrienolate Derivatives; RXN39 Amination or Amidation of Alkenes; RXN40 Alkoxylation of Alkenes and Alkynes; RXN41 Acetalization of Alkenes; RXN42 Allylic Acyloxylation of Cycloalkenes; RXN43 Tandem Acyloxylation-Cyclization of 1,5-Dienes; RXN44 Tandem Acyloxychlorination-Cyclization of 1,6-Dienes; RXN45 1,4-Acyloxychlorination of 1,3-Dienes RXN46 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions |
Record Nr. | UNINA-9910784534503321 |
Malleron Jean-Luc | ||
San Diego, : Academic Press, c1997 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Handbook of palladium-catalyzed organic reactions [[electronic resource] ] : synthetic aspects and catalytic cycles / / J.-L. Malleron, J.-C. Fiaud and J.-Y. Legros |
Autore | Malleron Jean-Luc |
Edizione | [1st ed.] |
Pubbl/distr/stampa | San Diego, : Academic Press, c1997 |
Descrizione fisica | 1 online resource (319 p.) |
Disciplina | 547.1395 |
Altri autori (Persone) |
FiaudJ. C
LegrosJ.-Y (Jean-Yves) MalleronJean-Luc |
Soggetto topico |
Chemistry, Inorganic
Palladium catalysts |
ISBN |
1-281-74939-7
9786611749392 0-08-053314-0 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Handbook of Palladium-Catalyzed Organic Reactions: Synthetic Aspects and Catalytic Cycles; Copyright Page; Table of Contents; Foreword; Abbreviations; I- Introduction; II- Graphical abstracts of reaction numbers (RXN); III- Reactions catalysed by palladium complexes; RXN1 Cross-Coupling of Organometallics with RX Derivatives; RXN2 Cross-Coupling of Organometallics with RCOX Derivatives; RXN3 Cross-Coupling of Siloxycyclopropanes with RX and RCOX Derivatives; RXN4 Cross-Coupling of Terminal Alkynes with RX Derivatives; RXN5 Intermolecular HECK Reaction
RXN6 Intramolecular HECK ReactionRXN7 Intramolecular Coupling of Di(Vinyl Halides); RXN8 Tandem HECK-Anion Capture Process of Alkenes, Alkynes, Allenes and Dienes; RXN9 Tandem HECK-Anion Capture Process of Norbornene and Related Compounds; RXN10 Tandem Arylsulfonation-Cyclization Process; RXN11 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Alkenes, Allenes and Alkynes; RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides; RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and Yne-Aryl Halides RXN14 Hydroarylation and Hydrovinylation of Alkenes and AlkynesRXN15 Reduction of Alkenes; RXN16 Semihydrogenation of Alkynes and 1,3-Dienes; RXN17 Hydroboration, Hydrogermylation, Hydrosilylation and Hydrostannation of Alkynes, Allenes, Dienes and Enynes; RXN18 Hydroselenation of Alkynes; RXN19 1,4- Disilylation of Conjugated Enones; RXN20 Hydrocarboxylation, Hydrocarboalkoxylation and Hydrocarboamination of Alkenes and Alkynes; RXN21 Tandem Carbonylation-Arylation with Alkynes; RXN22 1,2-Dimetallation of Alkynes and Alkenes and Related Reactions; RXN23 1,2-Dimetallation of Isonitriles RXN24 1,2-Dimetallation of Allenes or 1,3-DienesRXN25 Coupling of Aryl Derivatives with Alkenes Involving a Pd(II) Catalyst; RXN26 Homocoupling of Aryl and Vinyl Derivatives; RXN27 Codimerization of Alkynes; RXN28 Codimerization of Terminal Alkynes with Allenes; RXN29 Codimerization of Alkynes and Allyl Halides; RXN30 Cyclopropanation of Alkenes and 1,3-Dienes by Diazomethane; RXN31 Rearrangement of α-Hydroxy Diazo Compounds; RXN32 Substitution, Addition and Elimination on Pro-π-Allyl Substrates; RXN33 [3,3]-Sigmatropic Rearrangement and [1,3]-Shift on Allylic Derivatives RXN34 1,3-Diene Monoepoxide RearrangementRXN35 Ring Extension of Cyclobutane Derivatives; RXN36 [3+2], [3+4], [3+6], [1+2] Cycloadditions; RXN37 Intramolecular Ene-Like Reactions; RXN38 Cyclization of Hexatrienolate Derivatives; RXN39 Amination or Amidation of Alkenes; RXN40 Alkoxylation of Alkenes and Alkynes; RXN41 Acetalization of Alkenes; RXN42 Allylic Acyloxylation of Cycloalkenes; RXN43 Tandem Acyloxylation-Cyclization of 1,5-Dienes; RXN44 Tandem Acyloxychlorination-Cyclization of 1,6-Dienes; RXN45 1,4-Acyloxychlorination of 1,3-Dienes RXN46 1,4-Diacyloxylation of 1,3-Dienes and Related Reactions |
Record Nr. | UNINA-9910826075503321 |
Malleron Jean-Luc | ||
San Diego, : Academic Press, c1997 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
Autore | Oestreich Martin |
Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
Descrizione fisica | 1 online resource (609 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | OestreichMartin |
Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
Record Nr. | UNINA-9910146128703321 |
Oestreich Martin | ||
Chichester, U.K., : Wiley, 2009 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
Autore | Oestreich Martin |
Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
Descrizione fisica | 1 online resource (609 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | OestreichMartin |
Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
Record Nr. | UNINA-9910830440403321 |
Oestreich Martin | ||
Chichester, U.K., : Wiley, 2009 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
Autore | Oestreich Martin |
Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
Descrizione fisica | 1 online resource (609 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | OestreichMartin |
Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
Record Nr. | UNINA-9910840874903321 |
Oestreich Martin | ||
Chichester, U.K., : Wiley, 2009 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
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Palladium in heterocyclic chemistry : a guide for the synthetic chemist / Jie Jack Li, Gordon W. Gribble |
Autore | Li, Jie Jack |
Pubbl/distr/stampa | Amsterdam : Pergamon, 2000 |
Descrizione fisica | xviii, 413 p. : ill. ; 25 cm |
Disciplina | 547.590459 |
Altri autori (Persone) | Gribble, Gordon W. |
Collana | Tetrahedron organic chemistry series ; 20 |
Soggetto topico |
Heterocyclic compounds - Synthesis
Organopalladium compounds Palladium catalysts |
ISBN |
0080437052
0080437044 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNISALENTO-991000215329707536 |
Li, Jie Jack | ||
Amsterdam : Pergamon, 2000 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. del Salento | ||
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Palladium reagents and catalysts : new perspectives for the 21st century |
Autore | Tsuji Jiro |
Pubbl/distr/stampa | [Place of publication not identified], : Wiley, 2004 |
Disciplina | 547/.2 |
Soggetto topico |
Organic compounds - Synthesis
Palladium catalysts Organic Chemistry Chemistry Physical Sciences & Mathematics |
ISBN |
9786610554324
0-470-02120-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910145753403321 |
Tsuji Jiro | ||
[Place of publication not identified], : Wiley, 2004 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
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